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Operation characteristics and carbon corrosion of PEMFC (Proton exchange membrane fuel cell) with dead-ended anode for high hydrogen utilization

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  • Chen, Ben
  • Ke, Wandi
  • Luo, Maji
  • Wang, Jun
  • Tu, Zhengkai
  • Pan, Mu
  • Zhang, Haining
  • Liu, Xiaowei
  • Liu, Wei

Abstract

PEMFC (Proton exchange membrane fuel cell) operated under dead-ended anode mode is an effective and simple device for high hydrogen utilization. Herein, the operation characteristics of PEMFC with dead-ended anode are systematically investigated under various operating temperature, anode inlet pressure, and cathode stoichiometry. In each operating parameter, the solenoid valve located at the anode outlet is closed all the time and the hydrogen utilization reaches 100%. It has been found that fuel cell with dead-ended anode can operate continuously for 26 h with slight decrease in output voltage under 600 mA cm−2 at 65 °C, 80% of RH (relative humidity) with hydrogen inlet pressure of 0.4 bar gauge and oxygen stoichiometry of 4.0. After accumulated 150 h operation under dead-ended anode mode, the degradation of according MEA (membrane electrode assembly) has been analyzed using CV (cyclic voltammetry) and cross-sectional morphology. The results show that the accumulation of water induced corrosion of catalyst layer is responsible for the decrease in ECSA (electrochemical surface area) of catalyst layer and the according degradation of cell performance. Moreover, the degradation of catalyst layer became much more serious at the vicinity of cathode outlet than the other regions.

Suggested Citation

  • Chen, Ben & Ke, Wandi & Luo, Maji & Wang, Jun & Tu, Zhengkai & Pan, Mu & Zhang, Haining & Liu, Xiaowei & Liu, Wei, 2015. "Operation characteristics and carbon corrosion of PEMFC (Proton exchange membrane fuel cell) with dead-ended anode for high hydrogen utilization," Energy, Elsevier, vol. 91(C), pages 799-806.
    • Handle: RePEc:eee:energy:v:91:y:2015:i:c:p:799-806
    DOI: 10.1016/j.energy.2015.08.083
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    as
    1. Chen, Yong-Song & Yang, Chih-Wei & Lee, Jiunn-Yih, 2014. "Implementation and evaluation for anode purging of a fuel cell based on nitrogen concentration," Applied Energy, Elsevier, vol. 113(C), pages 1519-1524.
    2. Gomez, Alberto & Raj, Abhishek & Sasmito, Agus P. & Shamim, Tariq, 2014. "Effect of operating parameters on the transient performance of a polymer electrolyte membrane fuel cell stack with a dead-end anode," Applied Energy, Elsevier, vol. 130(C), pages 692-701.
    3. Jian, Qifei & Zhao, Yang & Wang, Haoting, 2015. "An experimental study of the dynamic behavior of a 2 kW proton exchange membrane fuel cell stack under various loading conditions," Energy, Elsevier, vol. 80(C), pages 740-745.
    4. Kim, Jintae & Kim, Minjin & Kang, Taegon & Sohn, Young-Jun & Song, Taewon & Choi, Kyoung Hwan, 2014. "Degradation modeling and operational optimization for improving the lifetime of high-temperature PEM (proton exchange membrane) fuel cells," Energy, Elsevier, vol. 66(C), pages 41-49.
    5. Huang, Zhen-Ming & Su, Ay & Liu, Ying-Chieh, 2014. "Development and testing of a hybrid system with a sub-kW open-cathode type PEM (proton exchange membrane) fuel cell stack," Energy, Elsevier, vol. 72(C), pages 547-553.
    6. Iranzo, Alfredo & Boillat, Pierre & Biesdorf, Johannes & Salva, Antonio, 2015. "Investigation of the liquid water distributions in a 50 cm2 PEM fuel cell: Effects of reactants relative humidity, current density, and cathode stoichiometry," Energy, Elsevier, vol. 82(C), pages 914-921.
    7. Hou, Yongping & Shen, Caoyuan & Hao, Dong & Liu, Yanan & Wang, Hong, 2014. "A dynamic model for hydrogen consumption of fuel cell stacks considering the effects of hydrogen purge operation," Renewable Energy, Elsevier, vol. 62(C), pages 672-678.
    8. Wan, Zhongmin & Liu, Jing & Luo, Zhiping & Tu, Zhengkai & Liu, Zhichun & Liu, Wei, 2013. "Evaluation of self-water-removal in a dead-ended proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 104(C), pages 751-757.
    9. Yang, Chih-Wei & Chen, Yong-Song, 2014. "A mathematical model to study the performance of a proton exchange membrane fuel cell in a dead-ended anode mode," Applied Energy, Elsevier, vol. 130(C), pages 113-121.
    10. Pei, Pucheng & Chen, Huicui, 2014. "Main factors affecting the lifetime of Proton Exchange Membrane fuel cells in vehicle applications: A review," Applied Energy, Elsevier, vol. 125(C), pages 60-75.
    11. Kariya, Tetsuro & Yanagimoto, Katsu & Funakubo, Hiroshi & Shudo, Toshio, 2015. "Effects of porous flow field type separators using sintered Ni-based alloy powders on interfacial contact resistances and fuel cell performances," Energy, Elsevier, vol. 87(C), pages 134-141.
    12. Jang, Jer-Huan & Yan, Wei-Mon & Chiu, Han-Chieh & Lui, Jun-Yi, 2015. "Dynamic cell performance of kW-grade proton exchange membrane fuel cell stack with dead-ended anode," Applied Energy, Elsevier, vol. 142(C), pages 108-114.
    13. Ferreira, Rui B. & Falcão, D.S. & Oliveira, V.B. & Pinto, A.M.F.R., 2015. "Numerical simulations of two-phase flow in an anode gas channel of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 82(C), pages 619-628.
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    3. Chen, Ben & Cai, Yonghua & Tu, Zhengkai & Chan, Siew Hwa & Wang, Jun & Yu, Yi, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation I. With different electrolytes," Energy, Elsevier, vol. 141(C), pages 40-49.
    4. Li, Bing & Wan, Kechuang & Xie, Meng & Chu, Tiankuo & Wang, Xiaolei & Li, Xiang & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2022. "Durability degradation mechanism and consistency analysis for proton exchange membrane fuel cell stack," Applied Energy, Elsevier, vol. 314(C).
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    6. Lei, Gang & Zheng, Hualin & Zhang, Jun & Siong Chin, Cheng & Xu, Xinhai & Zhou, Weijiang & Zhang, Caizhi, 2023. "Analyzing characteristic and modeling of high-temperature proton exchange membrane fuel cells with CO poisoning effect," Energy, Elsevier, vol. 282(C).
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    9. Tsai, Shang-Wen & Chen, Yong-Song, 2017. "A mathematical model to study the energy efficiency of a proton exchange membrane fuel cell with a dead-ended anode," Applied Energy, Elsevier, vol. 188(C), pages 151-159.
    10. Chu, Tiankuo & Zhang, Ruofan & Wang, Yanbo & Ou, Mingyang & Xie, Meng & Shao, Hangyu & Yang, Daijun & Li, Bing & Ming, Pingwen & Zhang, Cunman, 2021. "Performance degradation and process engineering of the 10 kW proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 219(C).
    11. Chen, Ben & Wang, Jun & Yang, Tianqi & Cai, Yonghua & Zhang, Caizhi & Chan, Siew Hwa & Yu, Yi & Tu, Zhengkai, 2016. "Carbon corrosion and performance degradation mechanism in a proton exchange membrane fuel cell with dead-ended anode and cathode," Energy, Elsevier, vol. 106(C), pages 54-62.
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    13. Chen, Ben & Liu, Qi & Zhang, Cheng & Liu, Yang & Shen, Jun & Tu, Zhengkai, 2022. "Numerical study on water transfer characteristics under joint effect of placement orientation and flow channel size for PEMFC with dead-ended anode," Energy, Elsevier, vol. 254(PB).
    14. Pedro A. Pérez-Guizado & Alba María Fernández-Sotillo & Paloma Ferreira-Aparicio, 2020. "Passive Regulation of the Water Content at the Anode Chamber under Dead-Ended Conditions: Innovative Design of an Air-Breathing Proton Exchange Membrane Fuel Cell," Energies, MDPI, vol. 13(22), pages 1-11, November.
    15. Deng, Hao & Wang, Dawei & Wang, Renfang & Xie, Xu & Yin, Yan & Du, Qing & Jiao, Kui, 2016. "Effect of electrode design and operating condition on performance of hydrogen alkaline membrane fuel cell," Applied Energy, Elsevier, vol. 183(C), pages 1272-1278.
    16. Yuemeng Zhang & Jia Wang & Zhanhui Yao, 2023. "Recent Development of Fuel Cell Core Components and Key Materials: A Review," Energies, MDPI, vol. 16(5), pages 1-23, February.

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