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Determination and comparison of combustion kinetics parameters of agricultural biomass from olive trees

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  • Garcia-Maraver, Angela
  • Perez-Jimenez, Jose A.
  • Serrano-Bernardo, Francisco
  • Zamorano, Montserrat

Abstract

Thermogravimetric curves in air, measured for the different types of agricultural residues from olive trees (leaves, pruning and wood) at different heating rates (5, 10, 20, 40, 100 K/min), are subjected to kinetic evaluation by model-based and model-free methods. It is shown that the combustion process in the samples analyzed can be divided into three stages: water removal, roasting phase and char decomposition. At every stage, the activated energy varies with the mass conversion for the kinetic models considered. Its value was determined by the model-free methods, of which Flynn–Wall– Ozawa and Kissinger–Akahira–Sunose were the most appropriate for this purpose and resulted in similar values of activated energy. Once the activation energy was determined, the order of the reactions and the frequency factors of each stage were calculated by means of the Coats–Redfern model-based method in order to complete the determination of the kinetic triplet. From the results obtained, it was deduced that the most feasible reaction order was one.

Suggested Citation

  • Garcia-Maraver, Angela & Perez-Jimenez, Jose A. & Serrano-Bernardo, Francisco & Zamorano, Montserrat, 2015. "Determination and comparison of combustion kinetics parameters of agricultural biomass from olive trees," Renewable Energy, Elsevier, vol. 83(C), pages 897-904.
  • Handle: RePEc:eee:renene:v:83:y:2015:i:c:p:897-904
    DOI: 10.1016/j.renene.2015.05.049
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    11. João Silva & Senhorinha Teixeira & José Teixeira, 2023. "A Review of Biomass Thermal Analysis, Kinetics and Product Distribution for Combustion Modeling: From the Micro to Macro Perspective," Energies, MDPI, vol. 16(18), pages 1-23, September.
    12. Almendros, A.I. & Blázquez, G. & Ronda, A. & Martín-Lara, M.A. & Calero, M., 2017. "Study of the catalytic effect of nickel in the thermal decomposition of olive tree pruning via thermogravimetric analysis," Renewable Energy, Elsevier, vol. 103(C), pages 825-835.
    13. Sirisomboon, Panmanas & Posom, Jetsada, 2019. "On-line measurement of activation energy of ground bamboo using near infrared spectroscopy," Renewable Energy, Elsevier, vol. 133(C), pages 480-488.
    14. Ma, Peiyong & Yang, Jing & Xing, Xianjun & Weihrich, Sebastian & Fan, Fangyu & Zhang, Xianwen, 2017. "Isoconversional kinetics and characteristics of combustion on hydrothermally treated biomass," Renewable Energy, Elsevier, vol. 114(PB), pages 1069-1076.
    15. Ni, Liangmeng & Feng, Zixing & Zhang, Tao & Gao, Qi & Hou, Yanmei & He, Yuyu & Su, Mengfu & Ren, Hao & Hu, Wanhe & Liu, Zhijia, 2022. "Effect of pyrolysis heating rates on fuel properties of molded charcoal: Imitating industrial pyrolysis process," Renewable Energy, Elsevier, vol. 197(C), pages 257-267.
    16. Jiang, Haipeng & Bi, Mingshu & Li, Bei & Gan, Bo & Gao, Wei, 2018. "Combustion behaviors and temperature characteristics in pulverized biomass dust explosions," Renewable Energy, Elsevier, vol. 122(C), pages 45-54.
    17. Paniagua, S. & Escudero, L. & Escapa, C. & Coimbra, R.N. & Otero, M. & Calvo, L.F., 2016. "Effect of waste organic amendments on Populus sp biomass production and thermal characteristics," Renewable Energy, Elsevier, vol. 94(C), pages 166-174.
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