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Performance evaluation of direct borohydride–hydrogen peroxide fuel cells with electrocatalysts supported on multiwalled carbon nanotubes

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  • Oh, Taek Hyun
  • Jang, Bosun
  • Kwon, Sejin

Abstract

The performance of direct borohydride–hydrogen peroxide fuel cells with electrocatalysts supported on multiwalled carbon nanotubes is evaluated under various conditions. Electrocatalysts are reduced on multiwalled carbon nanotubes by NaH2PO2 and electrodes are investigated using scanning electron microscopy, energy dispersive spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and fuel cell testing. The maximum power density decreases with increasing NaBH4 concentration, likely owing to increases in NaBH4 decomposition and crossover rates and to production of increasing amounts of NaBO2. In contrast, the maximum power density increases with increasing H2O2 concentration, likely owing to increases in reactant concentrations. Moreover, increased operating temperatures improve decomposition and electrochemical reaction rates. A thin membrane increases fuel crossover, whereas a thick membrane decreases the maximum power density; consequently, the Nafion 212 membrane is the optimal thickness for use in fuel cells such as those studied here. Under selected conditions, the maximum power density is 101.9 mW/cm2. As operation time increases, fuel cell performance is degraded by oxidation and Na deposition.

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  • Oh, Taek Hyun & Jang, Bosun & Kwon, Sejin, 2014. "Performance evaluation of direct borohydride–hydrogen peroxide fuel cells with electrocatalysts supported on multiwalled carbon nanotubes," Energy, Elsevier, vol. 76(C), pages 911-919.
  • Handle: RePEc:eee:energy:v:76:y:2014:i:c:p:911-919
    DOI: 10.1016/j.energy.2014.09.002
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    2. Oh, Taek Hyun & Gang, Byeong Gyu & Kim, Hyuntak & Kwon, Sejin, 2015. "Sodium borohydride hydrogen generator using Co–P/Ni foam catalysts for 200 W proton exchange membrane fuel cell system," Energy, Elsevier, vol. 90(P1), pages 1163-1170.
    3. Oh, Taek Hyun, 2021. "Effect of cathode conditions on performance of direct borohydride–hydrogen peroxide fuel cell system for space exploration," Renewable Energy, Elsevier, vol. 178(C), pages 1156-1164.
    4. Hosseini, M.G. & Mahmoodi, R. & Sadeghi Amjadi, M., 2017. "Carbon supported Ni1Pt1 nanocatalyst as superior electrocatalyst with increased power density in direct borohydride-hydrogen peroxide and investigation of cell impedance at different temperatures and ," Energy, Elsevier, vol. 131(C), pages 137-148.
    5. Oh, Taek Hyun & Jang, Bosun & Kwon, Sejin, 2015. "Estimating the energy density of direct borohydride–hydrogen peroxide fuel cell systems for air-independent propulsion applications," Energy, Elsevier, vol. 90(P1), pages 980-986.
    6. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    7. Yin, Xianzhi & Hou, Meiling & Zhu, Kai & Ye, Ke & Yan, Jun & Cao, Dianxue & Zhang, Dongming & Yao, Jiaxin & Wang, Guiling, 2022. "PdCu nanoparticles modified free-standing reduced graphene oxide framework as a highly efficient catalyst for direct borohydride-hydrogen peroxide fuel cell," Renewable Energy, Elsevier, vol. 201(P1), pages 160-170.
    8. Oh, Taek Hyun, 2021. "Gold-based bimetallic electrocatalysts supported on multiwalled carbon nanotubes for direct borohydride–hydrogen peroxide fuel cell," Renewable Energy, Elsevier, vol. 163(C), pages 930-938.
    9. Bizon, Nicu, 2019. "Hybrid power sources (HPSs) for space applications: Analysis of PEMFC/Battery/SMES HPS under unknown load containing pulses," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 14-37.

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