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Novel sorbents of ethanol “salt confined to porous matrix” for adsorptive cooling

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  • Gordeeva, Larisa
  • Aristov, Yuriy

Abstract

In this paper a new family of sorbents, specifically designed for ethanol sorption, is presented. The composites were synthesized by a dry impregnation of matrices with an aqueous solution of various salts. The ethanol sorption capacity of the composites, under conditions typical for adsorptive air conditioning cycle, has been measured by using an express method based on the Polanyi principle of temperature invariance. Results obtained show that the best novel composites have the ethanol sorption ability which is higher than that of known ethanol sorbents. The composite LiBr(30 wt.%)/SiO2 appears to show the highest sorption capacity and an uptake variation Δw=0.56 and 0.40g/g for air conditioning and ice making cycles, respectively. They are much larger than those obtained for conventional adsorbents. The correspondent cooling coefficient of performance (COP) was estimated to be 0.66 and 0.61, which is comparable with the COP of the best water sorbents.

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  • Gordeeva, Larisa & Aristov, Yuriy, 2010. "Novel sorbents of ethanol “salt confined to porous matrix” for adsorptive cooling," Energy, Elsevier, vol. 35(6), pages 2703-2708.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:6:p:2703-2708
    DOI: 10.1016/j.energy.2009.04.001
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    1. Frazzica, A. & Palomba, V. & Dawoud, B. & Gullì, G. & Brancato, V. & Sapienza, A. & Vasta, S. & Freni, A. & Costa, F. & Restuccia, G., 2016. "Design, realization and testing of an adsorption refrigerator based on activated carbon/ethanol working pair," Applied Energy, Elsevier, vol. 174(C), pages 15-24.
    2. Zheng, X. & Wang, R.Z. & Ge, T.S. & Hu, L.M., 2015. "Performance study of SAPO-34 and FAPO-34 desiccants for desiccant coated heat exchanger systems," Energy, Elsevier, vol. 93(P1), pages 88-94.
    3. Sapienza, Alessio & Santamaria, Salvatore & Frazzica, Andrea & Freni, Angelo, 2011. "Influence of the management strategy and operating conditions on the performance of an adsorption chiller," Energy, Elsevier, vol. 36(9), pages 5532-5538.
    4. Gordeeva, Larisa & Frazzica, Andrea & Sapienza, Alessio & Aristov, Yuri & Freni, Angelo, 2014. "Adsorption cooling utilizing the “LiBr/silica – ethanol” working pair: Dynamic optimization of the adsorber/heat exchanger unit," Energy, Elsevier, vol. 75(C), pages 390-399.
    5. Frazzica, A. & Brancato, V. & Caprì, A. & Cannilla, C. & Gordeeva, L.G. & Aristov, Y.I., 2020. "Development of “salt in porous matrix” composites based on LiCl for sorption thermal energy storage," Energy, Elsevier, vol. 208(C).
    6. Saha, Bidyut Baran & El-Sharkawy, Ibrahim I. & Miyazaki, Takahiko & Koyama, Shigeru & Henninger, Stefan K. & Herbst, Annika & Janiak, Christoph, 2015. "Ethanol adsorption onto metal organic framework: Theory and experiments," Energy, Elsevier, vol. 79(C), pages 363-370.
    7. Brancato, V. & Frazzica, A. & Sapienza, A. & Gordeeva, L. & Freni, A., 2015. "Ethanol adsorption onto carbonaceous and composite adsorbents for adsorptive cooling system," Energy, Elsevier, vol. 84(C), pages 177-185.
    8. Dias, João M.S. & Costa, Vítor A.F., 2018. "Adsorption heat pumps for heating applications: A review of current state, literature gaps and development challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 317-327.
    9. Gordeeva, Larisa G. & Aristov, Yuriy I., 2011. "Composite sorbent of methanol “LiCl in mesoporous silica gel” for adsorption cooling: Dynamic optimization," Energy, Elsevier, vol. 36(2), pages 1273-1279.
    10. Choudhury, Biplab & Saha, Bidyut Baran & Chatterjee, Pradip K. & Sarkar, Jyoti Prakas, 2013. "An overview of developments in adsorption refrigeration systems towards a sustainable way of cooling," Applied Energy, Elsevier, vol. 104(C), pages 554-567.

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