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Fabrication and experimental validation of a full-scale depleted uranium bed with thin double-layered annulus configuration for hydrogen isotopes recovery and delivery

Author

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  • Kou, Huaqin
  • Luo, Wenhua
  • Huang, Zhiyong
  • Sang, Ge
  • Meng, Daqiao
  • Zhang, Guanghui
  • Chen, Changan
  • Luo, Deli
  • Hu, Changwen

Abstract

Metal hydride beds play an important role in the application of hydrogen-related energy. In the present work, a full-scale DU (depleted uranium) bed with the newly proposed bed design of thin double-layered annulus configuration was fabricated for hydrogen isotopes recovery and delivery. The hydrogen recovery/delivery properties and the thermal effect of the fabricated bed were experimentally investigated. It was found that the fabricated bed was able to achieve the hydrogen storage target of 17.5 mol H2 with a fast hydrogen recovery rate. Not only hydrogen delivery amount as high as 16.5 mol (∼94% of recovery amount) but also an average delivery rate of 20 Pa m3/s could be obtained at 450 °C, even though the hydrogen delivery time of the bed reached as long as 30.9 min. The fabricated DU bed also exhibited outstanding cyclic hydrogen recovery/delivery performances. Deterioration in both hydrogen recovery/delivery amount and rate was not observed even up to 10 cycles. Besides, it was shown that utilization of the water cooling loops drilled in the DU bed was beneficial to enhance the heat transfer and promote the hydrogen recovery process of the bed. Meanwhile, the internal structure of the fabricated bed was observed by ICT (industrial computed tomography). And the ICT results demonstrated that DU expanded seriously after hydrogen recovery/delivery cycles, resulting in the deformation of the filters in the bed. The experimental results suggested that the fabricated DU bed was technically feasible to be applied for hydrogen isotopes recovery and delivery in the International Thermonuclear Experimental Reactor.

Suggested Citation

  • Kou, Huaqin & Luo, Wenhua & Huang, Zhiyong & Sang, Ge & Meng, Daqiao & Zhang, Guanghui & Chen, Changan & Luo, Deli & Hu, Changwen, 2015. "Fabrication and experimental validation of a full-scale depleted uranium bed with thin double-layered annulus configuration for hydrogen isotopes recovery and delivery," Energy, Elsevier, vol. 90(P1), pages 588-594.
    • Handle: RePEc:eee:energy:v:90:y:2015:i:p1:p:588-594
    DOI: 10.1016/j.energy.2015.07.097
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    as
    1. Chung, Kyong-Hwan, 2010. "High-pressure hydrogen storage on microporous zeolites with varying pore properties," Energy, Elsevier, vol. 35(5), pages 2235-2241.
    2. Ding, Xiangqian & Zhu, Yunfeng & Wei, Lingjun & Li, Ying & Li, Liquan, 2013. "Synergistic hydrogen desorption of HCS MgH2 + LiAlH4 composite," Energy, Elsevier, vol. 55(C), pages 933-938.
    3. Kikkinides, Eustathios S. & Georgiadis, Michael C. & Stubos, Athanasios K., 2006. "Dynamic modelling and optimization of hydrogen storage in metal hydride beds," Energy, Elsevier, vol. 31(13), pages 2428-2446.
    4. Aadmi, Moussa & Karkri, Mustapha & El Hammouti, Mimoun, 2015. "Heat transfer characteristics of thermal energy storage for PCM (phase change material) melting in horizontal tube: Numerical and experimental investigations," Energy, Elsevier, vol. 85(C), pages 339-352.
    5. Neef, H.-J., 2009. "International overview of hydrogen and fuel cell research," Energy, Elsevier, vol. 34(3), pages 327-333.
    6. Komiyama, Ryoichi & Otsuki, Takashi & Fujii, Yasumasa, 2015. "Energy modeling and analysis for optimal grid integration of large-scale variable renewables using hydrogen storage in Japan," Energy, Elsevier, vol. 81(C), pages 537-555.
    7. Pedicini, R. & Schiavo, B. & Rispoli, P. & Saccà, A. & Carbone, A. & Gatto, I. & Passalacqua, E., 2014. "Progress in polymeric material for hydrogen storage application in middle conditions," Energy, Elsevier, vol. 64(C), pages 607-614.
    8. Baker, Charles C. & Conn, Robert W. & Najmabadi, Farrokh & Tillack, Mark S., 1998. "Status and prospects for fusion energy from magnetically confined plasmas," Energy, Elsevier, vol. 23(7), pages 649-694.
    9. Fan, Mei-Qiang & Liu, Shu-sheng & Zhang, Yao & Zhang, Jian & Sun, Li-Xian & Xu, Fen, 2010. "Superior hydrogen storage properties of MgH2–10 wt.% TiC composite," Energy, Elsevier, vol. 35(8), pages 3417-3421.
    10. Pukazhselvan, D. & Hudson, M. Sterlin Leo & Sinha, A.S.K. & Srivastava, O.N., 2010. "Studies on metal oxide nanoparticles catalyzed sodium aluminum hydride," Energy, Elsevier, vol. 35(12), pages 5037-5042.
    11. Avril, S. & Arnaud, G. & Florentin, A. & Vinard, M., 2010. "Multi-objective optimization of batteries and hydrogen storage technologies for remote photovoltaic systems," Energy, Elsevier, vol. 35(12), pages 5300-5308.
    12. Chung, C.A. & Yang, Su-Wen & Yang, Chien-Yuh & Hsu, Che-Weu & Chiu, Pai-Yuh, 2013. "Experimental study on the hydrogen charge and discharge rates of metal hydride tanks using heat pipes to enhance heat transfer," Applied Energy, Elsevier, vol. 103(C), pages 581-587.
    13. Kumar, Sanjay & Tiwari, G.P. & Sonak, Sagar & Jain, Uttam & Krishnamurthy, Nagaiyar, 2014. "High performance FeTi – 3.1 mass % V alloy for on board hydrogen storage solution," Energy, Elsevier, vol. 75(C), pages 520-524.
    14. Zarrella, Angelo & Capozza, Antonio & De Carli, Michele, 2013. "Analysis of short helical and double U-tube borehole heat exchangers: A simulation-based comparison," Applied Energy, Elsevier, vol. 112(C), pages 358-370.
    15. Shih, Yu-Jen & Su, Chia-Chi & Huang, Yao-Hui & Lu, Ming-Chun, 2013. "SiO2-supported ferromagnetic catalysts for hydrogen generation from alkaline NaBH4 (sodium borohydride) solution," Energy, Elsevier, vol. 54(C), pages 263-270.
    16. Gao, Dan & Jiang, Dongfang & Liu, Pei & Li, Zheng & Hu, Sangao & Xu, Hong, 2014. "An integrated energy storage system based on hydrogen storage: Process configuration and case studies with wind power," Energy, Elsevier, vol. 66(C), pages 332-341.
    17. Jeong, Dongho & Lee, Jongsoo, 2014. "Electrode design optimization of lithium secondary batteries to enhance adhesion and deformation capabilities," Energy, Elsevier, vol. 75(C), pages 525-533.
    18. Barbir, Frano, 2009. "Transition to renewable energy systems with hydrogen as an energy carrier," Energy, Elsevier, vol. 34(3), pages 308-312.
    19. Weng, Baicheng & Wu, Zhu & Li, Zhilin & Yang, Hui, 2012. "Hydrogen generation from hydrolysis of MNH2BH3 and NH3BH3/MH (M=Li, Na) for fuel cells based unmanned submarine vehicles application," Energy, Elsevier, vol. 38(1), pages 205-211.
    20. Wenelska, Karolina & Michalkiewicz, Beata & Chen, Xuecheng & Mijowska, Ewa, 2014. "Pd nanoparticles with tunable diameter deposited on carbon nanotubes with enhanced hydrogen storage capacity," Energy, Elsevier, vol. 75(C), pages 549-554.
    21. Ismail, M., 2015. "Effect of LaCl3 addition on the hydrogen storage properties of MgH2," Energy, Elsevier, vol. 79(C), pages 177-182.
    22. Dittmar, Michael, 2012. "Nuclear energy: Status and future limitations," Energy, Elsevier, vol. 37(1), pages 35-40.
    23. Zarrella, Angelo & De Carli, Michele, 2013. "Heat transfer analysis of short helical borehole heat exchangers," Applied Energy, Elsevier, vol. 102(C), pages 1477-1491.
    24. Principi, G. & Agresti, F. & Maddalena, A. & Lo Russo, S., 2009. "The problem of solid state hydrogen storage," Energy, Elsevier, vol. 34(12), pages 2087-2091.
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    2. Wang, Feng & Li, Rongfeng & Ding, Cuiping & Tang, Wukui & Wang, Yibo & Xu, Shimeng & Yu, Ronghai & Wang, Zhongmin, 2017. "Enhanced hydrogen storage properties of ZrCo alloy decorated with flower-like Pd particles," Energy, Elsevier, vol. 139(C), pages 8-17.

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