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A structured catalyst support combining electrochemically exfoliated graphene oxide and carbon black for enhanced performance and durability in low-temperature hydrogen fuel cells

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  • Ji, Zhaoqi
  • Perez-Page, Maria
  • Chen, Jianuo
  • Rodriguez, Romeo Gonzalez
  • Cai, Rongsheng
  • Haigh, Sarah J.
  • Holmes, Stuart M.

Abstract

Reduced electrochemically exfoliated graphene oxide (rEGO) is combined with carbon black (CB) as a hybrid support material to improve platinum (Pt) catalyst electrochemical activity and durability. Pt/rEGO2-CB3 (rEGO/CB ratio 2/3) retains 71% of initial electrochemical surface area (ECSA) and maintains higher oxygen reduction reaction (ORR) activity compared to Pt/CB after 30000 cycles of the accelerated stress test (AST). In addition, Pt/rEGO2-CB3 shows a 1.8 times improvement in the hydrogen fuel cell performance compared with Pt/CB and is more stable after 24 h at a continuous 0.60 V. The Pt/rEGO2-CB3 promotes the 4e− reaction pathway demonstrated by linear sweep voltammetry (LSV), which leads to greater ORR activity. In addition, the combination of rEGO and CB leads to both enhanced transport properties and improved stability. The Pt particles on both CB and rEGO are less likely to agglomerate in the composite support than in either of the two carbon supports when used alone.

Suggested Citation

  • Ji, Zhaoqi & Perez-Page, Maria & Chen, Jianuo & Rodriguez, Romeo Gonzalez & Cai, Rongsheng & Haigh, Sarah J. & Holmes, Stuart M., 2021. "A structured catalyst support combining electrochemically exfoliated graphene oxide and carbon black for enhanced performance and durability in low-temperature hydrogen fuel cells," Energy, Elsevier, vol. 226(C).
    • Handle: RePEc:eee:energy:v:226:y:2021:i:c:s0360544221005673
    DOI: 10.1016/j.energy.2021.120318
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    Cited by:

    1. Wilberforce, Tabbi & Abdelkareem, Mohammad Ali & Elsaid, Khaled & Olabi, A.G. & Sayed, Enas Taha, 2022. "Role of carbon-based nanomaterials in improving the performance of microbial fuel cells," Energy, Elsevier, vol. 240(C).
    2. Jaimes-Paez, C.D. & Morallón, E. & Cazorla-Amorós, D., 2023. "Few layers graphene-based electrocatalysts for ORR synthesized by electrochemical exfoliation methods," Energy, Elsevier, vol. 278(PA).
    3. Han, Yuan & Lai, Cong & Li, Jiarui & Zhang, Zhufeng & Zhang, Houcheng & Hou, Shujin & Wang, Fu & Zhao, Jiapei & Zhang, Chunfei & Miao, He & Yuan, Jinliang, 2022. "Elastocaloric cooler for waste heat recovery from proton exchange membrane fuel cells," Energy, Elsevier, vol. 238(PA).
    4. Eugenio Meloni & Giuseppina Iervolino & Concetta Ruocco & Simona Renda & Giovanni Festa & Marco Martino & Vincenzo Palma, 2022. "Electrified Hydrogen Production from Methane for PEM Fuel Cells Feeding: A Review," Energies, MDPI, vol. 15(10), pages 1-34, May.

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