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Investigation on prospective bioenergy from pyrolysis of butia seed waste using TGA-FTIR: Assessment of kinetic triplet, thermodynamic parameters and evolved volatiles

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  • Mumbach, Guilherme Davi
  • Alves, José Luiz Francisco
  • da Silva, Jean Constantino Gomes
  • Domenico, Michele Di
  • Marangoni, Cintia
  • Machado, Ricardo Antonio Francisco
  • Bolzan, Ariovaldo

Abstract

The pyrolysis of butia seed waste (BSW) was investigated under a thermogravimetric scale at multiples heating rates (5–40 °C min−1) in a nitrogen atmosphere. First, the pyrolysis behavior of BSW was deconvoluted into four independent reactions using the Asym2Sig fitting function. The kinetic triplets (activation energies, pre-exponential factors, and reaction models) were acquired using four isoconversional methods, the compensation effect method and the master plot method. The kinetic parameters estimated were in the range of 111.5–190.9 kJ mol−1 for the average activation energy and 1.55 × 1010–2.89 × 1014 min−1 for the pre-exponential factor. According to the master plot method, the pyrolysis of BSW is described by the summative effect of geometrical contraction and n-order reaction mechanisms. A multi-component kinetic approach was suitable for capturing the complexity involved in the pyrolysis of BSW, with a coefficient of determination (R2) > 0.95 and quality of fit (QOF) > 93%. Pyrolytic conversion of BSW into biofuels is characterized by an endothermic nature (ΔH > 0) and low reactivity (ΔS < 0). The volatile products evolved from the pyrolytic decomposition of BSW were characterized using the integrated TGA-FTIR system, which confirmed the presence of high-energy compounds (aromatics) and useful chemicals (aldehyde, ketone, esters, ether, and alcohols).

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  • Mumbach, Guilherme Davi & Alves, José Luiz Francisco & da Silva, Jean Constantino Gomes & Domenico, Michele Di & Marangoni, Cintia & Machado, Ricardo Antonio Francisco & Bolzan, Ariovaldo, 2022. "Investigation on prospective bioenergy from pyrolysis of butia seed waste using TGA-FTIR: Assessment of kinetic triplet, thermodynamic parameters and evolved volatiles," Renewable Energy, Elsevier, vol. 191(C), pages 238-250.
    • Handle: RePEc:eee:renene:v:191:y:2022:i:c:p:238-250
    DOI: 10.1016/j.renene.2022.03.159
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    References listed on IDEAS

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    1. Badshah, Syed Lal & Shah, Zahir & Francisco Alves, José Luiz & Gomes da Silva, Jean Constantino & Iqbal, Arshad, 2021. "Pyrolysis of the freshwater macroalgae Spirogyra crassa: Evaluating its bioenergy potential using kinetic triplet and thermodynamic parameters," Renewable Energy, Elsevier, vol. 179(C), pages 1169-1178.
    2. Slopiecka, Katarzyna & Bartocci, Pietro & Fantozzi, Francesco, 2012. "Thermogravimetric analysis and kinetic study of poplar wood pyrolysis," Applied Energy, Elsevier, vol. 97(C), pages 491-497.
    3. Mumbach, Guilherme Davi & Alves, José Luiz Francisco & da Silva, Jean Constantino Gomes & Domenico, Michele Di & Arias, Santiago & Pacheco, Jose Geraldo A. & Marangoni, Cintia & Machado, Ricardo Anton, 2022. "Prospecting pecan nutshell pyrolysis as a source of bioenergy and bio-based chemicals using multicomponent kinetic modeling, thermodynamic parameters estimation, and Py-GC/MS analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    4. Alves, José Luiz Francisco & da Silva, Jean Constantino Gomes & Mumbach, Guilherme Davi & de Sena, Rennio Felix & Machado, Ricardo Antonio Francisco & Marangoni, Cintia, 2022. "Prospection of catole coconut (Syagrus cearensis) as a new bioenergy feedstock: Insights from physicochemical characterization, pyrolysis kinetics, and thermodynamics parameters," Renewable Energy, Elsevier, vol. 181(C), pages 207-218.
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