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Design and analysis of fuel ethanol production from raw glycerol

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  • Posada, J.A.
  • Cardona, C.A.

Abstract

Three configurations for fuel ethanol production from raw glycerol using Escherichia coli were simulated and economically assessed using Aspen Plus and Aspen Icarus, respectively. These assessments considered raw glycerol (60 wt%) purification to both crude glycerol (88 wt%) and pure glycerol (98 wt%). The highest purification cost (PC) was obtained using pure glycerol due to its higher energy consumption in the distillation stage. In addition, the remaining methanol in the raw glycerol stream was recovered and recycled, decreasing the purification costs. The E. coli strain is able to convert crude glycerol (at 10 g/L or 20 g/L), or pure glycerol (at 10 g/L) to ethanol. Among these three glycerol concentrations, the lowest bioconversion cost was obtained when crude glycerol was diluted at 20 g/L. Purification and global production costs were compared with the commercial prices of glycerol and fuel ethanol from corn and sugarcane. Purification costs of raw glycerol were lower than previously reported values due to the methanol recovery. Global production costs for fuel ethanol from glycerol were lower than the reported values for corn-based production and higher than those for cane-based production.

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  • Posada, J.A. & Cardona, C.A., 2010. "Design and analysis of fuel ethanol production from raw glycerol," Energy, Elsevier, vol. 35(12), pages 5286-5293.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:12:p:5286-5293
    DOI: 10.1016/j.energy.2010.07.036
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    References listed on IDEAS

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    1. Quintero, J.A. & Montoya, M.I. & Sánchez, O.J. & Giraldo, O.H. & Cardona, C.A., 2008. "Fuel ethanol production from sugarcane and corn: Comparative analysis for a Colombian case," Energy, Elsevier, vol. 33(3), pages 385-399.
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    1. Setyawan, Hendrix Y. & Zhu, Mingming & Zhang, Zhezi & Zhang, Dongke, 2016. "Ignition and combustion characteristics of single droplets of a crude glycerol in comparison with pure glycerol, petroleum diesel, biodiesel and ethanol," Energy, Elsevier, vol. 113(C), pages 153-159.
    2. Chatzifragkou, Afroditi & Makri, Anna & Belka, Aikaterini & Bellou, Stamatina & Mavrou, Marilena & Mastoridou, Maria & Mystrioti, Paraskevi & Onjaro, Grace & Aggelis, George & Papanikolaou, Seraphim, 2011. "Biotechnological conversions of biodiesel derived waste glycerol by yeast and fungal species," Energy, Elsevier, vol. 36(2), pages 1097-1108.
    3. Quispe, César A.G. & Coronado, Christian J.R. & Carvalho Jr., João A., 2013. "Glycerol: Production, consumption, prices, characterization and new trends in combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 475-493.
    4. Chen, Yi-Hung & Chen, Jhih-Hong & Luo, Yu-Min & Shang, Neng-Chou & Chang, Cheng-Hsin & Chang, Ching-Yuan & Chiang, Pen-Chi & Shie, Je-Lueng, 2011. "Property modification of jatropha oil biodiesel by blending with other biodiesels or adding antioxidants," Energy, Elsevier, vol. 36(7), pages 4415-4421.
    5. Oliveira, V.B. & Simões, M. & Melo, L.F. & Pinto, A.M.F.R., 2013. "A 1D mathematical model for a microbial fuel cell," Energy, Elsevier, vol. 61(C), pages 463-471.

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