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Heat integration of methanol steam reformer with a high-temperature polymeric electrolyte membrane fuel cell

Author

Listed:
  • Ribeirinha, P.
  • Alves, I.
  • Vázquez, F. Vidal
  • Schuller, G.
  • Boaventura, M.
  • Mendes, A.

Abstract

A fuel cell is an exothermic device that wastes ca. 50% of the input chemical energy while methanol steam-reforming (MSR) reaction is endothermic. The integration of a low temperature methanol steam-reforming cell (MSR-C) with a high temperature polymer electrolyte membrane fuel cell (HT-PEMFC) in a combined stack arrangement allows the thermal integration of both reactors. A novel bipolar plate of poly(p-phenylene sulfide) (PPS) featuring the fuel cell flow field in one side and the reformer flow field in the other was designed, built and assessed. For the first time are reported high current densities (>0.5 A cm−2) with the integrated system running at 453 K. The system was also ran for more than 100 h at 453 K, at 0.3 A cm−2, with a methanol conversion of >90%. It was observed some degradation of the membrane electrode assembly (MEA) due to the continuous presence of methanol in the reformate stream. Electrochemical impedance spectroscopy (EIS) analyses revealed an overall increase of the resistances. The self-thermal sustainability of the combined device was only reached for >0.75 A cm−2 due to the poor thermal insulation of the combined reactor.

Suggested Citation

  • Ribeirinha, P. & Alves, I. & Vázquez, F. Vidal & Schuller, G. & Boaventura, M. & Mendes, A., 2017. "Heat integration of methanol steam reformer with a high-temperature polymeric electrolyte membrane fuel cell," Energy, Elsevier, vol. 120(C), pages 468-477.
    • Handle: RePEc:eee:energy:v:120:y:2017:i:c:p:468-477
    DOI: 10.1016/j.energy.2016.11.101
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    References listed on IDEAS

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    Cited by:

    1. Gabriele Loreti & Andrea Luigi Facci & Stefano Ubertini, 2021. "High-Efficiency Combined Heat and Power through a High-Temperature Polymer Electrolyte Membrane Fuel Cell and Gas Turbine Hybrid System," Sustainability, MDPI, vol. 13(22), pages 1-24, November.
    2. Perng, Shiang-Wuu & Chien, Tsai-Chieh & Horng, Rong-Fang & Wu, Horng-Wen, 2019. "Performance enhancement of a plate methanol steam reformer by ribs installed in the reformer channel," Energy, Elsevier, vol. 167(C), pages 588-601.
    3. Li, Yanju & Li, Dongxu & Ma, Zheshu & Zheng, Meng & Lu, Zhanghao & Song, Hanlin & Guo, Xinjia & Shao, Wei, 2022. "Performance analysis and optimization of a novel vehicular power system based on HT-PEMFC integrated methanol steam reforming and ORC," Energy, Elsevier, vol. 257(C).
    4. Konstantinos Kappis & Joan Papavasiliou & George Avgouropoulos, 2021. "Methanol Reforming Processes for Fuel Cell Applications," Energies, MDPI, vol. 14(24), pages 1-30, December.
    5. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    6. Chen, Xueye & Li, Tiechuan & Shen, Jienan & Hu, Zengliang, 2017. "From structures, packaging to application: A system-level review for micro direct methanol fuel cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 669-678.
    7. Chang, Cheng-Ping & Wu, Yen-Chih & Chen, Wei-Yen & Pan, Chin & Su, Yu-Chuan & Huang, Yuh-Jeen & Tseng, Fan-Gang, 2020. "A hybrid phosphorus-acid fuel cell system incorporated with oxidative steam reforming of methanol (OSRM) reformer," Renewable Energy, Elsevier, vol. 153(C), pages 530-538.
    8. Ribeirinha, P. & Abdollahzadeh, M. & Sousa, J.M. & Boaventura, M. & Mendes, A., 2017. "Modelling of a high-temperature polymer electrolyte membrane fuel cell integrated with a methanol steam reformer cell," Applied Energy, Elsevier, vol. 202(C), pages 6-19.
    9. Zhang, Jun & Zhang, Caizhi & Li, Jin & Deng, Bo & Fan, Min & Ni, Meng & Mao, Zhanxin & Yuan, Honggeng, 2021. "Multi-perspective analysis of CO poisoning in high-temperature proton exchange membrane fuel cell stack via numerical investigation," Renewable Energy, Elsevier, vol. 180(C), pages 313-328.
    10. Ribeirinha, P. & Abdollahzadeh, M. & Pereira, A. & Relvas, F. & Boaventura, M. & Mendes, A., 2018. "High temperature PEM fuel cell integrated with a cellular membrane methanol steam reformer: Experimental and modelling," Applied Energy, Elsevier, vol. 215(C), pages 659-669.
    11. Mosayebi, Amir & Eghbal Ahmadi, Mohammad Hosein, 2022. "Combined steam and dry reforming of methanol process to syngas formation: Kinetic modeling and thermodynamic equilibrium analysis," Energy, Elsevier, vol. 261(PB).
    12. Li, Na & Cui, Xiaoti & Zhu, Jimin & Zhou, Mengfan & Liso, Vincenzo & Cinti, Giovanni & Sahlin, Simon Lennart & Araya, Samuel Simon, 2023. "A review of reformed methanol-high temperature proton exchange membrane fuel cell systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    13. Samuel Simon Araya & Vincenzo Liso & Xiaoti Cui & Na Li & Jimin Zhu & Simon Lennart Sahlin & Søren Højgaard Jensen & Mads Pagh Nielsen & Søren Knudsen Kær, 2020. "A Review of The Methanol Economy: The Fuel Cell Route," Energies, MDPI, vol. 13(3), pages 1-32, January.
    14. Liu, Jiaran & Tan, Jinzhu & Yang, Weizhan & Li, Yang & Wang, Chao, 2021. "Better electrochemical performance of PEMFC under a novel pneumatic clamping mechanism," Energy, Elsevier, vol. 229(C).

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    More about this item

    Keywords

    Methanol steam reforming; HT-PEMFC; Integration; H2 production;
    All these keywords.

    JEL classification:

    • H2 - Public Economics - - Taxation, Subsidies, and Revenue

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