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Study of physicochemical characterization of potassium-doped Nafion117 membrane and performance evaluation of air-breathing fuel cell in different alkali-methanol solutions

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  • Alipour Najmi, Ali
  • Rowshanzamir, Soosan
  • Parnian, Mohammad Javad

Abstract

Direct methanol alkaline fuel cell (DMAFC) using a cation exchange membrane (CEM) was operated in passive condition and compared to passive direct methanol fuel cell (DMFC). A polymer electrolyte membrane for passive DMAFC was prepared by immersing Nafion117 membrane into KOH solution at temperature of 80 °C. The prepared membrane (potassium-doped Nafion117) exhibited higher mechanical properties and thermal stability than Nafion117. Ionic conductivity of K+ form Nafion117 membrane was measured to be lower than that for pristine Nafion117. Single cell in alkaline condition (passive DMAFC) exhibited better cell performance than that in the cell using Nafion117 in acidic condition (passive DMFC). The open circuit voltage (OCV) of passive DMAFC reached to about 1 V which was considerably higher than that for passive DMFC (0.45 V). The methanol crossover rate through membranes was also measured and the results implied that the potassium-doped Nafion117 membrane had lower permeability to methanol.

Suggested Citation

  • Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of physicochemical characterization of potassium-doped Nafion117 membrane and performance evaluation of air-breathing fuel cell in different alkali-methanol solutions," Energy, Elsevier, vol. 113(C), pages 1090-1098.
    • Handle: RePEc:eee:energy:v:113:y:2016:i:c:p:1090-1098
    DOI: 10.1016/j.energy.2016.07.134
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    References listed on IDEAS

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    1. Yuan, Wei & Deng, Jun & Zhang, Zhaochun & Yang, Xiaojun & Tang, Yong, 2014. "Study on operational aspects of a passive direct methanol fuel cell incorporating an anodic methanol barrier," Renewable Energy, Elsevier, vol. 62(C), pages 640-648.
    2. Achmad, F. & Kamarudin, S.K. & Daud, W.R.W. & Majlan, E.H., 2011. "Passive direct methanol fuel cells for portable electronic devices," Applied Energy, Elsevier, vol. 88(5), pages 1681-1689, May.
    3. Carton, J.G. & Olabi, A.G., 2010. "Design of experiment study of the parameters that affect performance of three flow plate configurations of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 35(7), pages 2796-2806.
    4. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Investigation of NaOH concentration effect in injected fuel on the performance of passive direct methanol alkaline fuel cell with modified cation exchange membrane," Energy, Elsevier, vol. 94(C), pages 589-599.
    5. Döner, Ali & Solmaz, Ramazan & Kardaş, Gülfeza, 2015. "Fabrication and characterization of alkaline leached CuZn/Cu electrode as anode material for direct methanol fuel cell," Energy, Elsevier, vol. 90(P1), pages 1144-1151.
    6. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
    7. Deng, Huichao & Zhang, Yufeng & Zheng, Xue & Li, Yang & Zhang, Xuelin & Liu, Xiaowei, 2015. "A CNT (carbon nanotube) paper as cathode gas diffusion electrode for water management of passive μ-DMFC (micro-direct methanol fuel cell) with highly concentrated methanol," Energy, Elsevier, vol. 82(C), pages 236-241.
    8. Deng, Huichao & Zhang, Xuelin & Ma, Zezhong & Chen, Hailong & Sun, Qiu & Zhang, Yufeng & Liu, Xiaowei, 2014. "A micro passive direct methanol fuel cell with high performance via plasma electrolytic oxidation on aluminum-based substrate," Energy, Elsevier, vol. 78(C), pages 149-153.
    9. Wang, Luwen & He, Mingyan & Hu, Yue & Zhang, Yufeng & Liu, Xiaowei & Wang, Gaofeng, 2015. "A “4-cell” modular passive DMFC (direct methanol fuel cell) stack for portable applications," Energy, Elsevier, vol. 82(C), pages 229-235.
    10. Iranzo, Alfredo & Boillat, Pierre & Oberholzer, Pierre & Guerra, José, 2014. "A novel approach coupling neutron imaging and numerical modelling for the analysis of the impact of water on fuel cell performance," Energy, Elsevier, vol. 68(C), pages 971-981.
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    Cited by:

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    2. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    3. Hosseini, Mir Ghasem & Mahmoodi, Raana & Daneshvari-Esfahlan, Vahid, 2018. "Ni@Pd core-shell nanostructure supported on multi-walled carbon nanotubes as efficient anode nanocatalysts for direct methanol fuel cells with membrane electrode assembly prepared by catalyst coated m," Energy, Elsevier, vol. 161(C), pages 1074-1084.
    4. Alipour Moghaddam, Jafar & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2018. "Preparation, characterization, and electrochemical properties investigation of recycled proton exchange membrane for fuel cell applications," Energy, Elsevier, vol. 161(C), pages 699-709.

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