IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v149y2020icp535-548.html
   My bibliography  Save this article

Alkane from hydrodeoxygenation (HDO) combined with in-situ multistage condensation of biomass continuous pyrolysis bio-oil via mixed supports catalyst Ni/HZSM-5-γ-Al2O3

Author

Listed:
  • Li, Zhiyu
  • Xu, Xiwei
  • Jiang, Enchen
  • Han, Ping
  • Sun, Yan
  • Zhou, Ling
  • Zhong, Peidong
  • Fan, Xudong

Abstract

Faced with fossil fuel depletion and increasing environmental concerns, the conversion of renewable biomass into fuels or chemicals is promising but extremely challenging due to the inertness and complexity of biomass. Therefore, in situ multistage condensation combined with the HDO of pyrolysis bio-oil was chosen to reduce the complexity and improve the quality of bio-oil. In addition, the activity and stability of the catalyst was enhanced. The bio-oil obtained via continuous pyrolysis was divided into four-stage depending on their boiling point via in situ multistage condensation. After HDO, the relative content of long-chain alkanes was over 80% for each stage bio-oil via mixed supported Ni/HZSM-5-γ-Al2O3 catalyst. Especially, the main components in the 3rd oil (aqueous phase) were n-heneicosane (31.60%), icosane (5.13%) and n-heptadecane (4.36%) based on the highest HDO ratio. Moreover, the reaction mechanism was discussed via the HDO of model bio-oil. The main reaction pathway consisted of hydrogenation and dehydration reactions (HYD pathway), and a side reaction was the direct deoxygenation route (DDO pathway). This work provides a general and efficient pathway for directly converting biomass into valuable long chain alkanes.

Suggested Citation

  • Li, Zhiyu & Xu, Xiwei & Jiang, Enchen & Han, Ping & Sun, Yan & Zhou, Ling & Zhong, Peidong & Fan, Xudong, 2020. "Alkane from hydrodeoxygenation (HDO) combined with in-situ multistage condensation of biomass continuous pyrolysis bio-oil via mixed supports catalyst Ni/HZSM-5-γ-Al2O3," Renewable Energy, Elsevier, vol. 149(C), pages 535-548.
  • Handle: RePEc:eee:renene:v:149:y:2020:i:c:p:535-548
    DOI: 10.1016/j.renene.2019.10.035
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119315265
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2019.10.035?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Defever, Fabrice & Imbruno, Michele & Kneller, Richard, 2020. "Trade liberalization, input intermediaries and firm productivity: Evidence from China," Journal of International Economics, Elsevier, vol. 126(C).
    2. Kapetanios, George & Price, Simon & Tasiou, Menelaos & Ventouri, Alexia, 2021. "State-level wage Phillips curves," Econometrics and Statistics, Elsevier, vol. 18(C), pages 1-11.
    3. Defever, Fabrice & Reyes, José-Daniel & Riaño, Alejandro & Varela, Gonzalo, 2020. "All these worlds are yours, except india: The effectiveness of cash subsidies to export in nepal," European Economic Review, Elsevier, vol. 128(C).
    4. Spyros Galanis, 2021. "Speculative trade and the value of public information," Journal of Public Economic Theory, Association for Public Economic Theory, vol. 23(1), pages 53-68, February.
    5. Bai, Ye & Girma, Sourafel & Riaño, Alejandro, 2024. "Corporate acquisitions and firm-level uncertainty: Domestic versus cross-border deals," Journal of International Money and Finance, Elsevier, vol. 140(C).
    6. Bharadwaj, P. & Doiron, D. & Fiebig, D. G. & Suziedelyte, A., 2020. "Psychological Costs of Migration: Home Country Natural Disasters and Mental Health," Working Papers 20/03, Department of Economics, City University London.
    7. Emara, Noha & El Said, Ayah & Pearlman, Joseph, 2019. "On the Impact of Financial Inclusion on Financial Stability and Inequality: The Role of Macroprudential Policies," MPRA Paper 99258, University Library of Munich, Germany.
    8. Galanis, S. & Ioannou, C. & Kotronis, S., 2019. "Information Aggregation Under Ambiguity: Theory and Experimental Evidence," Working Papers 20/05, Department of Economics, City University London.
    9. Paul Levine & Joseph Pearlman & Stephen Wright & Bo Yang, 2019. "Information, VARs and DSGE Models," School of Economics Discussion Papers 1619, School of Economics, University of Surrey.
    10. Offiaeli, K. & Yaman, F., 2020. "Social Norms as a Cost-Effective Measure of Managing Transport Demand: Evidence from an Experiment on the London Underground," Working Papers 20/07, Department of Economics, City University London.
    11. Che, X. & Huang, Y. & Zhang, L., 2020. "Supervisory Efficiency and Collusion in a Multiple-Agent Hierarchy," Working Papers 20/01, Department of Economics, City University London.
    12. Aligishiev, Z. & Ben-Gad, M. & Pearlman, J., 2020. "Evaluating Historical Episodes using Shock Decompositions in the DSGE Model," Working Papers 20/10, Department of Economics, City University London.
    13. Che, X. & Katayama, H. & Lee, P., 2020. "Willingness to Pay for Brand Reputation: Lessons from the Volkswagen Diesel Emissions Scandal," Working Papers 20/02, Department of Economics, City University London.
    14. Laliotis, Ioannis & Minos, Dimitrios, 2020. "Spreading the disease: The role of culture," SocArXiv z4ndc, Center for Open Science.
    15. Mamageishvili, A. & Schlegel, J. C., 2019. "Optimal Smart Contracts with Costly Verification," Working Papers 19/13, Department of Economics, City University London.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Alderremy, A.A. & Saad, Khaled M. & Agarwal, Praveen & Aly, Shaban & Jain, Shilpi, 2020. "Certain new models of the multi space-fractional Gardner equation," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 545(C).
    2. Coma, Julià & Chàfer, Marta & Pérez, Gabriel & Cabeza, Luisa F., 2020. "How internal heat loads of buildings affect the effectiveness of vertical greenery systems? An experimental study," Renewable Energy, Elsevier, vol. 151(C), pages 919-930.
    3. Rotundo, G. & Ausloos, M., 2007. "Microeconomic co-evolution model for financial technical analysis signals," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 373(C), pages 569-585.
    4. Nie, Binjian & Zou, Boyang & She, Xiaohui & Zhang, Tongtong & Li, Yongliang & Ding, Yulong, 2020. "Development of a heat transfer coefficient based design method of a thermal energy storage device for transport air-conditioning applications," Energy, Elsevier, vol. 196(C).
    5. Zhu, H.B. & Zhou, Y.J. & Wu, W.J., 2020. "Modeling traffic flow mixed with automated vehicles considering drivers ’ character difference," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 549(C).
    6. Yoo, Yeawon & Escobedo, Adolfo R. & Skolfield, J. Kyle, 2020. "A new correlation coefficient for comparing and aggregating non-strict and incomplete rankings," European Journal of Operational Research, Elsevier, vol. 285(3), pages 1025-1041.
    7. Shi, Xin & Jiang, Haizhou & Li, Huan & Xu, Dong, 2020. "Maritime cluster research: Evolutionary classification and future development," Transportation Research Part A: Policy and Practice, Elsevier, vol. 133(C), pages 237-254.
    8. Fa, Kwok Sau, 2020. "A class of nonlinear Langevin equation with the drift and diffusion coefficients separable in time and space driven by different noises," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 545(C).
    9. Liu, Changqing & He, Yigang & Peng, Guanghan, 2019. "The stabilization effect of self-delayed flux integral for two-lane lattice hydrodynamic model," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 535(C).
    10. Torres-Vargas, G. & Fossion, R. & Méndez-Bermúdez, J.A., 2020. "Normal mode analysis of spectra of random networks," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 545(C).
    11. Kowalski, A.M. & Plastino, A., 2019. "A nonlinear matter-field Hamiltonian analyzed with Renyi and Tsallis statistics," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 535(C).
    12. Cebreiros, Florencia & Clavijo, Leonardo & Boix, Elzeario & Ferrari, Mario Daniel & Lareo, Claudia, 2020. "Integrated valorization of eucalyptus sawdust within a biorefinery approach by autohydrolysis and organosolv pretreatments," Renewable Energy, Elsevier, vol. 149(C), pages 115-127.
    13. Algaba, Encarnación & Béal, Sylvain & Fragnelli, Vito & Llorca, Natividad & Sánchez-Soriano, Joaquin, 2019. "Relationship between labeled network games and other cooperative games arising from attributes situations," Economics Letters, Elsevier, vol. 185(C).
    14. Nunes, Maria Eugênia Silva & de Mello Silva, Érica & Martins, Paulo H.L. & Florencio, João & Plascak, J.A., 2020. "Dynamics of the one-dimensional isotropic Heisenberg model with Dzyaloshinskii–Moryia interaction in a random transverse field," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 541(C).
    15. Wu, Jing Cynthia & Zhang, Ji, 2019. "A shadow rate New Keynesian model," Journal of Economic Dynamics and Control, Elsevier, vol. 107(C), pages 1-1.
    16. Aldakheel, F. & Ismail, M.S. & Hughes, K.J. & Ingham, D.B. & Ma, L. & Pourkashanian, M. & Cumming, D. & Smith, R., 2020. "Gas permeability, wettability and morphology of gas diffusion layers before and after performing a realistic ex-situ compression test," Renewable Energy, Elsevier, vol. 151(C), pages 1082-1091.
    17. Zhu, Wen-Xing & Zhang, Jing-Yu & Song, Ze-Rui, 2019. "Study on braking process of vehicles at the signalized intersection based on car-following theory," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 523(C), pages 1306-1314.
    18. Liu, Hong & Gao, Yuhang & Tisdell, Clement A. & Wang, Fei, 2020. "Are housing property rights important for fertility outcomes in China? Empirical evidence and policy issues," Economic Analysis and Policy, Elsevier, vol. 65(C), pages 211-223.
    19. Nagatani, Takashi, 2019. "Infection promotes species coexistence: Rock–paper–scissors game with epidemic on graphs," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 535(C).
    20. Jiang, Mengmeng & Westerholm, Maria & Qiao, Wei & Wandera, Simon M. & Dong, Renjie, 2020. "High rate anaerobic digestion of swine wastewater in an anaerobic membrane bioreactor," Energy, Elsevier, vol. 193(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:149:y:2020:i:c:p:535-548. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.