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Hydroxide-ion selective electrolytes based on a polybenzimidazole/graphene oxide composite membrane

Author

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  • Yu, Bor-Chern
  • Wang, Yi-Chun
  • Lu, Hsin-Chun
  • Lin, Hsiu-Li
  • Shih, Chao-Ming
  • Kumar, S. Rajesh
  • Lue, Shingjiang Jessie

Abstract

The objectives of this work are to prepare and characterize poly[2,2′-m-(phenylene)-5,5′-bibenzimidazole]/graphene oxide (PBI/GO) solid electrolyte for direct alcohol alkaline fuel cell (DAAFC) applications. GO nanosheets are coated onto a PBI surface using a spin coater to construct the PBI/GO composite membrane. The PBI/GO composite membrane exhibits an ionic conductivity of 2.53 × 10−2 S cm−1 at 80 °C, which is improved by 72–93% when compared with the pure PBI membrane. In addition, the methanol permeability is reduced by 18–25% by incorporating GO onto the PBI top surface. The peak power density (Pmax) of the PBI/GO electrolyte reaches 200 mW cm−2 when using alkaline methanol as fuel with Pt-based catalysts, or 120 mW cm−2 when fed with an ethanol and alkaline solution mixture at 80 °C. Replacing the Pt-based catalysts with Hypermec™ catalysts resulted in Pmax of 40 and 100 mW cm−2, for methanol and ethanol fuel cells, respectively. These superior DAAFC power outputs are ascribed to the improved anion conduction of the KOH doped GO and the suppressed methanol cross-over from high aspect ratio GO as the alcohol barrier layer.

Suggested Citation

  • Yu, Bor-Chern & Wang, Yi-Chun & Lu, Hsin-Chun & Lin, Hsiu-Li & Shih, Chao-Ming & Kumar, S. Rajesh & Lue, Shingjiang Jessie, 2017. "Hydroxide-ion selective electrolytes based on a polybenzimidazole/graphene oxide composite membrane," Energy, Elsevier, vol. 134(C), pages 802-812.
    • Handle: RePEc:eee:energy:v:134:y:2017:i:c:p:802-812
    DOI: 10.1016/j.energy.2017.06.061
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    2. Peydayesh, Mohammad & Mohammadi, Toraj & Bakhtiari, Omid, 2017. "Effective hydrogen purification from methane via polyimide Matrimid® 5218- Deca-dodecasil 3R type zeolite mixed matrix membrane," Energy, Elsevier, vol. 141(C), pages 2100-2107.
    3. Tang, Michael & Chang, Jia-Cheng & Kumar, S. Rajesh & Lue, Shingjiang Jessie, 2019. "Glyme-based electrolyte formulation analysis in aprotic lithium-oxygen battery and its cyclic stability," Energy, Elsevier, vol. 187(C).

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