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Glyme-based electrolyte formulation analysis in aprotic lithium-oxygen battery and its cyclic stability

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  • Tang, Michael
  • Chang, Jia-Cheng
  • Kumar, S. Rajesh
  • Lue, Shingjiang Jessie

Abstract

In this work, the effect of electrolyte composition was evaluated on lithium-oxygen (Li–O2) battery using carbon cloth air electrode. Seven ether-based solvents were measured for their conductivity, viscosity, contact angle and decomposition temperature. The results were compiled with other physical properties to screen potential solvents for future testing. Diglyme and tetraglyme were identified and each of them was individually mixed with one of four lithium salts, yielding eight combinations of electrolytes. These electrolytes were assembled into Li–O2 batteries and the voltage and capacity data were recorded during cycling discharge/charge test. The effects of organic electrolyte physical properties on the battery impedance and cyclic life were discussed. Among the eight electrolytes, lithium bis(trifluoromethane) sulfonimide (LiTFSI) in tetraethylene glycol dimethyl ether (tetraglyme) resulted in the longest cyclic life at a discharge capacity cutoff of 2000 mAh gPt−1 than other compositions. This performance may be ascribed to the electrolyte's high conductivity, sufficient viscosity and suitable contact angle with the air electrode.

Suggested Citation

  • Tang, Michael & Chang, Jia-Cheng & Kumar, S. Rajesh & Lue, Shingjiang Jessie, 2019. "Glyme-based electrolyte formulation analysis in aprotic lithium-oxygen battery and its cyclic stability," Energy, Elsevier, vol. 187(C).
    • Handle: RePEc:eee:energy:v:187:y:2019:i:c:s036054421931610x
    DOI: 10.1016/j.energy.2019.115926
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    References listed on IDEAS

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    1. Li, Xianglin & Huang, Jing & Faghri, Amir, 2015. "Modeling study of a Li–O2 battery with an active cathode," Energy, Elsevier, vol. 81(C), pages 489-500.
    2. Farooqui, U.R. & Ahmad, A.L. & Hamid, N.A., 2017. "Challenges and potential advantages of membranes in lithium air batteries: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1114-1129.
    3. Yu, Bor-Chern & Wang, Yi-Chun & Lu, Hsin-Chun & Lin, Hsiu-Li & Shih, Chao-Ming & Kumar, S. Rajesh & Lue, Shingjiang Jessie, 2017. "Hydroxide-ion selective electrolytes based on a polybenzimidazole/graphene oxide composite membrane," Energy, Elsevier, vol. 134(C), pages 802-812.
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    Cited by:

    1. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    2. Qiang Li & Tanghu Zhang & Tianyu Zhang & Zhichao Xue & Hong Sun, 2022. "Study on Two-Phase Permeation of Oxygen and Electrolyte in Lithium Air Battery Electrode Based on Digital Twin," Energies, MDPI, vol. 15(19), pages 1-12, September.

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