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Composite sorbent of methanol “LiCl in mesoporous silica gel” for adsorption cooling: Dynamic optimization

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  • Gordeeva, Larisa G.
  • Aristov, Yuriy I.

Abstract

A novel composite sorbent of methanol “LiCl in mesoporous silica gel” has recently been proposed for AC (adsorption cooling). Its testing in a lab-scale adsorption chiller resulted in the specific cooling power of 210–290 W/kg and the cooling COP of 0.32–0.4. Although these values are rather encouraging, a room for their enhancement still exists. The aim of this paper was a dynamic optimization of the composite performance in AC cycles. Dynamics of methanol sorption on loose grains of the LiCl/silica composites was studied by a Large Temperature Jump method under typical conditions of AC cycle. Effects of number of the sorbent layers, salt content, grain size and cycle boundary temperatures were studied. Physico-chemical processes in the three-phase system (salt, solution, vapor) were shown to be quite complex and can strongly affect the dynamics of methanol ad-/desorption. Several obstacles which can retard the sorption were analyzed. Appropriate recommendations on improving the cycle dynamics, which concern optimal conversion degree, salt content and relative durations of ad- and desorption phases, were made.

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  • Gordeeva, Larisa G. & Aristov, Yuriy I., 2011. "Composite sorbent of methanol “LiCl in mesoporous silica gel” for adsorption cooling: Dynamic optimization," Energy, Elsevier, vol. 36(2), pages 1273-1279.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:2:p:1273-1279
    DOI: 10.1016/j.energy.2010.11.016
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    4. Sapienza, Alessio & Santamaria, Salvatore & Frazzica, Andrea & Freni, Angelo, 2011. "Influence of the management strategy and operating conditions on the performance of an adsorption chiller," Energy, Elsevier, vol. 36(9), pages 5532-5538.
    5. Yannan Zhang & Ruzhu Wang & Tingxian Li & Yanjie Zhao, 2016. "Thermochemical Characterizations of Novel Vermiculite-LiCl Composite Sorbents for Low-Temperature Heat Storage," Energies, MDPI, vol. 9(10), pages 1-15, October.
    6. Zhang, Y.N. & Wang, R.Z. & Zhao, Y.J. & Li, T.X. & Riffat, S.B. & Wajid, N.M., 2016. "Development and thermochemical characterizations of vermiculite/SrBr2 composite sorbents for low-temperature heat storage," Energy, Elsevier, vol. 115(P1), pages 120-128.
    7. El Fadar, Abdellah, 2015. "Thermal behavior and performance assessment of a solar adsorption cooling system with finned adsorber," Energy, Elsevier, vol. 83(C), pages 674-684.
    8. Frazzica, A. & Brancato, V. & Caprì, A. & Cannilla, C. & Gordeeva, L.G. & Aristov, Y.I., 2020. "Development of “salt in porous matrix” composites based on LiCl for sorption thermal energy storage," Energy, Elsevier, vol. 208(C).
    9. Saha, Bidyut Baran & El-Sharkawy, Ibrahim I. & Miyazaki, Takahiko & Koyama, Shigeru & Henninger, Stefan K. & Herbst, Annika & Janiak, Christoph, 2015. "Ethanol adsorption onto metal organic framework: Theory and experiments," Energy, Elsevier, vol. 79(C), pages 363-370.
    10. Ilya Girnik & Yuri Aristov, 2020. "An Aqueous CaCl 2 Solution in the Condenser/Evaporator Instead of Pure Water: Application for the New Adsorptive Cycle “Heat from Cold”," Energies, MDPI, vol. 13(11), pages 1-11, June.
    11. Hassan, H.Z. & Mohamad, A.A. & Al-Ansary, H.A. & Alyousef, Y.M., 2014. "Dynamic analysis of the CTAR (constant temperature adsorption refrigeration) cycle," Energy, Elsevier, vol. 77(C), pages 852-858.
    12. Girnik, Ilya S. & Aristov, Yuri I., 2016. "Dynamics of water vapour adsorption by a monolayer of loose AQSOA™-FAM-Z02 grains: Indication of inseparably coupled heat and mass transfer," Energy, Elsevier, vol. 114(C), pages 767-773.
    13. Zhang, Y.N. & Wang, R.Z. & Li, T.X., 2017. "Experimental investigation on an open sorption thermal storage system for space heating," Energy, Elsevier, vol. 141(C), pages 2421-2433.
    14. Girnik, I.S. & Aristov, Yu.I., 2020. "Water as an adsorptive for adsorption cycles operating at a temperature below 0 °C," Energy, Elsevier, vol. 211(C).
    15. Choudhury, Biplab & Saha, Bidyut Baran & Chatterjee, Pradip K. & Sarkar, Jyoti Prakas, 2013. "An overview of developments in adsorption refrigeration systems towards a sustainable way of cooling," Applied Energy, Elsevier, vol. 104(C), pages 554-567.
    16. Grekova, A.D. & Girnik, I.S. & Nikulin, V.V. & Tokarev, M.M. & Gordeeva, L.G. & Aristov, Yu.I., 2016. "New composite sorbents of water and methanol “salt in anodic alumina”: Evaluation for adsorption heat transformation," Energy, Elsevier, vol. 106(C), pages 231-239.
    17. Aristov, Yuriy I. & Glaznev, Ivan S. & Girnik, Ilya S., 2012. "Optimization of adsorption dynamics in adsorptive chillers: Loose grains configuration," Energy, Elsevier, vol. 46(1), pages 484-492.

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