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Influence of Operating Conditions on the Thermal Behavior and Kinetics of Pine Wood Particles Using Thermogravimetric Analysis

Author

Listed:
  • Lelis Gonzaga Fraga

    (Department of Mechanical Engineering, Faculty of Engineering, Science and Technology, Universidade Nacional Timor Lorosa’e, Díli PO.Box 317, Timor-Leste)

  • João Silva

    (MEtRICs Research Centre, University of Minho, 4800-058 Guimarães, Portugal
    ALGORITMI Research Centre, University of Minho, 4800-058 Guimarães, Portugal)

  • Senhorinha Teixeira

    (ALGORITMI Research Centre, University of Minho, 4800-058 Guimarães, Portugal)

  • Delfim Soares

    (CMEMS Research Centre, University of Minho, 4800-058 Guimarães, Portugal)

  • Manuel Ferreira

    (MEtRICs Research Centre, University of Minho, 4800-058 Guimarães, Portugal)

  • José Teixeira

    (MEtRICs Research Centre, University of Minho, 4800-058 Guimarães, Portugal)

Abstract

Although there are many studies available in literature about biomass pyrolysis or devolatilization using thermogravimetric analysis (TGA), the effects of important operating parameters have infrequently been investigated for pine wood particle combustion. Consequently, the present study investigates the influence of particle size (63 µm to 1 mm), heating rate (5 to 243 °C/min), and air flow rate (10 to 150 mL/min) on the mass loss of pine wood using TGA. Additionally, the kinetic parameters considering the different conditions were determined to be incorporated in a numerical model. The effect of the heating rate on the thermal decomposition behavior has shown that the thermogravimetric and derivative thermogravimetric curves were shifted to higher temperatures with the increase in the heating rate. In this way, the heating rate affects the temperature at which the highest mass loss rate occurs as well as its value. Furthermore, comparing the higher and lower heating rate, the time to complete the combustion and the release are around 22 times higher when a higher heating rate is applied. On the other hand, the effects of four different air flow rates were compared and similar results were obtained. Regarding the kinetic analysis, it was verified at various heating and air flow rates with different particle sizes that the highest activation energy was mostly obtained during char combustion (~131–229 kJ/mol). Furthermore, in the second stage higher heating rates had the highest reactivity, and in the third stage there were not too many changes. In terms of the effect of air flow rates, a maximum variation of 15 kJ/mol was obtained in the third stage and, therefore, no significant effect on the reactivity for all particles was found.

Suggested Citation

  • Lelis Gonzaga Fraga & João Silva & Senhorinha Teixeira & Delfim Soares & Manuel Ferreira & José Teixeira, 2020. "Influence of Operating Conditions on the Thermal Behavior and Kinetics of Pine Wood Particles Using Thermogravimetric Analysis," Energies, MDPI, vol. 13(11), pages 1-22, June.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:11:p:2756-:d:365594
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    References listed on IDEAS

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    1. Garcia-Maraver, Angela & Perez-Jimenez, Jose A. & Serrano-Bernardo, Francisco & Zamorano, Montserrat, 2015. "Determination and comparison of combustion kinetics parameters of agricultural biomass from olive trees," Renewable Energy, Elsevier, vol. 83(C), pages 897-904.
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    2. Min Wei & Fu Yang & Xuyan Song & Ran Li & Xi Pan & Qiang Gao & Yunlu He & Mingqiao Ye & Hongyun Hu, 2020. "Extraction of Nitrogen Compounds from Tobacco Waste via Thermal Treatment," Energies, MDPI, vol. 13(18), pages 1-11, September.
    3. João Silva & Senhorinha Teixeira & José Teixeira, 2023. "A Review of Biomass Thermal Analysis, Kinetics and Product Distribution for Combustion Modeling: From the Micro to Macro Perspective," Energies, MDPI, vol. 16(18), pages 1-23, September.
    4. Sergio Paniagua & Alba Prado-Guerra & Ana Isabel Neto & Teresa Nunes & Luís Tarelho & Célia Alves & Luis Fernando Calvo, 2020. "Influence of Varieties and Organic Fertilizer in the Elaboration of a New Poplar-Straw Pellet and Its Emissions in a Domestic Boiler," Energies, MDPI, vol. 13(23), pages 1-17, November.

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