IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v66y2014icp41-49.html
   My bibliography  Save this article

Degradation modeling and operational optimization for improving the lifetime of high-temperature PEM (proton exchange membrane) fuel cells

Author

Listed:
  • Kim, Jintae
  • Kim, Minjin
  • Kang, Taegon
  • Sohn, Young-Jun
  • Song, Taewon
  • Choi, Kyoung Hwan

Abstract

High-temperature PEMFCs (proton exchange membrane fuel cells) using PA (phosphoric acid)-doped PBI (polybenzimidazole) membranes have received attention as a potential solution to several of the issues with traditional low-temperature PEMFCs. However, the durability of high-temperature PEMFCs deteriorates rapidly with increasing temperature, although its performance improves. This characteristic makes it difficult to select the proper operating temperature to achieve its target lifetime. In this paper, to resolve this problem, models were developed to predict the performance and durability of the high-temperature PEMFC as a function of operating temperature. The optimal operating temperature was then determined for a variety of lifetimes. Theoretical model to estimate cell performance and empirical model to predict the degradation rate of cell performance were constructed, respectively. The prediction results of the developed models agreed well with the experimental data. From the simulation, we could obtain higher average cell performances by optimizing the operating temperature for the given target lifetime compared to the cell performance at some temperatures determined using an existing rule of thumb. It is expected that the proposed methodologies will lead to the more rapid commercialization of this technology in such applications as stationary and automotive fuel cell systems.

Suggested Citation

  • Kim, Jintae & Kim, Minjin & Kang, Taegon & Sohn, Young-Jun & Song, Taewon & Choi, Kyoung Hwan, 2014. "Degradation modeling and operational optimization for improving the lifetime of high-temperature PEM (proton exchange membrane) fuel cells," Energy, Elsevier, vol. 66(C), pages 41-49.
    • Handle: RePEc:eee:energy:v:66:y:2014:i:c:p:41-49
    DOI: 10.1016/j.energy.2013.08.053
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544213007421
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2013.08.053?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Appleby, A.J., 1996. "Fuel cell technology: Status and future prospects," Energy, Elsevier, vol. 21(7), pages 521-653.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ryu, Sung Kwan & Vinothkannan, Mohanraj & Kim, Ae Rhan & Yoo, Dong Jin, 2022. "Effect of type and stoichiometry of fuels on performance of polybenzimidazole-based proton exchange membrane fuel cells operating at the temperature range of 120–160 °C," Energy, Elsevier, vol. 238(PB).
    2. Roshandel, Ramin & Parhizkar, Tarannom, 2016. "Degradation based optimization framework for long term applications of energy systems, case study: Solid oxide fuel cell stacks," Energy, Elsevier, vol. 107(C), pages 172-181.
    3. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    4. Kun He & Dongchen Qin & Jiangyi Chen & Tingting Wang & Hongxia Wu & Peizhuo Wang, 2023. "Adaptive Equivalent Consumption Minimization Strategy for Fuel Cell Buses Based on Driving Style Recognition," Sustainability, MDPI, vol. 15(10), pages 1-17, May.
    5. Zhang, Caizhi & Liu, Zhitao & Zhang, Xiongwen & Chan, Siew Hwa & Wang, Youyi, 2016. "Dynamic performance of a high-temperature PEM (proton exchange membrane) fuel cell – Modelling and fuzzy control of purging process," Energy, Elsevier, vol. 95(C), pages 425-432.
    6. Lee, Won-Yong & Kim, Minjin & Sohn, Young-Jun & Kim, Seung-Gon, 2016. "Power optimization of a combined power system consisting of a high-temperature polymer electrolyte fuel cell and an organic Rankine cycle system," Energy, Elsevier, vol. 113(C), pages 1062-1070.
    7. Alizadeh, E. & Ghadimi, M. & Barzegari, M.M. & Momenifar, M. & Saadat, S.H.M., 2017. "Development of contact pressure distribution of PEM fuel cell's MEA using novel clamping mechanism," Energy, Elsevier, vol. 131(C), pages 92-97.
    8. Lee, Won-Yong & Kim, Minjin & Sohn, Young-Jun & Kim, Seung-Gon, 2017. "Performance of a hybrid system consisting of a high-temperature polymer electrolyte fuel cell and an absorption refrigerator," Energy, Elsevier, vol. 141(C), pages 2397-2407.
    9. Zhang, S. & Reimer, U. & Beale, S.B. & Lehnert, W. & Stolten, D., 2019. "Modeling polymer electrolyte fuel cells: A high precision analysis," Applied Energy, Elsevier, vol. 233, pages 1094-1103.
    10. Sun, Hong & Xie, Chen & Chen, Hao & Almheiri, Saif, 2015. "A numerical study on the effects of temperature and mass transfer in high temperature PEM fuel cells with ab-PBI membrane," Applied Energy, Elsevier, vol. 160(C), pages 937-944.
    11. Wu, Horng-Wen & Ho, Tzu-Yi & Han, Yueh-Jung, 2021. "Parametric optimization of wall-mounted cuboid rows installed in interdigitated flow channel of HT-PEM fuel cells," Energy, Elsevier, vol. 216(C).
    12. Andraž Kravos & Ambrož Kregar & Kurt Mayer & Viktor Hacker & Tomaž Katrašnik, 2021. "Identifiability Analysis of Degradation Model Parameters from Transient CO 2 Release in Low-Temperature PEM Fuel Cell under Various AST Protocols," Energies, MDPI, vol. 14(14), pages 1-16, July.
    13. Chen, Ben & Ke, Wandi & Luo, Maji & Wang, Jun & Tu, Zhengkai & Pan, Mu & Zhang, Haining & Liu, Xiaowei & Liu, Wei, 2015. "Operation characteristics and carbon corrosion of PEMFC (Proton exchange membrane fuel cell) with dead-ended anode for high hydrogen utilization," Energy, Elsevier, vol. 91(C), pages 799-806.
    14. Rahnavard, Aylin & Rowshanzamir, Soosan & Parnian, Mohammad Javad & Amirkhanlou, Gholam Reza, 2015. "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells," Energy, Elsevier, vol. 82(C), pages 746-757.
    15. Najafi, Behzad & Haghighat Mamaghani, Alireza & Rinaldi, Fabio & Casalegno, Andrea, 2015. "Long-term performance analysis of an HT-PEM fuel cell based micro-CHP system: Operational strategies," Applied Energy, Elsevier, vol. 147(C), pages 582-592.
    16. Richard Symes & Tchable-Nan Djaname & Michael Deligant & Emilie Sauret, 2021. "Design and Optimization of a Radial Inflow Turbine for Use with a Low Temperature ORC," Energies, MDPI, vol. 14(24), pages 1-16, December.
    17. Víctor Sanz i López & Ramon Costa-Castelló & Carles Batlle, 2022. "Literature Review of Energy Management in Combined Heat and Power Systems Based on High-Temperature Proton Exchange Membrane Fuel Cells for Residential Comfort Applications," Energies, MDPI, vol. 15(17), pages 1-22, September.
    18. Guan, Dong & Pan, Biyu & Chen, Zhen & Li, Jing & Shen, Hui & Pang, Huan, 2023. "Quantitative modeling and bio-inspired optimization the clamping load on the bipolar plate in PEMFC," Energy, Elsevier, vol. 263(PD).
    19. Mingzhang Pan & Chengjie Pan & Jinyang Liao & Chao Li & Rong Huang & Qiwei Wang, 2021. "Assessment of Sensitivity to Evaluate the Impact of Operating Parameters on Stability and Performance in Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 14(14), pages 1-23, July.
    20. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    21. Kim, Eunji & Song, Seunghwan & Choi, Seoeun & Park, Jung Ock & Kim, Junghwan & Kwon, Kyungjung, 2021. "Parameter analysis from the modeling of high temperature proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 301(C).
    22. El-Hay, Enas A. & El-Hameed, Mohamed A. & El-Fergany, Attia A., 2018. "Performance enhancement of autonomous system comprising proton exchange membrane fuel cells and switched reluctance motor," Energy, Elsevier, vol. 163(C), pages 699-711.
    23. Chen, Dongfang & Pei, Pucheng & Meng, Yining & Ren, Peng & Li, Yuehua & Wang, Mingkai & Wang, Xizhong, 2022. "Novel extraction method of working condition spectrum for the lifetime prediction and energy management strategy evaluation of automotive fuel cells," Energy, Elsevier, vol. 255(C).
    24. Authayanun, Suthida & Saebea, Dang & Patcharavorachot, Yaneeporn & Arpornwichanop, Amornchai, 2015. "Evaluation of an integrated methane autothermal reforming and high-temperature proton exchange membrane fuel cell system," Energy, Elsevier, vol. 80(C), pages 331-339.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Papurello, Davide & Lanzini, Andrea & Drago, Davide & Leone, Pierluigi & Santarelli, Massimo, 2016. "Limiting factors for planar solid oxide fuel cells under different trace compound concentrations," Energy, Elsevier, vol. 95(C), pages 67-78.
    2. Keramiotis, Ch. & Vourliotakis, G. & Skevis, G. & Founti, M.A. & Esarte, C. & Sánchez, N.E. & Millera, A. & Bilbao, R. & Alzueta, M.U., 2012. "Experimental and computational study of methane mixtures pyrolysis in a flow reactor under atmospheric pressure," Energy, Elsevier, vol. 43(1), pages 103-110.
    3. Stempien, Jan Pawel & Sun, Qiang & Chan, Siew Hwa, 2013. "Performance of power generation extension system based on solid-oxide electrolyzer cells under various design conditions," Energy, Elsevier, vol. 55(C), pages 647-657.
    4. Jiao, Yong & Zhang, Liqin & An, Wenting & Zhou, Wei & Sha, Yujing & Shao, Zongping & Bai, Jianping & Li, Si-Dian, 2016. "Controlled deposition and utilization of carbon on Ni-YSZ anodes of SOFCs operating on dry methane," Energy, Elsevier, vol. 113(C), pages 432-443.
    5. Lee, Won-Yong & Kim, Minjin & Sohn, Young-Jun & Kim, Seung-Gon, 2016. "Power optimization of a combined power system consisting of a high-temperature polymer electrolyte fuel cell and an organic Rankine cycle system," Energy, Elsevier, vol. 113(C), pages 1062-1070.
    6. Kong, Im Mo & Jung, Aeri & Kim, Young Sang & Kim, Min Soo, 2017. "Numerical investigation on double gas diffusion backing layer functionalized on water removal in a proton exchange membrane fuel cell," Energy, Elsevier, vol. 120(C), pages 478-487.
    7. Avasarala, Bharat & Haldar, Pradeep, 2013. "Durability and degradation mechanism of titanium nitride based electrocatalysts for PEM (proton exchange membrane) fuel cell applications," Energy, Elsevier, vol. 57(C), pages 545-553.
    8. Daria Kolbantseva & Dmitriy Treschev & Milana Trescheva & Irina Anikina & Yuriy Kolbantsev & Konstantin Kalmykov & Alena Aleshina & Aleksandr Kalyutik & Iaroslav Vladimirov, 2022. "Analysis of Technologies for Hydrogen Consumption, Transition and Storage at Operating Thermal Power Plants," Energies, MDPI, vol. 15(10), pages 1-30, May.
    9. Sun, Qie & Li, Hailong & Yan, Jinying & Liu, Longcheng & Yu, Zhixin & Yu, Xinhai, 2015. "Selection of appropriate biogas upgrading technology-a review of biogas cleaning, upgrading and utilisation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 521-532.
    10. Lee, Won-Yong & Kim, Minjin & Sohn, Young-Jun & Kim, Seung-Gon, 2017. "Performance of a hybrid system consisting of a high-temperature polymer electrolyte fuel cell and an absorption refrigerator," Energy, Elsevier, vol. 141(C), pages 2397-2407.
    11. Díaz, Manuel Antonio & Iranzo, Alfredo & Rosa, Felipe & Isorna, Fernando & López, Eduardo & Bolivar, Juan Pedro, 2015. "Effect of carbon dioxide on the contamination of low temperature and high temperature PEM (polymer electrolyte membrane) fuel cells. Influence of temperature, relative humidity and analysis of regener," Energy, Elsevier, vol. 90(P1), pages 299-309.
    12. Zhou, Juan & Liu, Qinglin & Zhang, Lan & Pan, Zehua & Chan, Siew Hwa, 2016. "Influence of pore former on electrochemical performance of fuel-electrode supported SOFCs manufactured by aqueous-based tape-casting," Energy, Elsevier, vol. 115(P1), pages 149-154.
    13. Roberto Schaeffer & Jeffrey Logan & Alexandre Szklo & William Chandler & João de Souza Marques, 2001. "Brazil's Electric Power Choices and Their Corresponding Carbon Emissions Implications," Mitigation and Adaptation Strategies for Global Change, Springer, vol. 6(1), pages 47-69, March.
    14. Sadhukhan, Jhuma & Lloyd, Jon R. & Scott, Keith & Premier, Giuliano C. & Yu, Eileen H. & Curtis, Tom & Head, Ian M., 2016. "A critical review of integration analysis of microbial electrosynthesis (MES) systems with waste biorefineries for the production of biofuel and chemical from reuse of CO2," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 116-132.
    15. Zhang, Houcheng & Lin, Guoxing & Chen, Jincan, 2011. "The performance analysis and multi-objective optimization of a typical alkaline fuel cell," Energy, Elsevier, vol. 36(7), pages 4327-4332.
    16. Papadias, Dionissios D. & Ahmed, Shabbir & Kumar, Romesh, 2012. "Fuel quality issues with biogas energy – An economic analysis for a stationary fuel cell system," Energy, Elsevier, vol. 44(1), pages 257-277.
    17. Ghosh, P.C. & Vasudeva, U., 2011. "Analysis of 3000T class submarines equipped with polymer electrolyte fuel cells," Energy, Elsevier, vol. 36(5), pages 3138-3147.
    18. Abed Alaswad & Abdelnasir Omran & Jose Ricardo Sodre & Tabbi Wilberforce & Gianmichelle Pignatelli & Michele Dassisti & Ahmad Baroutaji & Abdul Ghani Olabi, 2020. "Technical and Commercial Challenges of Proton-Exchange Membrane (PEM) Fuel Cells," Energies, MDPI, vol. 14(1), pages 1-21, December.
    19. Buonomano, Annamaria & Calise, Francesco & d’Accadia, Massimo Dentice & Palombo, Adolfo & Vicidomini, Maria, 2015. "Hybrid solid oxide fuel cells–gas turbine systems for combined heat and power: A review," Applied Energy, Elsevier, vol. 156(C), pages 32-85.
    20. Kong, Im Mo & Jung, Aeri & Kim, Min Soo, 2016. "Investigations on the double gas diffusion backing layer for performance improvement of self-humidified proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 176(C), pages 149-156.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:66:y:2014:i:c:p:41-49. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.