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Anode partial flooding modelling of proton exchange membrane fuel cells: Model development and validation

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  • Xing, Lei
  • Du, Shangfeng
  • Chen, Rui
  • Mamlouk, Mohamed
  • Scott, Keith

Abstract

A two-dimensional along-the-channel CFD (computational fluid dynamic) model, coupled with a two-phase flow model of liquid water and gas transport for a PEM (proton exchange membrane) fuel cell is described. The model considers non-isothermal operation and thus the non-uniform temperature distribution in the cell structure. Water phase-transfer between the vapour, liquid water and dissolved phase is modelled with the combinational transport mechanism through the membrane. Liquid water saturation is simulated inside the electrodes and channels at both the anode and cathode sides. Three types of models are compared for the HOR (hydrogen oxidation reaction) and ORR (oxygen reduction reaction) in catalyst layers, including Butler–Volmer (B–V), liquid water saturation corrected B–V and agglomerate mechanisms. Temperature changes in MEA (membrane electrode assembly) and channels due to electrochemical reaction, ohmic resistance and water phase-transfer are analysed as a function of current density. Nonlinear relations of liquid water saturations with respect to current densities at both the anode and cathode are regressed. At low and high current densities, liquid water saturation at the anode linearly increases as a consequence of the linear increase of liquid water saturation at the cathode. In contrast, exponential relation is found to be more accurate at medium current densities.

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  • Xing, Lei & Du, Shangfeng & Chen, Rui & Mamlouk, Mohamed & Scott, Keith, 2016. "Anode partial flooding modelling of proton exchange membrane fuel cells: Model development and validation," Energy, Elsevier, vol. 96(C), pages 80-95.
    • Handle: RePEc:eee:energy:v:96:y:2016:i:c:p:80-95
    DOI: 10.1016/j.energy.2015.12.048
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    References listed on IDEAS

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    1. Wang, Junye, 2015. "Barriers of scaling-up fuel cells: Cost, durability and reliability," Energy, Elsevier, vol. 80(C), pages 509-521.
    2. Xing, Lei & Liu, Xiaoteng & Alaje, Taiwo & Kumar, Ravi & Mamlouk, Mohamed & Scott, Keith, 2014. "A two-phase flow and non-isothermal agglomerate model for a proton exchange membrane (PEM) fuel cell," Energy, Elsevier, vol. 73(C), pages 618-634.
    3. Lund, Henrik & Andersen, Anders N. & Østergaard, Poul Alberg & Mathiesen, Brian Vad & Connolly, David, 2012. "From electricity smart grids to smart energy systems – A market operation based approach and understanding," Energy, Elsevier, vol. 42(1), pages 96-102.
    4. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
    5. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    6. Xing, Lei & Mamlouk, Mohamed & Scott, Keith, 2013. "A two dimensional agglomerate model for a proton exchange membrane fuel cell," Energy, Elsevier, vol. 61(C), pages 196-210.
    7. Iranzo, Alfredo & Boillat, Pierre & Biesdorf, Johannes & Salva, Antonio, 2015. "Investigation of the liquid water distributions in a 50 cm2 PEM fuel cell: Effects of reactants relative humidity, current density, and cathode stoichiometry," Energy, Elsevier, vol. 82(C), pages 914-921.
    8. Rokni, Masoud, 2014. "Thermodynamic and thermoeconomic analysis of a system with biomass gasification, solid oxide fuel cell (SOFC) and Stirling engine," Energy, Elsevier, vol. 76(C), pages 19-31.
    9. Djilali, N., 2007. "Computational modelling of polymer electrolyte membrane (PEM) fuel cells: Challenges and opportunities," Energy, Elsevier, vol. 32(4), pages 269-280.
    10. Wu, Hao & Berg, Peter & Li, Xianguo, 2010. "Steady and unsteady 3D non-isothermal modeling of PEM fuel cells with the effect of non-equilibrium phase transfer," Applied Energy, Elsevier, vol. 87(9), pages 2778-2784, September.
    11. Cappa, Francesco & Facci, Andrea Luigi & Ubertini, Stefano, 2015. "Proton exchange membrane fuel cell for cooperating households: A convenient combined heat and power solution for residential applications," Energy, Elsevier, vol. 90(P2), pages 1229-1238.
    12. Carton, J.G. & Olabi, A.G., 2010. "Wind/hydrogen hybrid systems: Opportunity for Ireland’s wind resource to provide consistent sustainable energy supply," Energy, Elsevier, vol. 35(12), pages 4536-4544.
    13. Rokni, Masoud, 2014. "Biomass gasification integrated with a solid oxide fuel cell and Stirling engine," Energy, Elsevier, vol. 77(C), pages 6-18.
    14. Ferreira, Rui B. & Falcão, D.S. & Oliveira, V.B. & Pinto, A.M.F.R., 2015. "Numerical simulations of two-phase flow in an anode gas channel of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 82(C), pages 619-628.
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    8. Ismail, M.S. & Ingham, D.B. & Ma, L. & Hughes, K.J. & Pourkashanian, M., 2017. "Effects of catalyst agglomerate shape in polymer electrolyte fuel cells investigated by a multi-scale modelling framework," Energy, Elsevier, vol. 122(C), pages 420-430.
    9. Bhuvanendran, Narayanamoorthy & Ravichandran, Sabarinathan & Jayaseelan, Santhana Sivabalan & Xu, Qian & Khotseng, Lindiwe & Su, Huaneng, 2020. "Improved bi-functional oxygen electrocatalytic performance of Pt–Ir alloy nanoparticles embedded on MWCNT with Pt-enriched surfaces," Energy, Elsevier, vol. 211(C).
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    11. Akira Nishimura & Tatsuya Okado & Yuya Kojima & Masafumi Hirota & Eric Hu, 2020. "Impact of MPL on Temperature Distribution in Single Polymer Electrolyte Fuel Cell with Various Thicknesses of Polymer Electrolyte Membrane," Energies, MDPI, vol. 13(10), pages 1-17, May.
    12. Yin, Cong & Gao, Jianlong & Wen, Xuhui & Xie, Guangyou & Yang, Chunhua & Fang, Honglin & Tang, Hao, 2016. "In situ investigation of proton exchange membrane fuel cell performance with novel segmented cell design and a two-phase flow model," Energy, Elsevier, vol. 113(C), pages 1071-1089.
    13. Hu, Zunyan & Xu, Liangfei & Huang, Yiyuan & Li, Jianqiu & Ouyang, Minggao & Du, Xiaoli & Jiang, Hongliang, 2018. "Comprehensive analysis of galvanostatic charge method for fuel cell degradation diagnosis," Applied Energy, Elsevier, vol. 212(C), pages 1321-1332.
    14. Guo, Hang & Song, Jia & Ye, Fang & Chong Fang, M.A., 2022. "Dynamic response during mode switching of unitized regenerative fuel cells with orientational flow channels," Renewable Energy, Elsevier, vol. 188(C), pages 698-710.
    15. Xing, Lei & Shi, Weidong & Su, Huaneng & Xu, Qian & Das, Prodip K. & Mao, Baodong & Scott, Keith, 2019. "Membrane electrode assemblies for PEM fuel cells: A review of functional graded design and optimization," Energy, Elsevier, vol. 177(C), pages 445-464.
    16. Xing, Lei & Cai, Qiong & Xu, Chenxi & Liu, Chunbo & Scott, Keith & Yan, Yongsheng, 2016. "Numerical study of the effect of relative humidity and stoichiometric flow ratio on PEM (proton exchange membrane) fuel cell performance with various channel lengths: An anode partial flooding modelli," Energy, Elsevier, vol. 106(C), pages 631-645.

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