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Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel cell applications

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  • Parnian, Mohammad Javad
  • Rowshanzamir, Soosan
  • Gashoul, Fatemeh

Abstract

The investigation of the effect of various degrees of sulfonation (DS) is important for the selection and modification of hydrocarbon type membranes towards ion exchange applications. In this work, twelve kinds of sulfonated poly (ether ether ketone) membranes with different DS were prepared and their physicochemical and electrochemical properties were studied. The sulfonated polymers were prepared by sulfonation of PEEK and characterized by H NMR, FTIR, and XRD. Then, the different SPEEK membranes were prepared by the solvent casting method, and their morphology and homogeneity were investigated by FESEM. The effect of DS on the thermal (TGA and DSC), mechanical and oxidative stabilities, water uptake behavior, and ionic exchange capacity of the membranes was determined. Also, the proton conductivity of the membranes at different temperatures and relative humidities were measured. The results indicated that the SPEEK samples showed progressive deterioration of thermal stability, an increase of glass transition temperature, a decrease of the elastic modulus, and a decrease of the chemical stability with increasing of the DS. The proton conductivity of SPEEK membranes increased with DS, and for each membrane increased with increasing temperature and humidity. The results showed that moderate DS membranes (DS ∼ 65%) had acceptable mechanical, thermal, electrochemical, and chemical stability.

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  • Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    • Handle: RePEc:eee:energy:v:125:y:2017:i:c:p:614-628
    DOI: 10.1016/j.energy.2017.02.143
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    1. Thepkaew, Jarupuk & Therdthianwong, Apichai & Therdthianwong, Supaporn, 2008. "Key parameters of active layers affecting proton exchange membrane (PEM) fuel cell performance," Energy, Elsevier, vol. 33(12), pages 1794-1800.
    2. Yang, H.N. & Lee, D.C. & Park, K.W. & Kim, W.J., 2015. "Platinum–boron doped graphene intercalated by carbon black for cathode catalyst in proton exchange membrane fuel cell," Energy, Elsevier, vol. 89(C), pages 500-510.
    3. Rahnavard, Aylin & Rowshanzamir, Soosan & Parnian, Mohammad Javad & Amirkhanlou, Gholam Reza, 2015. "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells," Energy, Elsevier, vol. 82(C), pages 746-757.
    4. Ayyaru, Sivasankaran & Dharmalingam, Sangeetha, 2015. "A study of influence on nanocomposite membrane of sulfonated TiO2 and sulfonated polystyrene-ethylene-butylene-polystyrene for microbial fuel cell application," Energy, Elsevier, vol. 88(C), pages 202-208.
    5. Lakshminarayana, G. & Nogami, Masayuki & Kityk, I.V., 2010. "Synthesis and characterization of anhydrous proton conducting inorganic–organic composite membranes for medium temperature proton exchange membrane fuel cells (PEMFCs)," Energy, Elsevier, vol. 35(12), pages 5260-5268.
    6. Kim, Jintae & Kim, Minjin & Kang, Taegon & Sohn, Young-Jun & Song, Taewon & Choi, Kyoung Hwan, 2014. "Degradation modeling and operational optimization for improving the lifetime of high-temperature PEM (proton exchange membrane) fuel cells," Energy, Elsevier, vol. 66(C), pages 41-49.
    7. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
    8. Deng, Huichao & Zhang, Yufeng & Zheng, Xue & Li, Yang & Zhang, Xuelin & Liu, Xiaowei, 2015. "A CNT (carbon nanotube) paper as cathode gas diffusion electrode for water management of passive μ-DMFC (micro-direct methanol fuel cell) with highly concentrated methanol," Energy, Elsevier, vol. 82(C), pages 236-241.
    9. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of physicochemical characterization of potassium-doped Nafion117 membrane and performance evaluation of air-breathing fuel cell in different alkali-methanol solutions," Energy, Elsevier, vol. 113(C), pages 1090-1098.
    10. Brian C. H. Steele & Angelika Heinzel, 2001. "Materials for fuel-cell technologies," Nature, Nature, vol. 414(6861), pages 345-352, November.
    11. Beltrán-Gastélum, M. & Salazar-Gastélum, M.I. & Félix-Navarro, R.M. & Pérez-Sicairos, S. & Reynoso-Soto, E.A. & Lin, S.W. & Flores-Hernández, J.R. & Romero-Castañón, T. & Albarrán-Sánchez, I.L. & Para, 2016. "Evaluation of PtAu/MWCNT (Multiwalled Carbon Nanotubes) electrocatalyst performance as cathode of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 109(C), pages 446-455.
    12. Nikouei, Mohammad Ali & Oroujzadeh, Maryam & Mehdipour-Ataei, Shahram, 2017. "The PROMETHEE multiple criteria decision making analysis for selecting the best membrane prepared from sulfonated poly(ether ketone)s and poly(ether sulfone)s for proton exchange membrane fuel cell," Energy, Elsevier, vol. 119(C), pages 77-85.
    13. Rakhshanpouri, S. & Rowshanzamir, S., 2013. "Water transport through a PEM (proton exchange membrane) fuel cell in a seven-layer model," Energy, Elsevier, vol. 50(C), pages 220-231.
    14. Okur, Osman & İyigün Karadağ, Çiğdem & Boyacı San, Fatma Gül & Okumuş, Emin & Behmenyar, Gamze, 2013. "Optimization of parameters for hot-pressing manufacture of membrane electrode assembly for PEM (polymer electrolyte membrane fuel cells) fuel cell," Energy, Elsevier, vol. 57(C), pages 574-580.
    15. Carton, J.G. & Olabi, A.G., 2010. "Design of experiment study of the parameters that affect performance of three flow plate configurations of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 35(7), pages 2796-2806.
    16. Elden, Gülşah & Çelik, Muhammet & Genç, Gamze & Yapıcı, Hüseyin, 2016. "The effects of temperature on transport phenomena in phosphoric acid doped polybenzimidazole polymer electrolyte membrane fuel cell," Energy, Elsevier, vol. 103(C), pages 772-783.
    17. Döner, Ali & Solmaz, Ramazan & Kardaş, Gülfeza, 2015. "Fabrication and characterization of alkaline leached CuZn/Cu electrode as anode material for direct methanol fuel cell," Energy, Elsevier, vol. 90(P1), pages 1144-1151.
    18. Therdthianwong, Apichai & Manomayidthikarn, Phochan & Therdthianwong, Supaporn, 2007. "Investigation of membrane electrode assembly (MEA) hot-pressing parameters for proton exchange membrane fuel cell," Energy, Elsevier, vol. 32(12), pages 2401-2411.
    19. Zhiani, Mohammad & Majidi, Somayeh & Silva, Valter Bruno & Gharibi, Hussein, 2016. "Comparison of the performance and EIS (electrochemical impedance spectroscopy) response of an activated PEMFC (proton exchange membrane fuel cell) under low and high thermal and pressure stresses," Energy, Elsevier, vol. 97(C), pages 560-567.
    20. Yang, H.N. & Lee, W.H. & Choi, B.S. & Ko, Y.D. & Yi, S.C. & Kim, W.J., 2017. "Self-humidifying Pt-C/Pt-TiO2 dual-catalyst electrode membrane assembly for proton-exchange membrane fuel cells," Energy, Elsevier, vol. 120(C), pages 12-19.
    21. Lee, Chi-Hung & Chen, Szu-Hsien & Wang, Yen-Zen & Lin, Chao-Chien & Huang, Chih-Kai & Chuang, Ching-Nan & Wang, Chih-Kuang & Hsieh, Kuo-Huang, 2013. "Preparation and characterization of proton exchange membranes based on semi-interpenetrating sulfonated poly(imide-siloxane)/epoxy polymer networks," Energy, Elsevier, vol. 55(C), pages 905-915.
    22. Bhavani, Perumal & Sangeetha, Dharmalingam, 2011. "Preparation and characterization of proton exchange membrane based on SPSEBS/PSU blends for fuel cell applications," Energy, Elsevier, vol. 36(5), pages 3360-3369.
    23. Ghasemi, Mostafa & Wan Daud, Wan Ramli & Alam, Javed & Ilbeygi, Hamid & Sedighi, Mehdi & Ismail, Ahmad Fauzi & Yazdi, Mohammad H. & Aljlil, Saad A., 2016. "Treatment of two different water resources in desalination and microbial fuel cell processes by poly sulfone/Sulfonated poly ether ether ketone hybrid membrane," Energy, Elsevier, vol. 96(C), pages 303-313.
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    2. Yousefi Tehrani, Mehran & Mirfarsi, Seyed Hesam & Rowshanzamir, Soosan, 2022. "Mechanical stress and strain investigation of sulfonated Poly(ether ether ketone) proton exchange membrane in fuel cells: A numerical study," Renewable Energy, Elsevier, vol. 184(C), pages 182-200.
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    5. Alipour Moghaddam, Jafar & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2018. "Preparation, characterization, and electrochemical properties investigation of recycled proton exchange membrane for fuel cell applications," Energy, Elsevier, vol. 161(C), pages 699-709.

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