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Effects of reduction temperature and pH value of polyol process on reduced graphene oxide supported Pt electrocatalysts for oxygen reduction reaction

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  • Chou, Chang-Chen
  • Liu, Cheng-Hong
  • Chen, Bing-Hung

Abstract

Effects of the reduction temperature and the pH value of Pt precursor solutions of the polyol reduction process on the resulted Pt electrocatalysts supported on the reduced graphene oxide (Pt/r-GO) nanosheets for the ORR (oxygen reduction reaction) are investigated. The Pt/r-GO catalyst possesses Pt nanoparticles having an average size from 2 to 4 nm and a Pt loading from 13 to 20 wt%. The electrochemical performance of the Pt/r-GO catalysts is examined with the glassy carbon RDE (rotating disk electrode) technique in the O2-saturated HClO4 (0.5 M) solution. The Pt/r-GO catalysts have less ORR limiting currents near 3.5 mA cm−2, but, in general, the more positive onset potentials than the commercial Pt/carbon black catalysts. The number of electron transfer in ORR over the Pt/r-GO catalysts is 3.85 in average, close to that of a 4-electron transfer process.

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  • Chou, Chang-Chen & Liu, Cheng-Hong & Chen, Bing-Hung, 2014. "Effects of reduction temperature and pH value of polyol process on reduced graphene oxide supported Pt electrocatalysts for oxygen reduction reaction," Energy, Elsevier, vol. 70(C), pages 231-238.
    • Handle: RePEc:eee:energy:v:70:y:2014:i:c:p:231-238
    DOI: 10.1016/j.energy.2014.03.118
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    6. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    7. Yuan, Wenjing & Xie, Anjian & Li, Shikuo & Huang, Fangzhi & Zhang, Peigen & Shen, Yuhua, 2016. "High-activity oxygen reduction catalyst based on low-cost bagasse, nitrogen and large specific surface area," Energy, Elsevier, vol. 115(P1), pages 397-403.
    8. Miao, He & Wang, Zhouhang & Wang, Qin & Sun, Shanshan & Xue, Yejian & Wang, Fu & Zhao, Jiapei & Liu, Zhaoping & Yuan, Jinliang, 2018. "A new family of Mn-based perovskite (La1-xYxMnO3) with improved oxygen electrocatalytic activity for metal-air batteries," Energy, Elsevier, vol. 154(C), pages 561-570.
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    10. Yuan, Wenjing & Xie, Anjian & Chen, Ping & Huang, Fangzhi & Li, Shikuo & Shen, Yuhua, 2018. "Combustion reaction-derived nitrogen-doped porous carbon as an effective metal-Free catalyst for the oxygen reduction reaction," Energy, Elsevier, vol. 152(C), pages 333-340.
    11. Lee, W.H. & Yang, H.N. & Park, K.W. & Choi, B.S. & Yi, S.C. & Kim, W.J., 2016. "Synergistic effect of boron/nitrogen co-doping into graphene and intercalation of carbon black for Pt-BCN-Gr/CB hybrid catalyst on cell performance of polymer electrolyte membrane fuel cell," Energy, Elsevier, vol. 96(C), pages 314-324.
    12. Yuan, Wenjing & Xu, Wanghua & Xie, Anjian & Zhang, Hui & Wang, Cuiping & Shen, Yuhua, 2017. "An effective strategy for the preparation of nitrogen-doped carbon from Imperata cylindrica panicle and its use as a metal-free catalyst for the oxygen reduction reaction," Energy, Elsevier, vol. 141(C), pages 1324-1331.

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