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Modeling study of a Li–O2 battery with an active cathode

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  • Li, Xianglin
  • Huang, Jing
  • Faghri, Amir

Abstract

In this study, a new organic lithium oxygen (Li–O2) battery structure is proposed to enhance battery capacity. The electrolyte is forced to recirculate through the cathode and then saturated with oxygen in a tank external to the battery. The forced convection enhances oxygen transport and alleviates the problem of electrode blockage during discharge. A two dimensional, transient, non-isothermal simulation model is developed to study the heat and mass transfer within the battery and validate the proposed design. Results show that this novel active cathode design improves the battery capacity at all discharge current densities. The capacity of the Li–O2 battery is increased by 15.5 times (from 12.2 mAh g−1 to 201 mAh g−1) at the discharge current of 2.0 mA cm−2 when a conventional passive electrode is replaced by the newly designed active electrode. Furthermore, a cathode with non-uniform porosity is suggested and simulation results show that it can reach a higher discharge capacity without decreasing its power density. Detailed mass transport processes in the battery are also studied.

Suggested Citation

  • Li, Xianglin & Huang, Jing & Faghri, Amir, 2015. "Modeling study of a Li–O2 battery with an active cathode," Energy, Elsevier, vol. 81(C), pages 489-500.
    • Handle: RePEc:eee:energy:v:81:y:2015:i:c:p:489-500
    DOI: 10.1016/j.energy.2014.12.062
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    References listed on IDEAS

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    1. Li, Xianglin & Faghri, Amir, 2011. "Local entropy generation analysis on passive high-concentration DMFCs (direct methanol fuel cell) with different cell structures," Energy, Elsevier, vol. 36(1), pages 403-414.
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    Cited by:

    1. Ye, Luhan & Wang, Xiaoning & Lv, Weiqiang & Fei, Jipeng & Zhu, Gaolong & Liang, Yachun & Song, Yuanqiang & Zhai, Junyi & He, Weidong, 2015. "Analytical insight into the oxygen diffusion in wetted porous cathodes of Li-air batteries," Energy, Elsevier, vol. 93(P1), pages 416-420.
    2. Ren, Y.X. & Zhao, T.S. & Tan, P. & Wei, Z.H. & Zhou, X.L., 2017. "Modeling of an aprotic Li-O2 battery incorporating multiple-step reactions," Applied Energy, Elsevier, vol. 187(C), pages 706-716.
    3. Berrueta, Alberto & Urtasun, Andoni & Ursúa, Alfredo & Sanchis, Pablo, 2018. "A comprehensive model for lithium-ion batteries: From the physical principles to an electrical model," Energy, Elsevier, vol. 144(C), pages 286-300.
    4. Kisoo Yoo & Soumik Banerjee & Jonghoon Kim & Prashanta Dutta, 2017. "A Review of Lithium-Air Battery Modeling Studies," Energies, MDPI, vol. 10(11), pages 1-42, November.
    5. Yuan, Jiashu & Zhu, Yongming & Gao, Jian & Li, Wantang, 2015. "Electrochemical performance of mixed carbon material with waterproof membrane for lithium air battery in the ambient atmosphere," Energy, Elsevier, vol. 89(C), pages 84-91.
    6. Tang, Michael & Chang, Jia-Cheng & Kumar, S. Rajesh & Lue, Shingjiang Jessie, 2019. "Glyme-based electrolyte formulation analysis in aprotic lithium-oxygen battery and its cyclic stability," Energy, Elsevier, vol. 187(C).

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