IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v131y2017icp186-197.html
   My bibliography  Save this article

Fast pyrolysis of sweet sorghum bagasse in a fluidized bed reactor: Product characterization and comparison with vapors generated in analytical pyrolysis

Author

Listed:
  • Carvalho, Wender Santana
  • Santana Júnior, José Alair
  • de Oliveira, Tiago José Pires
  • Ataíde, Carlos Henrique

Abstract

Lignocellulosic biomass can be used as an alternative for the production of fuels and chemical feedstocks using thermochemical conversion processes, such as pyrolysis. This study aims to perform the fast pyrolysis of sweet sorghum bagasse in a fluidized bed unit, comparing the results obtained with the products from analytical pyrolysis. Furthermore, the apparent activation energy of thermal decomposition of biomass was determined using two global reaction models. The estimated values of apparent activation energy ranged from 106.2 to 203.3 kJ/mol. The main compounds identified in the vapors generated in the analytical pyrolysis were acetic acid, isoprene, methyl pyruvate, furfural, 2,3-dihydrobenzofuran, 4-hydroxy-3-methylacetophenone and 5-hydroxymethylfurfural. In the bio-oil produced in the fluidized bed unit, the main compounds identified were benzene, acetic acid, isoprene, 3-methoxypropanal, toluene, furfural, 1,1-dimethoxycyclohexane and phenol. The difference between the identified compounds could be attributed to the solvent used, the efficiency of the condensation system, the occurrence of secondary reactions during the fast pyrolysis process in the fluidized bed reactor and the polymerization after the condensation of the vapors produced.

Suggested Citation

  • Carvalho, Wender Santana & Santana Júnior, José Alair & de Oliveira, Tiago José Pires & Ataíde, Carlos Henrique, 2017. "Fast pyrolysis of sweet sorghum bagasse in a fluidized bed reactor: Product characterization and comparison with vapors generated in analytical pyrolysis," Energy, Elsevier, vol. 131(C), pages 186-197.
    • Handle: RePEc:eee:energy:v:131:y:2017:i:c:p:186-197
    DOI: 10.1016/j.energy.2017.05.058
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217308150
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.05.058?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Slopiecka, Katarzyna & Bartocci, Pietro & Fantozzi, Francesco, 2012. "Thermogravimetric analysis and kinetic study of poplar wood pyrolysis," Applied Energy, Elsevier, vol. 97(C), pages 491-497.
    2. Butler, Eoin & Devlin, Ger & Meier, Dietrich & McDonnell, Kevin, 2011. "A review of recent laboratory research and commercial developments in fast pyrolysis and upgrading," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 4171-4186.
    3. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Liu, Rongtang & Liu, Ming & Fan, Peipei & Zhao, Yongliang & Yan, Junjie, 2018. "Thermodynamic study on a novel lignite poly-generation system of electricity-gas-tar integrated with pre-drying and pyrolysis," Energy, Elsevier, vol. 165(PB), pages 140-152.
    2. Chen, Dongyu & Gao, Dongxiao & Capareda, Sergio C. & E, Shuang & Jia, Fengrui & Wang, Ying, 2020. "Influences of hydrochloric acid washing on the thermal decomposition behavior and thermodynamic parameters of sweet sorghum stalk," Renewable Energy, Elsevier, vol. 148(C), pages 1244-1255.
    3. Zheng, Ji-Lu & Zhu, Ya-Hong & Zhu, Ming-Qiang & Wu, Hai-Tang & Sun, Run-Cang, 2018. "Bio-oil gasification using air - Steam as gasifying agents in an entrained flow gasifier," Energy, Elsevier, vol. 142(C), pages 426-435.
    4. Stamenković, Olivera S. & Siliveru, Kaliramesh & Veljković, Vlada B. & Banković-Ilić, Ivana B. & Tasić, Marija B. & Ciampitti, Ignacio A. & Đalović, Ivica G. & Mitrović, Petar M. & Sikora, Vladimir Š., 2020. "Production of biofuels from sorghum," Renewable and Sustainable Energy Reviews, Elsevier, vol. 124(C).
    5. Andrew N. Amenaghawon & Chinedu L. Anyalewechi & Charity O. Okieimen & Heri Septya Kusuma, 2021. "Biomass pyrolysis technologies for value-added products: a state-of-the-art review," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(10), pages 14324-14378, October.
    6. Mariana Abreu & Luís Silva & Belina Ribeiro & Alice Ferreira & Luís Alves & Susana M. Paixão & Luísa Gouveia & Patrícia Moura & Florbela Carvalheiro & Luís C. Duarte & Ana Luisa Fernando & Alberto Rei, 2022. "Low Indirect Land Use Change (ILUC) Energy Crops to Bioenergy and Biofuels—A Review," Energies, MDPI, vol. 15(12), pages 1-68, June.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hao Luo & Lukasz Niedzwiecki & Amit Arora & Krzysztof Mościcki & Halina Pawlak-Kruczek & Krystian Krochmalny & Marcin Baranowski & Mayank Tiwari & Anshul Sharma & Tanuj Sharma & Zhimin Lu, 2020. "Influence of Torrefaction and Pelletizing of Sawdust on the Design Parameters of a Fixed Bed Gasifier," Energies, MDPI, vol. 13(11), pages 1-19, June.
    2. Dai, Leilei & Wang, Yunpu & Liu, Yuhuan & Ruan, Roger & He, Chao & Yu, Zhenting & Jiang, Lin & Zeng, Zihong & Tian, Xiaojie, 2019. "Integrated process of lignocellulosic biomass torrefaction and pyrolysis for upgrading bio-oil production: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 20-36.
    3. Siddiqi, Hammad & Bal, Manisha & Kumari, Usha & Meikap, B.C., 2020. "In-depth physiochemical characterization and detailed thermo-kinetic study of biomass wastes to analyze its energy potential," Renewable Energy, Elsevier, vol. 148(C), pages 756-771.
    4. Kabir, G. & Hameed, B.H., 2017. "Recent progress on catalytic pyrolysis of lignocellulosic biomass to high-grade bio-oil and bio-chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 945-967.
    5. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    6. Gorugantu SriBala & Hans‐Heinrich Carstensen & Kevin M. Van Geem & Guy B. Marin, 2019. "Measuring biomass fast pyrolysis kinetics: State of the art," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 8(2), March.
    7. Zhang, Chenting & Chao, Li & Zhang, Zhanming & Zhang, Lijun & Li, Qingyin & Fan, Huailin & Zhang, Shu & Liu, Qing & Qiao, Yingyun & Tian, Yuanyu & Wang, Yi & Hu, Xun, 2021. "Pyrolysis of cellulose: Evolution of functionalities and structure of bio-char versus temperature," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    8. Aboagye, D. & Banadda, N. & Kiggundu, N. & Kabenge, I., 2017. "Assessment of orange peel waste availability in ghana and potential bio-oil yield using fast pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 814-821.
    9. Yang, Yantao & Qu, Xia & Huang, Guorun & Ren, Suxia & Dong, Lili & Sun, Tanglei & Liu, Peng & Li, Yanling & Lei, Tingzhou & Cai, Junmeng, 2023. "Insight into lignocellulosic biomass torrefaction kinetics with case study of pinewood sawdust torrefaction," Renewable Energy, Elsevier, vol. 215(C).
    10. Yang, Haiyue & Wang, Yazhou & Yu, Qianqian & Cao, Guoliang & Yang, Rue & Ke, Jiaona & Di, Xin & Liu, Feng & Zhang, Wenbo & Wang, Chengyu, 2018. "Composite phase change materials with good reversible thermochromic ability in delignified wood substrate for thermal energy storage," Applied Energy, Elsevier, vol. 212(C), pages 455-464.
    11. Chen, Wei-Hsin & Lin, Bo-Jhih, 2016. "Characteristics of products from the pyrolysis of oil palm fiber and its pellets in nitrogen and carbon dioxide atmospheres," Energy, Elsevier, vol. 94(C), pages 569-578.
    12. Yang, Yuhan & Wang, Tiancheng & Hu, Hongyun & Yao, Dingding & Zou, Chan & Xu, Kai & Li, Xian & Yao, Hong, 2021. "Influence of partial components removal on pyrolysis behavior of lignocellulosic biowaste in molten salts," Renewable Energy, Elsevier, vol. 180(C), pages 616-625.
    13. Jun Sheng Teh & Yew Heng Teoh & Heoy Geok How & Thanh Danh Le & Yeoh Jun Jie Jason & Huu Tho Nguyen & Dong Lin Loo, 2021. "The Potential of Sustainable Biomass Producer Gas as a Waste-to-Energy Alternative in Malaysia," Sustainability, MDPI, vol. 13(7), pages 1-31, April.
    14. Primaz, Carmem T. & Ribes-Greus, Amparo & Jacques, Rosângela A., 2021. "Valorization of cotton residues for production of bio-oil and engineered biochar," Energy, Elsevier, vol. 235(C).
    15. Kluska, Jacek & Turzyński, Tomasz & Ochnio, Mateusz & Kardaś, Dariusz, 2020. "Characteristics of ash formation in the process of combustion of pelletised leather tannery waste and hardwood pellets," Renewable Energy, Elsevier, vol. 149(C), pages 1246-1253.
    16. Jie Gu & Cheng Tung Chong & Guo Ren Mong & Jo-Han Ng & William Woei Fong Chong, 2023. "Determination of Pyrolysis and Kinetics Characteristics of Chicken Manure Using Thermogravimetric Analysis Coupled with Particle Swarm Optimization," Energies, MDPI, vol. 16(4), pages 1-22, February.
    17. Mei Yin Ong & Nor-Insyirah Syahira Abdul Latif & Hui Yi Leong & Bello Salman & Pau Loke Show & Saifuddin Nomanbhay, 2019. "Characterization and Analysis of Malaysian Macroalgae Biomass as Potential Feedstock for Bio-Oil Production," Energies, MDPI, vol. 12(18), pages 1-14, September.
    18. Bergthorson, Jeffrey M. & Thomson, Murray J., 2015. "A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1393-1417.
    19. Qin, Fanzhi & Zhang, Chen & Zeng, Guangming & Huang, Danlian & Tan, Xiaofei & Duan, Abing, 2022. "Lignocellulosic biomass carbonization for biochar production and characterization of biochar reactivity," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    20. Sitek, Tomáš & Pospíšil, Jiří & Poláčik, Ján & Špiláček, Michal & Varbanov, Petar, 2019. "Fine combustion particles released during combustion of unit mass of beechwood," Renewable Energy, Elsevier, vol. 140(C), pages 390-396.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:131:y:2017:i:c:p:186-197. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.