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Property modification of jatropha oil biodiesel by blending with other biodiesels or adding antioxidants

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  • Chen, Yi-Hung
  • Chen, Jhih-Hong
  • Luo, Yu-Min
  • Shang, Neng-Chou
  • Chang, Cheng-Hsin
  • Chang, Ching-Yuan
  • Chiang, Pen-Chi
  • Shie, Je-Lueng

Abstract

The feasibility of biodiesel production from jatropha (Jatropha curcas) oil was investigated with respect to the biodiesel blending properties and its oxidation stability with antioxidants. The JME (jatropha oil methyl esters) had the cetane number of 54, cold filter plugging point of −2 °C, density of 881 kg/m3 at 15 °C, ester content of 99.4 wt.%, iodine value of 96.55 g I2/100 g, kinematic viscosity of 4.33 mm2/s at 40 °C, and oxidation stability of 3.86 h. Furthermore, the JME was blended with palm oil biodiesel and soybean oil biodiesel at various weight ratios and evaluated for fuel properties as compared to the relevant specifications. In addition, several antioxidants at concentrations between 100 and 1000 ppm were studied for their potential to improve the oxidation stability of the JME. The relationship between the IP (induction period) in the measurement of the oxidation stability associated with the antioxidant consumption in the JME was described by first-order reaction rate kinetics. Moreover, the ln IP (natural logarithm of the IP) at various concentrations of pyrogallol showed a linear relationship with the test temperature. The oxidation stability at ambient temperatures was predicted on the basis of an extrapolation of the temperature-dependent relationship.

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  • Chen, Yi-Hung & Chen, Jhih-Hong & Luo, Yu-Min & Shang, Neng-Chou & Chang, Cheng-Hsin & Chang, Ching-Yuan & Chiang, Pen-Chi & Shie, Je-Lueng, 2011. "Property modification of jatropha oil biodiesel by blending with other biodiesels or adding antioxidants," Energy, Elsevier, vol. 36(7), pages 4415-4421.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:7:p:4415-4421
    DOI: 10.1016/j.energy.2011.04.001
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    7. Aguieiras, Erika C.G. & de Barros, Daniele S.N. & Sousa, Homero & Fernandez-Lafuente, Roberto & Freire, Denise M.G., 2017. "Influence of the raw material on the final properties of biodiesel produced using lipase from Rhizomucor miehei grown on babassu cake as biocatalyst of esterification reactions," Renewable Energy, Elsevier, vol. 113(C), pages 112-118.
    8. Andrade-Tacca, Cesar Augusto & Chang, Chia-Chi & Chen, Yi-Hung & Manh, Do-Van & Chang, Ching-Yuan & Ji, Dar-Ren & Tseng, Jyi-Yeong & Shie, Je-Lueng, 2014. "Esterification of jatropha oil via ultrasonic irradiation with auto-induced temperature-rise effect," Energy, Elsevier, vol. 71(C), pages 346-354.
    9. Ko, Chun-Han & Yeh, Kai-Wun & Wang, Ya-Nang & Wu, Chien-Hou & Chang, Fang-Chih & Cheng, Ming-Hsun & Liou, Chia-Shin, 2012. "Impact of methanol addition strategy on enzymatic transesterification of jatropha oil for biodiesel processing," Energy, Elsevier, vol. 48(1), pages 375-379.
    10. Go, Alchris Woo & Sutanto, Sylviana & Zullaikah, Siti & Ismadji, Suryadi & Ju, Yi-Hsu, 2016. "A new approach in maximizing and direct utilization of whole Jatropha curcas L. kernels in biodiesel production – Technological improvement," Renewable Energy, Elsevier, vol. 85(C), pages 759-765.
    11. Shahabuddin, M. & Kalam, M.A. & Masjuki, H.H. & Bhuiya, M.M.K. & Mofijur, M., 2012. "An experimental investigation into biodiesel stability by means of oxidation and property determination," Energy, Elsevier, vol. 44(1), pages 616-622.
    12. Kalam, M.A. & Ahamed, J.U. & Masjuki, H.H., 2012. "Land availability of Jatropha production in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3999-4007.
    13. Yaakob, Zahira & Narayanan, Binitha N. & Padikkaparambil, Silija & Unni K., Surya & Akbar P., Mohammed, 2014. "A review on the oxidation stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 136-153.
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    15. Farah Halek & Ali Kavousi-Rahim, 2018. "Influence of antioxidant addition on the emissions of a diesel engine by using waste cooking oil biodiesel," Energy & Environment, , vol. 29(5), pages 732-741, August.
    16. Lamba, Bhawna Yadav & Joshi, Girdhar & Tiwari, Avanish K. & Rawat, Devendra Singh & Mallick, Sudesh, 2013. "Effect of antioxidants on physico-chemical properties of EURO-III HSD (high speed diesel) and Jatropha biodiesel blends," Energy, Elsevier, vol. 60(C), pages 222-229.

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