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Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation II. Under different operation pressures

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  • Chen, Ben
  • Cai, Yonghua
  • Yu, Yi
  • Wang, Jun
  • Tu, Zhengkai
  • Chan, Siew Hwa

Abstract

Gas purging is an effective method to remove the accumulated nitrogen and liquid water during the dead-end operation of polymer electrode membrane fuel cell (PEMFC). The effect of the operation pressure on the degradation characteristic of single cell is investigated under continuous gas purging cycles. Various diagnostic techniques including electrochemical characterization, physicochemical properties, and microstructure of the membrane electrode assembly (MEA) are applied to characterize the performance of the assembled single cells. After 1000 purging cycles, the single cell exhibits an obvious performance degradation, which can be proven from the change of the electrochemical surface area (ECSA), contact angle, cracks on the membrane and membrane thickness. The single cell with a relatively low oxygen pressure of 50 kPa has serious performance degradation. Comparatively, the assembled PEMFC has an enhanced durability with a high oxygen pressure of 200 kPa during the purging cycles under dead-ended operation mode.

Suggested Citation

  • Chen, Ben & Cai, Yonghua & Yu, Yi & Wang, Jun & Tu, Zhengkai & Chan, Siew Hwa, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation II. Under different operation pressures," Energy, Elsevier, vol. 131(C), pages 50-57.
    • Handle: RePEc:eee:energy:v:131:y:2017:i:c:p:50-57
    DOI: 10.1016/j.energy.2017.05.035
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    Cited by:

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    10. Wan, Yue & Qiu, Diankai & Yi, Peiyun & Peng, Linfa & Lai, Xinmin, 2022. "Design and optimization of gradient wettability pore structure of adaptive PEM fuel cell cathode catalyst layer," Applied Energy, Elsevier, vol. 312(C).
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    12. Chen, Ben & Liu, Qi & Zhang, Cheng & Liu, Yang & Shen, Jun & Tu, Zhengkai, 2022. "Numerical study on water transfer characteristics under joint effect of placement orientation and flow channel size for PEMFC with dead-ended anode," Energy, Elsevier, vol. 254(PB).
    13. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    14. Liu, Zhiyang & Chen, Jian & Liu, Hao & Yan, Chizhou & Hou, Yang & He, Qinggang & Zhang, Jiujun & Hissel, Daniel, 2020. "Anode purge management for hydrogen utilization and stack durability improvement of PEM fuel cell systems," Applied Energy, Elsevier, vol. 275(C).
    15. Yuan, Xian Ming & Guo, Hang & Liu, Jia Xing & Ye, Fang & Ma, Chong Fang, 2018. "Influence of operation parameters on mode switching from electrolysis cell mode to fuel cell mode in a unitized regenerative fuel cell," Energy, Elsevier, vol. 162(C), pages 1041-1051.
    16. Chen, Huicui & Liu, Zhao & Ye, Xichen & Yi, Liu & Xu, Sichen & Zhang, Tong, 2022. "Air flow and pressure optimization for air supply in proton exchange membrane fuel cell system," Energy, Elsevier, vol. 238(PC).
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