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The effect of vinegar–acetic acid solution on the hydrogen generation performance of mechanochemically modified Magnesium (Mg) granules

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  • Öz, Çisem
  • Coşkuner Filiz, Bilge
  • Kantürk Figen, Aysel

Abstract

An environmentally friendly magnesium (Mg)-based hydrogen (H2) generation system was set up based on an anodic polarization reaction using mechanochemically modified Mg granule samples combined with aqueous, biodegradable, vinegar-acetic acid solutions. The composition of the vinegar-acetic acid solutions (4.0–0.8 wt %) was changed to obtain the maximum H2 generation rate. An interpretation of the kinetic mechanisms for Nucleation–Growth and Surface Area models was made, and it was concluded that mechanochemical modification changed the hydrolysis kinetics from surface area control to nucleation and growth. This led to the enhanced hydrolysis properties of the mechanochemically modified Mg granules.

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  • Öz, Çisem & Coşkuner Filiz, Bilge & Kantürk Figen, Aysel, 2017. "The effect of vinegar–acetic acid solution on the hydrogen generation performance of mechanochemically modified Magnesium (Mg) granules," Energy, Elsevier, vol. 127(C), pages 328-334.
    • Handle: RePEc:eee:energy:v:127:y:2017:i:c:p:328-334
    DOI: 10.1016/j.energy.2017.03.106
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    1. Ding, Xiangqian & Zhu, Yunfeng & Wei, Lingjun & Li, Ying & Li, Liquan, 2013. "Synergistic hydrogen desorption of HCS MgH2 + LiAlH4 composite," Energy, Elsevier, vol. 55(C), pages 933-938.
    2. Liuzhang Ouyang & Miaolian Ma & Minghong Huang & Ruoming Duan & Hui Wang & Lixian Sun & Min Zhu, 2015. "Enhanced Hydrogen Generation Properties of MgH 2 -Based Hydrides by Breaking the Magnesium Hydroxide Passivation Layer," Energies, MDPI, vol. 8(5), pages 1-16, May.
    3. Sun, Qian & Zou, Meishuai & Guo, Xiaoyan & Yang, Rongjie & Huang, Haitao & Huang, Peng & He, Xiangdong, 2015. "A study of hydrogen generation by reaction of an activated Mg–CoCl2 (magnesium–cobalt chloride) composite with pure water for portable applications," Energy, Elsevier, vol. 79(C), pages 310-314.
    4. Liu, Yongan & Wang, Xinhua & Dong, Zhaohui & Liu, Haizhen & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2013. "Hydrogen generation from the hydrolysis of Mg powder ball-milled with AlCl3," Energy, Elsevier, vol. 53(C), pages 147-152.
    5. Fan, Mei-Qiang & Liu, Shu-sheng & Zhang, Yao & Zhang, Jian & Sun, Li-Xian & Xu, Fen, 2010. "Superior hydrogen storage properties of MgH2–10 wt.% TiC composite," Energy, Elsevier, vol. 35(8), pages 3417-3421.
    6. Zou, Mei-Shuai & Huang, Hai-Tao & Sun, Qian & Guo, Xiao-Yan & Yang, Rong-Jie, 2014. "Effect of the storage environment on hydrogen production via hydrolysis reaction from activated Mg-based materials," Energy, Elsevier, vol. 76(C), pages 673-678.
    7. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Cao, Guozhou & Yan, Mi, 2014. "Hydrogen generation from Mg–LiBH4 hydrolysis improved by AlCl3 addition," Energy, Elsevier, vol. 68(C), pages 548-554.
    8. Fan, Mei-qiang & Sun, Li-xian & Xu, Fen, 2010. "Feasibility study of hydrogen production for micro fuel cell from activated Al–In mixture in water," Energy, Elsevier, vol. 35(3), pages 1333-1337.
    9. Fan, Mei–qiang & Sun, Li–xian & Xu, Fen, 2010. "Experiment assessment of hydrogen production from activated aluminum alloys in portable generator for fuel cell applications," Energy, Elsevier, vol. 35(7), pages 2922-2926.
    10. Liang, J. & Gao, L.J. & Miao, N.N. & Chai, Y.J. & Wang, N. & Song, X.Q., 2016. "Hydrogen generation by reaction of Al–M (M = Fe,Co,Ni) with water," Energy, Elsevier, vol. 113(C), pages 282-287.
    11. Principi, G. & Agresti, F. & Maddalena, A. & Lo Russo, S., 2009. "The problem of solid state hydrogen storage," Energy, Elsevier, vol. 34(12), pages 2087-2091.
    12. Awad, A.S. & El-Asmar, E. & Tayeh, T. & Mauvy, F. & Nakhl, M. & Zakhour, M. & Bobet, J.-L., 2016. "Effect of carbons (G and CFs), TM (Ni, Fe and Al) and oxides (Nb2O5 and V2O5) on hydrogen generation from ball milled Mg-based hydrolysis reaction for fuel cell," Energy, Elsevier, vol. 95(C), pages 175-186.
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