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Influence of blending vegetable oil methyl esters on biodiesel fuel properties: Oxidative stability and cold flow properties

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  • Serrano, Marta
  • Oliveros, Rubén
  • Sánchez, Marcos
  • Moraschini, Andrea
  • Martínez, Mercedes
  • Aracil, José

Abstract

Properties of biodiesel can be related to the chemical composition of the biomass source used in transesterification. Saturated fatty acids confer high oxidative stability, while unsaturated fatty acids improve the cold flow properties, which are also influenced by the chain length. In the present study, blends of biodiesel produced from different vegetable oils were evaluated in order to obtain the proper blend to fulfill the European Standard EN14214 in terms of oxidative stability and cold flow properties. Citric acid was used to purify the methyl ester phase. Oxidative stability resulted highly dependent on polyunsaturated fatty esters while fatty ester chain length is a determining factor in cold flow performance of the blends. A preliminary study of the effectiveness of a commercial additive (a Poly alkyl methacrylate) in improving methyl ester flow at low temperatures was done, but no significant changes were found.

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  • Serrano, Marta & Oliveros, Rubén & Sánchez, Marcos & Moraschini, Andrea & Martínez, Mercedes & Aracil, José, 2014. "Influence of blending vegetable oil methyl esters on biodiesel fuel properties: Oxidative stability and cold flow properties," Energy, Elsevier, vol. 65(C), pages 109-115.
    • Handle: RePEc:eee:energy:v:65:y:2014:i:c:p:109-115
    DOI: 10.1016/j.energy.2013.11.072
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    6. Yusuff, Adeyinka S. & Bhonsle, Aman K. & Bangwal, Dinesh P. & Atray, Neeraj, 2021. "Development of a barium-modified zeolite catalyst for biodiesel production from waste frying oil: Process optimization by design of experiment," Renewable Energy, Elsevier, vol. 177(C), pages 1253-1264.
    7. Sierra-Cantor, Jonathan Fabián & Guerrero-Fajardo, Carlos Alberto, 2017. "Methods for improving the cold flow properties of biodiesel with high saturated fatty acids content: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 774-790.
    8. Murphy, Fionnuala & Devlin, Ger & Deverell, Rory & McDonnell, Kevin, 2014. "Potential to increase indigenous biodiesel production to help meet 2020 targets – An EU perspective with a focus on Ireland," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 154-170.
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    11. Go, Alchris Woo & Tran Nguyen, Phuong Lan & Huynh, Lien Huong & Liu, Ying-Tsung & Sutanto, Sylviana & Ju, Yi-Hsu, 2014. "Catalyst free esterification of fatty acids with methanol under subcritical condition," Energy, Elsevier, vol. 70(C), pages 393-400.
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