IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v36y2011i1p369-374.html
   My bibliography  Save this article

Storage stability and ageing effect of biodiesel blends treated with different antioxidants

Author

Listed:
  • Karavalakis, Georgios
  • Hilari, Despina
  • Givalou, Lida
  • Karonis, Dimitrios
  • Stournas, Stamos

Abstract

This study investigates the impact of various synthetic phenolic antioxidants on the oxidation stability of biodiesel blends with the employment of the modified Rancimat method. The experimental results revealed that an improvement in oxidation stability could be achieved with all antioxidants tested. Butylated hydroxytoluene (BHT) and butylated hydroxyanisol (BHA) displayed the lowest effectiveness in neat biodiesel, whereas their use in biodiesel blends showed a greater stabilizing potential. Propyl gallate (PG) and pyrogallol (PA) additives showed the strongest effectiveness in both the neat biodiesel and the biodiesel blends. During a naturally ageing process of the biodiesel blends which was conducted for a period of 10 weeks, samples were taken every 2 weeks to measure the oxidation stability, kinematic viscosity and acid value. This process was designed in such manner to simulate the ageing of an automotive biofuel stored in the fuel tank of a vehicle. The results showed a sharp decrease in fuel stability over time. Although limited effects were observed in viscosity, the acid value was significantly increased over time. The addition of antioxidants resulted in some increases in viscosity and acid value of the biodiesel blends.

Suggested Citation

  • Karavalakis, Georgios & Hilari, Despina & Givalou, Lida & Karonis, Dimitrios & Stournas, Stamos, 2011. "Storage stability and ageing effect of biodiesel blends treated with different antioxidants," Energy, Elsevier, vol. 36(1), pages 369-374.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:1:p:369-374
    DOI: 10.1016/j.energy.2010.10.029
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S036054421000592X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2010.10.029?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Sarin, Amit & Arora, Rajneesh & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K. & Sharma, Meeta & Khan, Arif Ali, 2010. "Synergistic effect of metal deactivator and antioxidant on oxidation stability of metal contaminated Jatropha biodiesel," Energy, Elsevier, vol. 35(5), pages 2333-2337.
    2. Chen, Kang-Shin & Lin, Yuan-Chung & Hsieh, Lien-Te & Lin, Long-Full & Wu, Chia-Chieh, 2010. "Saving energy and reducing pollution by use of emulsified palm-biodiesel blends with bio-solution additive," Energy, Elsevier, vol. 35(5), pages 2043-2048.
    3. Jain, Siddharth & Sharma, M.P., 2010. "Stability of biodiesel and its blends: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 667-678, February.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. How, H.G. & Teoh, Y.H. & Masjuki, H.H. & Kalam, M.A., 2012. "Impact of coconut oil blends on particulate-phase PAHs and regulated emissions from a light duty diesel engine," Energy, Elsevier, vol. 48(1), pages 500-509.
    2. Sorate, Kamalesh A. & Bhale, Purnanand V., 2015. "Biodiesel properties and automotive system compatibility issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 777-798.
    3. P Mohamed Shameer & P Mohamed Nishath, 2018. "Investigation and enhancement on fuel stability characteristics of biodiesel dosed with various synthetic antioxidants," Energy & Environment, , vol. 29(7), pages 1189-1207, November.
    4. Fazal, M.A. & Haseeb, A.S.M.A. & Masjuki, H.H., 2011. "Effect of temperature on the corrosion behavior of mild steel upon exposure to palm biodiesel," Energy, Elsevier, vol. 36(5), pages 3328-3334.
    5. How, H.G. & Masjuki, H.H. & Kalam, M.A. & Teoh, Y.H., 2014. "An investigation of the engine performance, emissions and combustion characteristics of coconut biodiesel in a high-pressure common-rail diesel engine," Energy, Elsevier, vol. 69(C), pages 749-759.
    6. Rawat, Devendra S. & Joshi, Girdhar & Lamba, Bhawna Y. & Tiwari, Avanish K. & Kumar, Pankaj, 2015. "The effect of binary antioxidant proportions on antioxidant synergy and oxidation stability of Jatropha and Karanja biodiesels," Energy, Elsevier, vol. 84(C), pages 643-655.
    7. Sundus, F. & Fazal, M.A. & Masjuki, H.H., 2017. "Tribology with biodiesel: A study on enhancing biodiesel stability and its fuel properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 399-412.
    8. Balaji, G. & Cheralathan, M., 2015. "Experimental investigation of antioxidant effect on oxidation stability and emissions in a methyl ester of neem oil fueled DI diesel engine," Renewable Energy, Elsevier, vol. 74(C), pages 910-916.
    9. Shahabuddin, M. & Kalam, M.A. & Masjuki, H.H. & Bhuiya, M.M.K. & Mofijur, M., 2012. "An experimental investigation into biodiesel stability by means of oxidation and property determination," Energy, Elsevier, vol. 44(1), pages 616-622.
    10. Chen, Yi-Hung & Chen, Jhih-Hong & Luo, Yu-Min & Shang, Neng-Chou & Chang, Cheng-Hsin & Chang, Ching-Yuan & Chiang, Pen-Chi & Shie, Je-Lueng, 2011. "Property modification of jatropha oil biodiesel by blending with other biodiesels or adding antioxidants," Energy, Elsevier, vol. 36(7), pages 4415-4421.
    11. Roveda, Ana Carolina & Comin, Marina & Caires, Anderson Rodrigues Lima & Ferreira, Valdir Souza & Trindade, Magno Aparecido Gonçalves, 2016. "Thermal stability enhancement of biodiesel induced by a synergistic effect between conventional antioxidants and an alternative additive," Energy, Elsevier, vol. 109(C), pages 260-265.
    12. Abul K. Hossain, 2020. "Combustion Characteristics of Waste Cooking Oil–Butanol/Diesel/Gasoline Blends for Cleaner Emission," Clean Technol., MDPI, vol. 2(4), pages 1-15, November.
    13. Nesma M. Helal & Hesham F. Alharby & Basmah M. Alharbi & Atif. A. Bamagoos & Ahmed M. Hashim, 2020. "Thymelaea hirsuta and Echinops spinosus : Xerophytic Plants with High Potential for First-Generation Biodiesel Production," Sustainability, MDPI, vol. 12(3), pages 1-16, February.
    14. Yaakob, Zahira & Narayanan, Binitha N. & Padikkaparambil, Silija & Unni K., Surya & Akbar P., Mohammed, 2014. "A review on the oxidation stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 136-153.
    15. Lamba, Bhawna Yadav & Joshi, Girdhar & Tiwari, Avanish K. & Rawat, Devendra Singh & Mallick, Sudesh, 2013. "Effect of antioxidants on physico-chemical properties of EURO-III HSD (high speed diesel) and Jatropha biodiesel blends," Energy, Elsevier, vol. 60(C), pages 222-229.
    16. Muteeb Ul Haq & Ali Turab Jafry & Saad Ahmad & Taqi Ahmad Cheema & Munib Qasim Ansari & Naseem Abbas, 2022. "Recent Advances in Fuel Additives and Their Spray Characteristics for Diesel-Based Blends," Energies, MDPI, vol. 15(19), pages 1-30, October.
    17. Bhawna Yadav Lamba & Wei-Hsin Chen, 2022. "Experimental Investigation of Biodiesel Blends with High-Speed Diesels—A Comprehensive Study," Energies, MDPI, vol. 15(21), pages 1-15, October.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shahabuddin, M. & Kalam, M.A. & Masjuki, H.H. & Bhuiya, M.M.K. & Mofijur, M., 2012. "An experimental investigation into biodiesel stability by means of oxidation and property determination," Energy, Elsevier, vol. 44(1), pages 616-622.
    2. Fernandes, David M. & Squissato, André L. & Lima, Alexandre F. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2019. "Corrosive character of Moringa oleifera Lam biodiesel exposed to carbon steel under simulated storage conditions," Renewable Energy, Elsevier, vol. 139(C), pages 1263-1271.
    3. Rizwanul Fattah, I.M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Masum, B.M. & Imtenan, S. & Ashraful, A.M., 2014. "Effect of antioxidants on oxidation stability of biodiesel derived from vegetable and animal based feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 356-370.
    4. Md Mofijur Rahman & Mohammad Rasul & Nur Md Sayeed Hassan, 2017. "Study on the Tribological Characteristics of Australian Native First Generation and Second Generation Biodiesel Fuel," Energies, MDPI, vol. 10(1), pages 1-16, January.
    5. Sarin, Amit & Singh, N.P. & Sarin, Rakesh & Malhotra, R.K., 2010. "Natural and synthetic antioxidants: Influence on the oxidative stability of biodiesel synthesized from non-edible oil," Energy, Elsevier, vol. 35(12), pages 4645-4648.
    6. Zhang, Wei & Chen, Zhaohui & Shen, Yinggang & Shu, Gequn & Chen, Guisheng & Xu, Biao & Zhao, Wei, 2013. "Influence of water emulsified diesel & oxygen-enriched air on diesel engine NO-smoke emissions and combustion characteristics," Energy, Elsevier, vol. 55(C), pages 369-377.
    7. Haseeb, A.S.M.A. & Jun, T.S. & Fazal, M.A. & Masjuki, H.H., 2011. "Degradation of physical properties of different elastomers upon exposure to palm biodiesel," Energy, Elsevier, vol. 36(3), pages 1814-1819.
    8. Dwivedi, Gaurav & Jain, Siddharth & Sharma, M.P., 2011. "Impact analysis of biodiesel on engine performance—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4633-4641.
    9. Dwivedi, Gaurav & Sharma, M.P., 2014. "Impact of cold flow properties of biodiesel on engine performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 650-656.
    10. Siddharth Jain, 2023. "An Assessment of the Operation and Emission Characteristics of a Diesel Engine Powered by a New Biofuel Prepared Using In Situ Transesterification of a Dry Spirogyra Algae–Jatropha Powder Mixture," Energies, MDPI, vol. 16(3), pages 1-16, February.
    11. Mahmudul, H.M. & Hagos, F.Y. & Mamat, R. & Adam, A. Abdul & Ishak, W.F.W. & Alenezi, R., 2017. "Production, characterization and performance of biodiesel as an alternative fuel in diesel engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 497-509.
    12. Khond, Vivek W. & Kriplani, V.M., 2016. "Effect of nanofluid additives on performances and emissions of emulsified diesel and biodiesel fueled stationary CI engine: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 1338-1348.
    13. Kumar, Himansh & Sarma, A.K. & Kumar, Pramod, 2020. "A comprehensive review on preparation, characterization, and combustion characteristics of microemulsion based hybrid biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 117(C).
    14. Goel, Varun & Kumar, Naresh & Singh, Paramvir, 2018. "Impact of modified parameters on diesel engine characteristics using biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2716-2729.
    15. Jain, Siddharth & Sharma, M.P., 2011. "Thermal stability of biodiesel and its blends: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 438-448, January.
    16. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    17. Meher, L.C. & Churamani, C.P. & Arif, Md. & Ahmed, Z. & Naik, S.N., 2013. "Jatropha curcas as a renewable source for bio-fuels—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 397-407.
    18. Misra, R.D. & Murthy, M.S., 2011. "Blending of additives with biodiesels to improve the cold flow properties, combustion and emission performance in a compression ignition engine--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(5), pages 2413-2422, June.
    19. Govindasamy, Mohan & Ramalingam, Senthil & Dhairiyasamy, Ratchagaraja & Rajendran, Silambarasan, 2022. "Investigation on thermal and storage stability of the Calophyllum inophyllum ester with natural leaf extract as antioxidant additive," Energy, Elsevier, vol. 253(C).
    20. Jakeria, M.R. & Fazal, M.A. & Haseeb, A.S.M.A., 2014. "Influence of different factors on the stability of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 154-163.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:36:y:2011:i:1:p:369-374. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.