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Estimating the energy density of direct borohydride–hydrogen peroxide fuel cell systems for air-independent propulsion applications

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  • Oh, Taek Hyun
  • Jang, Bosun
  • Kwon, Sejin

Abstract

The energy density of DBPFCs (direct borohydride–hydrogen peroxide fuel cells) is estimated for air-independent propulsion applications. The performance of DBPFCs containing heat-treated electrocatalysts supported on multiwalled carbon nanotubes is evaluated. The open circuit voltage and the maximum power density are 1.44 V and 243 mW/cm2, respectively, whereas the voltage efficiency is 17.9% at the maximum power density. Based on experimental results, the energy density is estimated to be 63.2 Wh/kg (87.1 Wh/L), which is much lower than those of other power sources. The degree of influence of various parameters on the energy density is ranked in the following order: fuel utilization efficiency > voltage efficiency > H2O2 (hydrogen peroxide) concentration > NaBH4 (sodium borohydride) concentration > maximum power density. Performance targets comprising of fuel utilization efficiency of 90%, voltage efficiency of 40%, H2O2 concentration of 50 wt%, NaBH4 concentration of 20 wt%, and maximum power density of 650 mW/cm2, have been determined. Under these conditions, the energy density and fuel volume are expected to be 378.5 Wh/kg (541.4 Wh/L) and 1.57 L, respectively, which would allow them to be used widely as power sources for air-independent propulsion.

Suggested Citation

  • Oh, Taek Hyun & Jang, Bosun & Kwon, Sejin, 2015. "Estimating the energy density of direct borohydride–hydrogen peroxide fuel cell systems for air-independent propulsion applications," Energy, Elsevier, vol. 90(P1), pages 980-986.
    • Handle: RePEc:eee:energy:v:90:y:2015:i:p1:p:980-986
    DOI: 10.1016/j.energy.2015.08.002
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    References listed on IDEAS

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    Cited by:

    1. Oh, Taek Hyun, 2021. "Effect of cathode conditions on performance of direct borohydride–hydrogen peroxide fuel cell system for space exploration," Renewable Energy, Elsevier, vol. 178(C), pages 1156-1164.
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    3. Uzundurukan, Arife & Akça, Elif Seda & Budak, Yağmur & Devrim, Yılser, 2021. "Carbon nanotube-graphene supported bimetallic electrocatalyst for direct borohydride hydrogen peroxide fuel cells," Renewable Energy, Elsevier, vol. 172(C), pages 1351-1364.
    4. Stoševski, Ivan & Krstić, Jelena & Milikić, Jadranka & Šljukić, Biljana & Kačarević-Popović, Zorica & Mentus, Slavko & Miljanić, Šćepan, 2016. "Radiolitically synthesized nano Ag/C catalysts for oxygen reduction and borohydride oxidation reactions in alkaline media, for potential applications in fuel cells," Energy, Elsevier, vol. 101(C), pages 79-90.

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