IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v90y2015ip1p588-594.html
   My bibliography  Save this article

Fabrication and experimental validation of a full-scale depleted uranium bed with thin double-layered annulus configuration for hydrogen isotopes recovery and delivery

Author

Listed:
  • Kou, Huaqin
  • Luo, Wenhua
  • Huang, Zhiyong
  • Sang, Ge
  • Meng, Daqiao
  • Zhang, Guanghui
  • Chen, Changan
  • Luo, Deli
  • Hu, Changwen

Abstract

Metal hydride beds play an important role in the application of hydrogen-related energy. In the present work, a full-scale DU (depleted uranium) bed with the newly proposed bed design of thin double-layered annulus configuration was fabricated for hydrogen isotopes recovery and delivery. The hydrogen recovery/delivery properties and the thermal effect of the fabricated bed were experimentally investigated. It was found that the fabricated bed was able to achieve the hydrogen storage target of 17.5 mol H2 with a fast hydrogen recovery rate. Not only hydrogen delivery amount as high as 16.5 mol (∼94% of recovery amount) but also an average delivery rate of 20 Pa m3/s could be obtained at 450 °C, even though the hydrogen delivery time of the bed reached as long as 30.9 min. The fabricated DU bed also exhibited outstanding cyclic hydrogen recovery/delivery performances. Deterioration in both hydrogen recovery/delivery amount and rate was not observed even up to 10 cycles. Besides, it was shown that utilization of the water cooling loops drilled in the DU bed was beneficial to enhance the heat transfer and promote the hydrogen recovery process of the bed. Meanwhile, the internal structure of the fabricated bed was observed by ICT (industrial computed tomography). And the ICT results demonstrated that DU expanded seriously after hydrogen recovery/delivery cycles, resulting in the deformation of the filters in the bed. The experimental results suggested that the fabricated DU bed was technically feasible to be applied for hydrogen isotopes recovery and delivery in the International Thermonuclear Experimental Reactor.

Suggested Citation

  • Kou, Huaqin & Luo, Wenhua & Huang, Zhiyong & Sang, Ge & Meng, Daqiao & Zhang, Guanghui & Chen, Changan & Luo, Deli & Hu, Changwen, 2015. "Fabrication and experimental validation of a full-scale depleted uranium bed with thin double-layered annulus configuration for hydrogen isotopes recovery and delivery," Energy, Elsevier, vol. 90(P1), pages 588-594.
    • Handle: RePEc:eee:energy:v:90:y:2015:i:p1:p:588-594
    DOI: 10.1016/j.energy.2015.07.097
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215009925
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.07.097?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chung, Kyong-Hwan, 2010. "High-pressure hydrogen storage on microporous zeolites with varying pore properties," Energy, Elsevier, vol. 35(5), pages 2235-2241.
    2. Ding, Xiangqian & Zhu, Yunfeng & Wei, Lingjun & Li, Ying & Li, Liquan, 2013. "Synergistic hydrogen desorption of HCS MgH2 + LiAlH4 composite," Energy, Elsevier, vol. 55(C), pages 933-938.
    3. Kikkinides, Eustathios S. & Georgiadis, Michael C. & Stubos, Athanasios K., 2006. "Dynamic modelling and optimization of hydrogen storage in metal hydride beds," Energy, Elsevier, vol. 31(13), pages 2428-2446.
    4. Aadmi, Moussa & Karkri, Mustapha & El Hammouti, Mimoun, 2015. "Heat transfer characteristics of thermal energy storage for PCM (phase change material) melting in horizontal tube: Numerical and experimental investigations," Energy, Elsevier, vol. 85(C), pages 339-352.
    5. Neef, H.-J., 2009. "International overview of hydrogen and fuel cell research," Energy, Elsevier, vol. 34(3), pages 327-333.
    6. Komiyama, Ryoichi & Otsuki, Takashi & Fujii, Yasumasa, 2015. "Energy modeling and analysis for optimal grid integration of large-scale variable renewables using hydrogen storage in Japan," Energy, Elsevier, vol. 81(C), pages 537-555.
    7. Pedicini, R. & Schiavo, B. & Rispoli, P. & Saccà, A. & Carbone, A. & Gatto, I. & Passalacqua, E., 2014. "Progress in polymeric material for hydrogen storage application in middle conditions," Energy, Elsevier, vol. 64(C), pages 607-614.
    8. Baker, Charles C. & Conn, Robert W. & Najmabadi, Farrokh & Tillack, Mark S., 1998. "Status and prospects for fusion energy from magnetically confined plasmas," Energy, Elsevier, vol. 23(7), pages 649-694.
    9. Fan, Mei-Qiang & Liu, Shu-sheng & Zhang, Yao & Zhang, Jian & Sun, Li-Xian & Xu, Fen, 2010. "Superior hydrogen storage properties of MgH2–10 wt.% TiC composite," Energy, Elsevier, vol. 35(8), pages 3417-3421.
    10. Pukazhselvan, D. & Hudson, M. Sterlin Leo & Sinha, A.S.K. & Srivastava, O.N., 2010. "Studies on metal oxide nanoparticles catalyzed sodium aluminum hydride," Energy, Elsevier, vol. 35(12), pages 5037-5042.
    11. Avril, S. & Arnaud, G. & Florentin, A. & Vinard, M., 2010. "Multi-objective optimization of batteries and hydrogen storage technologies for remote photovoltaic systems," Energy, Elsevier, vol. 35(12), pages 5300-5308.
    12. Chung, C.A. & Yang, Su-Wen & Yang, Chien-Yuh & Hsu, Che-Weu & Chiu, Pai-Yuh, 2013. "Experimental study on the hydrogen charge and discharge rates of metal hydride tanks using heat pipes to enhance heat transfer," Applied Energy, Elsevier, vol. 103(C), pages 581-587.
    13. Kumar, Sanjay & Tiwari, G.P. & Sonak, Sagar & Jain, Uttam & Krishnamurthy, Nagaiyar, 2014. "High performance FeTi – 3.1 mass % V alloy for on board hydrogen storage solution," Energy, Elsevier, vol. 75(C), pages 520-524.
    14. Zarrella, Angelo & Capozza, Antonio & De Carli, Michele, 2013. "Analysis of short helical and double U-tube borehole heat exchangers: A simulation-based comparison," Applied Energy, Elsevier, vol. 112(C), pages 358-370.
    15. Shih, Yu-Jen & Su, Chia-Chi & Huang, Yao-Hui & Lu, Ming-Chun, 2013. "SiO2-supported ferromagnetic catalysts for hydrogen generation from alkaline NaBH4 (sodium borohydride) solution," Energy, Elsevier, vol. 54(C), pages 263-270.
    16. Gao, Dan & Jiang, Dongfang & Liu, Pei & Li, Zheng & Hu, Sangao & Xu, Hong, 2014. "An integrated energy storage system based on hydrogen storage: Process configuration and case studies with wind power," Energy, Elsevier, vol. 66(C), pages 332-341.
    17. Jeong, Dongho & Lee, Jongsoo, 2014. "Electrode design optimization of lithium secondary batteries to enhance adhesion and deformation capabilities," Energy, Elsevier, vol. 75(C), pages 525-533.
    18. Barbir, Frano, 2009. "Transition to renewable energy systems with hydrogen as an energy carrier," Energy, Elsevier, vol. 34(3), pages 308-312.
    19. Weng, Baicheng & Wu, Zhu & Li, Zhilin & Yang, Hui, 2012. "Hydrogen generation from hydrolysis of MNH2BH3 and NH3BH3/MH (M=Li, Na) for fuel cells based unmanned submarine vehicles application," Energy, Elsevier, vol. 38(1), pages 205-211.
    20. Wenelska, Karolina & Michalkiewicz, Beata & Chen, Xuecheng & Mijowska, Ewa, 2014. "Pd nanoparticles with tunable diameter deposited on carbon nanotubes with enhanced hydrogen storage capacity," Energy, Elsevier, vol. 75(C), pages 549-554.
    21. Ismail, M., 2015. "Effect of LaCl3 addition on the hydrogen storage properties of MgH2," Energy, Elsevier, vol. 79(C), pages 177-182.
    22. Dittmar, Michael, 2012. "Nuclear energy: Status and future limitations," Energy, Elsevier, vol. 37(1), pages 35-40.
    23. Zarrella, Angelo & De Carli, Michele, 2013. "Heat transfer analysis of short helical borehole heat exchangers," Applied Energy, Elsevier, vol. 102(C), pages 1477-1491.
    24. Principi, G. & Agresti, F. & Maddalena, A. & Lo Russo, S., 2009. "The problem of solid state hydrogen storage," Energy, Elsevier, vol. 34(12), pages 2087-2091.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Feng & Li, Rongfeng & Ding, Cuiping & Tang, Wukui & Wang, Yibo & Xu, Shimeng & Yu, Ronghai & Wang, Zhongmin, 2017. "Enhanced hydrogen storage properties of ZrCo alloy decorated with flower-like Pd particles," Energy, Elsevier, vol. 139(C), pages 8-17.
    2. Yao, Zhendong & Liang, Zhaoqing & Xiao, Xuezhang & Qi, Jiacheng & He, Jiahuan & Huang, Xu & Kou, Huaqin & Luo, Wenhua & Chen, Changan & Chen, Lixin, 2022. "Achieving excellent cycle stability in Zr–Nb–Co–Ni based hydrogen isotope storage alloys by controllable phase transformation reaction," Renewable Energy, Elsevier, vol. 187(C), pages 500-507.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ma, Li-Juan & Wang, Jianfeng & Han, Min & Jia, Jianfeng & Wu, Hai-Shun & Zhang, Xiang, 2019. "Adsorption of multiple H2 molecules on the complex TiC6H6: An unusual combination of chemisorption and physisorption," Energy, Elsevier, vol. 171(C), pages 315-325.
    2. Kumar, Sandeep & Dhilip Kumar, T.J., 2020. "Hydrogen trapping potential of Ca decorated metal-graphyne framework," Energy, Elsevier, vol. 199(C).
    3. Valero-Pedraza, María José & Martín-Cortés, Alexandra & Navarrete, Alexander & Bermejo, María Dolores & Martín, Ángel, 2015. "Kinetics of hydrogen release from dissolutions of ammonia borane in different ionic liquids," Energy, Elsevier, vol. 91(C), pages 742-750.
    4. Kalamse, Vijayanand & Wadnerkar, Nitin & Chaudhari, Ajay, 2013. "Multi-functionalized naphthalene complexes for hydrogen storage," Energy, Elsevier, vol. 49(C), pages 469-474.
    5. Ding, Xiangqian & Zhu, Yunfeng & Wei, Lingjun & Li, Ying & Li, Liquan, 2013. "Synergistic hydrogen desorption of HCS MgH2 + LiAlH4 composite," Energy, Elsevier, vol. 55(C), pages 933-938.
    6. Zhang, Wei & Cheng, Ying & Han, Da & Han, Shumin, 2015. "The hydrogen storage properties of MgH2–Fe3S4 composites," Energy, Elsevier, vol. 93(P1), pages 625-630.
    7. Pedicini, R. & Schiavo, B. & Rispoli, P. & Saccà, A. & Carbone, A. & Gatto, I. & Passalacqua, E., 2014. "Progress in polymeric material for hydrogen storage application in middle conditions," Energy, Elsevier, vol. 64(C), pages 607-614.
    8. Wang, Feng & Li, Rongfeng & Ding, Cuiping & Tang, Wukui & Wang, Yibo & Xu, Shimeng & Yu, Ronghai & Wang, Zhongmin, 2017. "Enhanced hydrogen storage properties of ZrCo alloy decorated with flower-like Pd particles," Energy, Elsevier, vol. 139(C), pages 8-17.
    9. El-Eskandarany, M. Sherif & Al-Matrouk, H. & Shaban, Ehab & Al-Duweesh, Ahmed, 2015. "Superior catalytic effect of nanocrystalline big-cube Zr2Ni metastable phase for improving the hydrogen sorption/desorption kinetics and cyclability of MgH2 powders," Energy, Elsevier, vol. 91(C), pages 274-282.
    10. Ismail, M., 2015. "Effect of LaCl3 addition on the hydrogen storage properties of MgH2," Energy, Elsevier, vol. 79(C), pages 177-182.
    11. Kou, Huaqin & Huang, Zhiyong & Luo, Wenhua & Sang, Ge & Meng, Daqiao & Luo, Deli & Zhang, Guanghui & Chen, Hao & Zhou, Ying & Hu, Changwen, 2015. "Experimental study on full-scale ZrCo and depleted uranium beds applied for fast recovery and delivery of hydrogen isotopes," Applied Energy, Elsevier, vol. 145(C), pages 27-35.
    12. El-Eskandarany, M. Sherif & Shaban, Ehab & Alsairafi, Ammar A., 2016. "Synergistic dosing effect of TiC/FeCr nanocatalysts on the hydrogenation/dehydrogenation kinetics of nanocrystalline MgH2 powders," Energy, Elsevier, vol. 104(C), pages 158-170.
    13. Dou, Binlin & Zhang, Hua & Cui, Guomin & He, Mingxing & Ruan, Chenjie & Wang, Zilong & Chen, Haisheng & Xu, Yujie & Jiang, Bo & Wu, Chunfei, 2019. "Hydrogen sorption and desorption behaviors of Mg-Ni-Cu doped carbon nanotubes at high temperature," Energy, Elsevier, vol. 167(C), pages 1097-1106.
    14. Gkanas, Evangelos I. & Khzouz, Martin & Panagakos, Grigorios & Statheros, Thomas & Mihalakakou, Giouli & Siasos, Gerasimos I. & Skodras, Georgios & Makridis, Sofoklis S., 2018. "Hydrogenation behavior in rectangular metal hydride tanks under effective heat management processes for green building applications," Energy, Elsevier, vol. 142(C), pages 518-530.
    15. Wu, Zhen & Yang, Fusheng & Zhang, Zaoxiao & Bao, Zewei, 2014. "Magnesium based metal hydride reactor incorporating helical coil heat exchanger: Simulation study and optimal design," Applied Energy, Elsevier, vol. 130(C), pages 712-722.
    16. Shen, Xiaochen & Wang, Qing & Wu, Qingquan & Guo, Siqi & Zhang, Zhengyan & Sun, Ziyang & Liu, Baishu & Wang, Zhibin & Zhao, Bin & Ding, Weiping, 2015. "CoB supported on Ag-activated TiO2 as a highly active catalyst for hydrolysis of alkaline NaBH4 solution," Energy, Elsevier, vol. 90(P1), pages 464-474.
    17. Öz, Çisem & Coşkuner Filiz, Bilge & Kantürk Figen, Aysel, 2017. "The effect of vinegar–acetic acid solution on the hydrogen generation performance of mechanochemically modified Magnesium (Mg) granules," Energy, Elsevier, vol. 127(C), pages 328-334.
    18. Hunt, Julian David & Nascimento, Andreas & Zakeri, Behnam & Barbosa, Paulo Sérgio Franco, 2022. "Hydrogen Deep Ocean Link: a global sustainable interconnected energy grid," Energy, Elsevier, vol. 249(C).
    19. Fan, Mei-Qiang & Liu, Shu-sheng & Zhang, Yao & Zhang, Jian & Sun, Li-Xian & Xu, Fen, 2010. "Superior hydrogen storage properties of MgH2–10 wt.% TiC composite," Energy, Elsevier, vol. 35(8), pages 3417-3421.
    20. Aneta Sapińska-Sliwa & Marc A. Rosen & Andrzej Gonet & Joanna Kowalczyk & Tomasz Sliwa, 2019. "A New Method Based on Thermal Response Tests for Determining Effective Thermal Conductivity and Borehole Resistivity for Borehole Heat Exchangers," Energies, MDPI, vol. 12(6), pages 1-22, March.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:90:y:2015:i:p1:p:588-594. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.