IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v161y2018icp1074-1084.html
   My bibliography  Save this article

Ni@Pd core-shell nanostructure supported on multi-walled carbon nanotubes as efficient anode nanocatalysts for direct methanol fuel cells with membrane electrode assembly prepared by catalyst coated membrane method

Author

Listed:
  • Hosseini, Mir Ghasem
  • Mahmoodi, Raana
  • Daneshvari-Esfahlan, Vahid

Abstract

Multi-walled carbon nanotubes supported Ni@Pd core-shell nanoparticles (Ni@Pd/MWCNTs) are successfully synthesized by two-step reduction procedure. The Ni@Pd/MWCNTs electrocatalysts are characterized by using field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, high resolution transmission electron microscopy and X-ray photoelectron spectroscopy. According to characterization results, nanoparticles (5–10 nm) are spread on carbon support uniformly with high porosity. Moreover, the electrocatalytic performance of Ni@Pd/CNTs towards methanol electro-oxidation are evaluated using cyclic voltammetry, electrochemical impedance spectroscopy, chronoamperometry and chronopotentiometry methods in a conventional three-electrode cell. The results show that Ni@Pd/MWCNTs electrocatalysts have a good catalytic activity towards methanol oxidation in alkaline solutions. The performance of direct methanol fuel cell (DMFC) is evaluated in a single fuel cell set-up. The Membrane Electrode Assembly used in fuel cell set-up is prepared by catalyst-coated membrane technique. The catalyst loading is fixed at 0.5 mg Pt/C cm−2 for the cathode and 1.0 mg Ni@Pd/MWCNTs cm−2 for the anode. The used anolyte and catholyte are NaOH + CH3OH and H2SO4 + H2O2, respectively. The results exhibit that the maximum power density is about 67 mW cm−2 at 60 °C. The present paper clearly demonstrates the possibility of Ni@Pd/MWCNTs nanostructure as good performance and less expensive anode catalyst for DMFCs.

Suggested Citation

  • Hosseini, Mir Ghasem & Mahmoodi, Raana & Daneshvari-Esfahlan, Vahid, 2018. "Ni@Pd core-shell nanostructure supported on multi-walled carbon nanotubes as efficient anode nanocatalysts for direct methanol fuel cells with membrane electrode assembly prepared by catalyst coated m," Energy, Elsevier, vol. 161(C), pages 1074-1084.
    • Handle: RePEc:eee:energy:v:161:y:2018:i:c:p:1074-1084
    DOI: 10.1016/j.energy.2018.07.148
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218314488
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.07.148?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yeh, Pulin & Chang, Chu Hsiang & Shih, Naichien & Yeh, Naichia, 2016. "Durability and efficiency tests for direct methanol fuel cell's long-term performance assessment," Energy, Elsevier, vol. 107(C), pages 716-724.
    2. Wang, Junye, 2015. "Barriers of scaling-up fuel cells: Cost, durability and reliability," Energy, Elsevier, vol. 80(C), pages 509-521.
    3. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Investigation of NaOH concentration effect in injected fuel on the performance of passive direct methanol alkaline fuel cell with modified cation exchange membrane," Energy, Elsevier, vol. 94(C), pages 589-599.
    4. An, L. & Zhao, T.S. & Li, Y.S., 2015. "Carbon-neutral sustainable energy technology: Direct ethanol fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1462-1468.
    5. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of physicochemical characterization of potassium-doped Nafion117 membrane and performance evaluation of air-breathing fuel cell in different alkali-methanol solutions," Energy, Elsevier, vol. 113(C), pages 1090-1098.
    6. Hosseini, M.G. & Mahmoodi, R. & Sadeghi Amjadi, M., 2017. "Carbon supported Ni1Pt1 nanocatalyst as superior electrocatalyst with increased power density in direct borohydride-hydrogen peroxide and investigation of cell impedance at different temperatures and ," Energy, Elsevier, vol. 131(C), pages 137-148.
    7. Oliveira, V.B. & Pereira, J.P. & Pinto, A.M.F.R., 2017. "Modeling of passive direct ethanol fuel cells," Energy, Elsevier, vol. 133(C), pages 652-665.
    8. Kwok, Y.H. & Wang, Y.F. & Tsang, Alpha C.H. & Leung, Dennis Y.C., 2018. "Graphene-carbon nanotube composite aerogel with Ru@Pt nanoparticle as a porous electrode for direct methanol microfluidic fuel cell," Applied Energy, Elsevier, vol. 217(C), pages 258-265.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Weng, Guo-Ming & Li, Chi-Ying Vanessa & Chan, Kwong-Yu, 2019. "Three-electrolyte electrochemical energy storage systems using both anion- and cation-exchange membranes as separators," Energy, Elsevier, vol. 167(C), pages 1011-1018.
    2. Fang, Shuo & Liu, Yuntao & Zhao, Chunhui & Huang, Lilian & Zhong, Zhi & Wang, Yun, 2021. "Polarization analysis of a micro direct methanol fuel cell stack based on Debye-Hückel ionic atmosphere theory," Energy, Elsevier, vol. 222(C).
    3. Yang, Chii-Rong & Lu, Chang-Wei & Fu, Pin-Chi & Cheng, Chia & Chiou, Yuang-Cherng & Lee, Rong-Tsong & Tseng, Shih-Feng, 2020. "Performance evaluation of μDMFCs based on porous-silicon electrodes and methanol modification," Energy, Elsevier, vol. 192(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yu, Bor-Chern & Wang, Yi-Chun & Lu, Hsin-Chun & Lin, Hsiu-Li & Shih, Chao-Ming & Kumar, S. Rajesh & Lue, Shingjiang Jessie, 2017. "Hydroxide-ion selective electrolytes based on a polybenzimidazole/graphene oxide composite membrane," Energy, Elsevier, vol. 134(C), pages 802-812.
    2. Prapainainar, Paweena & Du, Zehui & Theampetch, Apichaya & Prapainainar, Chaiwat & Kongkachuichay, Paisan & Holmes, Stuart M., 2020. "Properties and DMFC performance of nafion/mordenite composite membrane fabricated by solution-casting method with different solvent ratio," Energy, Elsevier, vol. 190(C).
    3. Sánchez-Monreal, Juan & García-Salaberri, Pablo A. & Vera, Marcos, 2019. "A mathematical model for direct ethanol fuel cells based on detailed ethanol electro-oxidation kinetics," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    4. Mohammed, Hanin & Al-Othman, Amani & Nancarrow, Paul & Tawalbeh, Muhammad & El Haj Assad, Mamdouh, 2019. "Direct hydrocarbon fuel cells: A promising technology for improving energy efficiency," Energy, Elsevier, vol. 172(C), pages 207-219.
    5. Benipal, Neeva & Qi, Ji & Gentile, Jacob C. & Li, Wenzhen, 2017. "Direct glycerol fuel cell with polytetrafluoroethylene (PTFE) thin film separator," Renewable Energy, Elsevier, vol. 105(C), pages 647-655.
    6. Wang, Junye, 2017. "System integration, durability and reliability of fuel cells: Challenges and solutions," Applied Energy, Elsevier, vol. 189(C), pages 460-479.
    7. Alipour Moghaddam, Jafar & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2018. "Preparation, characterization, and electrochemical properties investigation of recycled proton exchange membrane for fuel cell applications," Energy, Elsevier, vol. 161(C), pages 699-709.
    8. Du, Jiuyu & Ouyang, Danhua, 2017. "Progress of Chinese electric vehicles industrialization in 2015: A review," Applied Energy, Elsevier, vol. 188(C), pages 529-546.
    9. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    10. Alves, Luís & Pereira, Vítor & Lagarteira, Tiago & Mendes, Adélio, 2021. "Catalytic methane decomposition to boost the energy transition: Scientific and technological advancements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    11. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    12. Ruffini, Eleonora & Wei, Max, 2018. "Future costs of fuel cell electric vehicles in California using a learning rate approach," Energy, Elsevier, vol. 150(C), pages 329-341.
    13. Najmi, Aezid-Ul-Hassan & Anyanwu, Ikechukwu S. & Xie, Xu & Liu, Zhi & Jiao, Kui, 2021. "Experimental investigation and optimization of proton exchange membrane fuel cell using different flow fields," Energy, Elsevier, vol. 217(C).
    14. Wang, Yifei & Luo, Shijing & Kwok, Holly Y.H. & Pan, Wending & Zhang, Yingguang & Zhao, Xiaolong & Leung, Dennis Y.C., 2021. "Microfluidic fuel cells with different types of fuels: A prospective review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    15. Wang, Junye, 2015. "Theory and practice of flow field designs for fuel cell scaling-up: A critical review," Applied Energy, Elsevier, vol. 157(C), pages 640-663.
    16. Mendiburu, Andrés Z. & Lauermann, Carlos H. & Hayashi, Thamy C. & Mariños, Diego J. & Rodrigues da Costa, Roberto Berlini & Coronado, Christian J.R. & Roberts, Justo J. & de Carvalho, João A., 2022. "Ethanol as a renewable biofuel: Combustion characteristics and application in engines," Energy, Elsevier, vol. 257(C).
    17. Ji, Zhaoqi & Perez-Page, Maria & Chen, Jianuo & Rodriguez, Romeo Gonzalez & Cai, Rongsheng & Haigh, Sarah J. & Holmes, Stuart M., 2021. "A structured catalyst support combining electrochemically exfoliated graphene oxide and carbon black for enhanced performance and durability in low-temperature hydrogen fuel cells," Energy, Elsevier, vol. 226(C).
    18. Xing, Lei & Du, Shangfeng & Chen, Rui & Mamlouk, Mohamed & Scott, Keith, 2016. "Anode partial flooding modelling of proton exchange membrane fuel cells: Model development and validation," Energy, Elsevier, vol. 96(C), pages 80-95.
    19. Olabi, A.G. & Wilberforce, Tabbi & Abdelkareem, Mohammad Ali, 2021. "Fuel cell application in the automotive industry and future perspective," Energy, Elsevier, vol. 214(C).
    20. Michaela Roschger & Sigrid Wolf & Boštjan Genorio & Viktor Hacker, 2022. "Effect of PdNiBi Metal Content: Cost Reduction in Alkaline Direct Ethanol Fuel Cells," Sustainability, MDPI, vol. 14(22), pages 1-15, November.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:161:y:2018:i:c:p:1074-1084. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.