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Pyrolysis Kinetics of Physical Components of Wood and Wood-Polymers Using Isoconversion Method

Author

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  • Wenjia Jin

    (Division of Forestry and Natural Resources, West Virginia University, Morgantown, WV 26506, USA)

  • Kaushlendra Singh

    (Division of Forestry and Natural Resources, West Virginia University, Morgantown, WV 26506, USA)

  • John Zondlo

    (Chemical Engineering, West Virginia University, Morgantown, WV 26506, USA)

Abstract

Two hardwood species, namely red oak and yellow-poplar, were separated into their bark, sapwood and heartwood components. The samples were tested for calorific value, specific gravity, proximate analysis, mineral composition, chemical composition, ultimate analysis, and thermo-chemical decomposition behavior. In addition, the thermo-chemical decomposition behaviors of cellulose, xylan, and lignin polymers were also tested. Thermo-chemical decomposition behavior was assessed using a thermo-gravimetric (TGA) system by heating the sample from 50 °C to 700 °C at the heating rates of 10, 30 and 50 °C/min under nitrogen. The activation energy was calculated for various fractional conversion values using the isoconversion method. The results showed that char yields of lignin, cellulose and xylan were 41.43%, 4.45% and 1.89%, respectively, at the end of pyrolysis. Furthermore, cellulose, xylan and lignin decomposed dramatically in the temperature range of 320 °C to 360 °C, 150 °C to 230 °C and 100 °C to 410 °C, respectively, with decomposition peaks occurring at 340 °C, 200 °C and 340 °C, respectively. In addition, the maximum activation energy for cellulose was 381 kJ/mol at 360 °C and for xylan it was 348 kJ/mol at 210 °C.

Suggested Citation

  • Wenjia Jin & Kaushlendra Singh & John Zondlo, 2013. "Pyrolysis Kinetics of Physical Components of Wood and Wood-Polymers Using Isoconversion Method," Agriculture, MDPI, vol. 3(1), pages 1-21, January.
    • Handle: RePEc:gam:jagris:v:3:y:2013:i:1:p:12-32:d:22802
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    References listed on IDEAS

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    Cited by:

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    4. Fang, Dong-dong & Chen, Jia & Zhang, Li-hui & Duan, Feng & Wang, Ping & Chyang, Chien-Song, 2017. "Experimental study on the shrinkage characteristics and devolatilization time of wood in a turbulent fluidized bed combustor using computed tomography," Energy, Elsevier, vol. 141(C), pages 348-357.
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