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Co-pyrolysis of bamboo sawdust and plastic: Synergistic effects and kinetics

Author

Listed:
  • Alam, Mahboob
  • Bhavanam, Anjireddy
  • Jana, Ashirbad
  • Viroja, Jaimin kumar S.
  • Peela, Nageswara Rao

Abstract

The co-pyrolysis of bamboo sawdust (BSD) and linear low-density polyethylene (LLDPE) is studied for the first time using thermogravimetric analysis (TGA) in the temperature range of 30–900 °C at heating rates 5, 10 and 20 °C·min−1. A blend containing 25 wt% BSD and 75 wt% LLDPE (BP1:3) shows the highest synergism as compared to other blends studied. The activation energy drop (36% with respect to biomass) is also highest with this blend. The kinetic parameters are determined using three models based on the isoconversional method: Kissinger-Akahira-Sunose (KAS), Ozawa-Flynn-Wall (OFW), and Friedman (FM) models. The mean values of apparent activation energy for the decomposition of blends (BP3:1 (75 wt% BSD and 25 wt% LLDPE), BP1:1 (50 wt% BSD and 50 wt% LLDPE) and BP1:3) are determined to be 357, 371 and 143 kJ mol−1 from KAS, 368, 400 and 165 kJ mol−1 from OFW and 468, 356 and 255 kJ mol−1 from FM, respectively. The reaction follows a multistep mechanism as depicted by Criado’s master plot. The decomposition of the blend BP1:3 follows a nucleation growth (A2) model in the lower conversion range and diffusion (D2) model in the higher conversion range.

Suggested Citation

  • Alam, Mahboob & Bhavanam, Anjireddy & Jana, Ashirbad & Viroja, Jaimin kumar S. & Peela, Nageswara Rao, 2020. "Co-pyrolysis of bamboo sawdust and plastic: Synergistic effects and kinetics," Renewable Energy, Elsevier, vol. 149(C), pages 1133-1145.
    • Handle: RePEc:eee:renene:v:149:y:2020:i:c:p:1133-1145
    DOI: 10.1016/j.renene.2019.10.103
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    References listed on IDEAS

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