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Efficiency of the sulfur–iodine thermochemical water splitting process for hydrogen production based on ADS (accelerator driven system)

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  • García, Lázaro
  • González, Daniel
  • García, Carlos
  • García, Laura
  • Brayner, Carlos

Abstract

The current hydrogen production is based on fossil fuels; they have a huge contribution to the atmosphere's pollution. Thermochemical water splitting cycles don't present this issue because the required process heat is obtained from nuclear energy and therefore, the environmental impact is smaller than using conventional fuels. Although, solar hydrogen production could be also used for practical applications because it's lower environmental impact. One of the promising approaches to produce large quantities of hydrogen in an efficient way using nuclear energy is the sulfur–iodine (S–I) thermochemical water splitting cycle. The nuclear source proposed in this paper is a pebble bed gas cooled transmutation facility. Pebble bed very high temperature advanced systems have great perspectives to assume the future nuclear energy. Softwares based on CPS (chemical process simulation) can be used to simulate the thermochemical water splitting sulfur-iodine cycle for hydrogen production. In this paper, a model for analyzing the sulfur-iodine process sensibility respect to the thermodynamics parameters: temperature, pressure and mass flow is developed. Efficiency is also calculated and the influence of different parameters on this value. The behavior of the proposed model for different values of initial reactant's flow, is analyzed.

Suggested Citation

  • García, Lázaro & González, Daniel & García, Carlos & García, Laura & Brayner, Carlos, 2013. "Efficiency of the sulfur–iodine thermochemical water splitting process for hydrogen production based on ADS (accelerator driven system)," Energy, Elsevier, vol. 57(C), pages 469-477.
    • Handle: RePEc:eee:energy:v:57:y:2013:i:c:p:469-477
    DOI: 10.1016/j.energy.2013.05.042
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    References listed on IDEAS

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    1. Jarosław Gryz & Krzysztof Król & Anna Witkowska & Mariusz Ruszel, 2021. "Mobile Nuclear-Hydrogen Synergy in NATO Operations," Energies, MDPI, vol. 14(23), pages 1-12, November.
    2. Yilmaz, Fatih & Selbaş, Reşat, 2017. "Thermodynamic performance assessment of solar based Sulfur-Iodine thermochemical cycle for hydrogen generation," Energy, Elsevier, vol. 140(P1), pages 520-529.
    3. González Rodríguez, Daniel & Brayner de Oliveira Lira, Carlos Alberto & García Parra, Lázaro Roger & García Hernández, Carlos Rafael & de la Torre Valdés, Raciel, 2018. "Computational model of a sulfur-iodine thermochemical water splitting system coupled to a VHTR for nuclear hydrogen production," Energy, Elsevier, vol. 147(C), pages 1165-1176.

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