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A review on the oxidation stability of biodiesel

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  • Yaakob, Zahira
  • Narayanan, Binitha N.
  • Padikkaparambil, Silija
  • Unni K., Surya
  • Akbar P., Mohammed

Abstract

Biodiesel consists of fatty acid monoalkyl esters and is derived from feedstocks, such as vegetable oils, used cooking oils and animal fats. Biodiesel is considered to be a promising alternative biofuel. Recently, biodiesel has received additional attention and intense research has been performed in this field all over the world due to its lower environmental impact compared to the conventional diesel fuels. The central drawback of biodiesel is its susceptible nature to oxidation due to the presence of unsaturated fatty acid portion in the ester. Oxidative degradation occurs in biodiesel on aerobic contact during storage as well as with metal contaminants. Antioxidants are very effective for the eradication of those oxidation stability problems. This article presents an overview of the factors affecting the oxidation stability of biodiesel and the methods available for the prediction of oxidation stability. The effect of antioxidants in preventing the oxidation of biodiesel is also discussed.

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  • Yaakob, Zahira & Narayanan, Binitha N. & Padikkaparambil, Silija & Unni K., Surya & Akbar P., Mohammed, 2014. "A review on the oxidation stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 136-153.
    • Handle: RePEc:eee:rensus:v:35:y:2014:i:c:p:136-153
    DOI: 10.1016/j.rser.2014.03.055
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    5. Singh, Paramvir & Varun, & Chauhan, S.R. & Kumar, Niraj, 2016. "A review on methodology for complete elimination of diesel from CI engines using mixed feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1110-1125.
    6. Mazumdar, Purabi & Singh, Pooja & Babu, Subramanian & Siva, Ramamoorthy & Harikrishna, Jennifer Ann, 2018. "An update on biological advancement of Jatropha curcas L.: New insight and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 903-917.
    7. Goh, Brandon Han Hoe & Ong, Hwai Chyuan & Cheah, Mei Yee & Chen, Wei-Hsin & Yu, Kai Ling & Mahlia, Teuku Meurah Indra, 2019. "Sustainability of direct biodiesel synthesis from microalgae biomass: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 59-74.
    8. Bukkarapu, Kiran Raj & Krishnasamy, Anand, 2022. "A critical review on available models to predict engine fuel properties of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    9. Wang, Wenchao & Liu, Huili & Li, Fashe & Wang, Hua & Ma, Xin & Li, Jingjing & Zhou, Li & Xiao, Quan, 2021. "Effects of unsaturated fatty acid methyl esters on the oxidation stability of biodiesel determined by gas chromatography-mass spectrometry and information entropy methods," Renewable Energy, Elsevier, vol. 175(C), pages 880-886.
    10. Kumar, Mukesh & Sharma, M.P., 2015. "Assessment of potential of oils for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 814-823.
    11. Al-lwayzy, Saddam H. & Yusaf, Talal, 2017. "Diesel engine performance and exhaust gas emissions using Microalgae Chlorella protothecoides biodiesel," Renewable Energy, Elsevier, vol. 101(C), pages 690-701.
    12. Jemima Romola, C.V. & Meganaharshini, M. & Rigby, S.P. & Ganesh Moorthy, I. & Shyam Kumar, R. & Karthikumar, Sankar, 2021. "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    13. Shen, Zijia & Wang, Feipeng & Wang, Zhiqing & Li, Jian, 2021. "A critical review of plant-based insulating fluids for transformer: 30-year development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    14. Roveda, Ana Carolina & Comin, Marina & Caires, Anderson Rodrigues Lima & Ferreira, Valdir Souza & Trindade, Magno Aparecido Gonçalves, 2016. "Thermal stability enhancement of biodiesel induced by a synergistic effect between conventional antioxidants and an alternative additive," Energy, Elsevier, vol. 109(C), pages 260-265.
    15. Varatharajan, K. & Pushparani, D.S., 2018. "Screening of antioxidant additives for biodiesel fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2017-2028.
    16. Chen, Tao & Hu, Run-Ze & Yao, Xiao-Hui & Yang, Qiang & Shuai, Shi-Min & Wang, Jun & Xu, Ming & Zhang, Dong-Yang & Fu, Yu-Jie & Li, Long & Zhao, Wei-Guo, 2020. "Effect of Pyrola extract on the stability of palm biodiesel upon exposure to copper," Renewable Energy, Elsevier, vol. 149(C), pages 1282-1289.
    17. Shao, Shanshan & Liu, Chengyue & Xiang, Xianliang & Li, Xiaohua & Zhang, Huiyan & Xiao, Rui & Cai, Yixi, 2021. "In situ catalytic fast pyrolysis over CeO2 catalyst: Impact of biomass source, pyrolysis temperature and metal ion," Renewable Energy, Elsevier, vol. 177(C), pages 1372-1381.
    18. Eryilmaz, Tanzer & Yesilyurt, Murat Kadir, 2016. "Influence of blending ratio on the physicochemical properties of safflower oil methyl ester-safflower oil, safflower oil methyl ester-diesel and safflower oil-diesel," Renewable Energy, Elsevier, vol. 95(C), pages 233-247.
    19. Mat Yasin, Mohd Hafizil & Mamat, Rizalman & Najafi, G. & Ali, Obed Majeed & Yusop, Ahmad Fitri & Ali, Mohd Hafiz, 2017. "Potentials of palm oil as new feedstock oil for a global alternative fuel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1034-1049.

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