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Effect of surface treatment on the interfacial contact resistance and corrosion resistance of Fe–Ni–Cr alloy as a bipolar plate for polymer electrolyte membrane fuel cells

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  • Yang, Meijun
  • Zhang, Dongming

Abstract

The bipolar plate is an important component of the PEMFC (polymer electrolyte membrane fuel cell) because it supplies the pathway of electron flow between each unit cell. Fe–Ni–Cr alloy is considered as a good candidate material for bipolar plate, but it is limited to use as a bipolar plate due to its high ICR (interfacial contact resistance) and corrosion problem. In order to explore a cost-effective method on surface modification, various chemical and electrochemical treatments are performed on Fe–Ni–Cr alloy to acquire the effect of the surface modification on the ICR and corrosion behavior. The ICR and corrosion resistance of Fe–Ni–Cr alloy can be effectively controlled by the chemical treatment of immersion in the mixed acid solution with 10 vol% HNO3, 2 vol% HCl and 1 vol% HF for 10 min at 65 °C and then was placed in 30 vol% HNO3 solution for 5 min. The chemical treatment is more effective on reducing ICR and improving corrosion resistance than that of electrochemical methods (be carried out in the 2 mol/L H2SO4 solution with the electrical potential from −0.4 V to 0.6 V) for Fe–Ni–Cr alloy as a bipolar plate for polymer electrolyte membrane fuel cells.

Suggested Citation

  • Yang, Meijun & Zhang, Dongming, 2014. "Effect of surface treatment on the interfacial contact resistance and corrosion resistance of Fe–Ni–Cr alloy as a bipolar plate for polymer electrolyte membrane fuel cells," Energy, Elsevier, vol. 64(C), pages 242-247.
    • Handle: RePEc:eee:energy:v:64:y:2014:i:c:p:242-247
    DOI: 10.1016/j.energy.2013.10.080
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    References listed on IDEAS

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    1. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
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    5. Ren, Zhijun & Zhang, Dongming & Wang, Zaiyi, 2012. "Stacks with TiN/titanium as the bipolar plate for PEMFCs," Energy, Elsevier, vol. 48(1), pages 577-581.
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    1. Kariya, Tetsuro & Yanagimoto, Katsu & Funakubo, Hiroshi & Shudo, Toshio, 2015. "Effects of porous flow field type separators using sintered Ni-based alloy powders on interfacial contact resistances and fuel cell performances," Energy, Elsevier, vol. 87(C), pages 134-141.
    2. Bhosale, Amit C. & Rengaswamy, Raghunathan, 2019. "Interfacial contact resistance in polymer electrolyte membrane fuel cells: Recent developments and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    3. Fan, Hong-Qiang & Wu, Yuan-Min & Su, Shuo & Shi, Dong-Dong & Wang, Xian-Zong & Behnamian, Yashar & Zhang, Jie-Yu & Li, Qian, 2022. "Solution acidity and temperature induced anodic dissolution and degradation of through-plane electrical conductivity of Au/TiN coated metal bipolar plates used in PEMFC," Energy, Elsevier, vol. 254(PC).
    4. Hu, Qinghui & Zhang, Dongming & Fu, Hao, 2015. "Effect of flow-field dimensions on the formability of Fe–Ni–Cr alloy as bipolar plate for PEM (proton exchange membrane) fuel cell," Energy, Elsevier, vol. 83(C), pages 156-163.

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