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Environmentally benign working pairs for adsorption refrigeration

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  • Cui, Qun
  • Tao, Gang
  • Chen, Haijun
  • Guo, Xinyue
  • Yao, Huqing

Abstract

This paper begins from adsorption working pairs: water and ethanol were selected as refrigerants; 13x molecular sieve, silica gel, activated carbon, adsorbent NA and NB, proposed by authors, were selected as adsorbents, and the performance of adsorption working pairs in adsorption refrigeration cycle was studied. The adsorption isotherms of adsorbents (NA and NB) were obtained by high-vacuum gravimetric method. Desorption properties of adsorbents were analyzed and compared by thermal analysis method. The performance of adsorption refrigeration was studied on simulation device of adsorption refrigeration cycle. After presentation of adsorption isotherms, the thermodynamic performance for their use in adsorption refrigeration system was calculated. The results show: (1) the maximum adsorption capacity of water on adsorbent NA reaches 0.7 kg/kg, and the maximum adsorption capacity of ethanol on adsorbent NB is 0.68 kg/kg, which is three times that of ethanol on activated carbon, (2) the refrigeration capacity of NA–water working pair is 922 kJ/kg, the refrigeration capacity of NB–ethanol is 2.4 times that of activated carbon–methanol, (3) as environmental friendly and no public hazard adsorption working pair, NA–H2O and NB–ethanol can substitute activated carbon–methanol in adsorption refrigeration system using low-grade heat source.

Suggested Citation

  • Cui, Qun & Tao, Gang & Chen, Haijun & Guo, Xinyue & Yao, Huqing, 2005. "Environmentally benign working pairs for adsorption refrigeration," Energy, Elsevier, vol. 30(2), pages 261-271.
    • Handle: RePEc:eee:energy:v:30:y:2005:i:2:p:261-271
    DOI: 10.1016/j.energy.2004.05.005
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    1. Ozsezen, Ahmet Necati & Canakci, Mustafa, 2011. "Performance and combustion characteristics of alcohol–gasoline blends at wide-open throttle," Energy, Elsevier, vol. 36(5), pages 2747-2752.
    2. Shmroukh, Ahmed N. & Ali, Ahmed Hamza H. & Ookawara, Shinichi, 2015. "Adsorption working pairs for adsorption cooling chillers: A review based on adsorption capacity and environmental impact," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 445-456.
    3. Solmus, Ismail & YamalI, Cemil & Kaftanoglu, Bilgin & Baker, Derek & Çaglar, Ahmet, 2010. "Adsorption properties of a natural zeolite-water pair for use in adsorption cooling cycles," Applied Energy, Elsevier, vol. 87(6), pages 2062-2067, June.
    4. Wu, J.Y. & Li, S., 2009. "Study on cyclic characteristics of silica gel–water adsorption cooling system driven by variable heat source," Energy, Elsevier, vol. 34(11), pages 1955-1962.
    5. Alves, Luís & Pereira, Vítor & Lagarteira, Tiago & Mendes, Adélio, 2021. "Catalytic methane decomposition to boost the energy transition: Scientific and technological advancements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    6. Elsayed, Ahmed M. & Askalany, Ahmed A. & Shea, Andrew D. & Dakkama, Hassan J. & Mahmoud, Saad & Al-Dadah, Raya & Kaialy, Waseem, 2017. "A state of the art of required techniques for employing activated carbon in renewable energy powered adsorption applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 503-519.
    7. Sapienza, Alessio & Santamaria, Salvatore & Frazzica, Andrea & Freni, Angelo, 2011. "Influence of the management strategy and operating conditions on the performance of an adsorption chiller," Energy, Elsevier, vol. 36(9), pages 5532-5538.
    8. Yu Yin & Junpeng Shao & Lin Zhang & Qun Cui & Haiyan Wang, 2021. "Experimental Study on Heat Transfer and Adsorption Cooling Performance of MIL-101/Few Layer Graphene Composite," Energies, MDPI, vol. 14(16), pages 1-19, August.
    9. Korhammer, Kathrin & Neumann, Karsten & Opel, Oliver & Ruck, Wolfgang K.L., 2018. "Thermodynamic and kinetic study of CaCl2-CH3OH adducts for solid sorption refrigeration by TGA/DSC," Applied Energy, Elsevier, vol. 230(C), pages 1255-1278.
    10. Wang, L. & Chen, L. & Wang, H.L. & Liao, D.L., 2009. "The adsorption refrigeration characteristics of alkaline-earth metal chlorides and its composite adsorbents," Renewable Energy, Elsevier, vol. 34(4), pages 1016-1023.
    11. Saha, Bidyut Baran & El-Sharkawy, Ibrahim I. & Miyazaki, Takahiko & Koyama, Shigeru & Henninger, Stefan K. & Herbst, Annika & Janiak, Christoph, 2015. "Ethanol adsorption onto metal organic framework: Theory and experiments," Energy, Elsevier, vol. 79(C), pages 363-370.
    12. Habib, Khairul & Choudhury, Biplab & Chatterjee, Pradip Kumar & Saha, Bidyut Baran, 2013. "Study on a solar heat driven dual-mode adsorption chiller," Energy, Elsevier, vol. 63(C), pages 133-141.
    13. Bouzid, Mohamed & Sellaoui, Lotfi & Khalfaoui, Mohamed & Belmabrouk, Hafedh & Lamine, Abdelmottaleb Ben, 2016. "Adsorption of ethanol onto activated carbon: Modeling and consequent interpretations based on statistical physics treatment," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 444(C), pages 853-869.
    14. Allouhi, A. & Kousksou, T. & Jamil, A. & El Rhafiki, T. & Mourad, Y. & Zeraouli, Y., 2015. "Optimal working pairs for solar adsorption cooling applications," Energy, Elsevier, vol. 79(C), pages 235-247.
    15. Gordeeva, Larisa & Aristov, Yuriy, 2010. "Novel sorbents of ethanol “salt confined to porous matrix” for adsorptive cooling," Energy, Elsevier, vol. 35(6), pages 2703-2708.
    16. Gordeeva, Larisa G. & Aristov, Yuriy I., 2011. "Composite sorbent of methanol “LiCl in mesoporous silica gel” for adsorption cooling: Dynamic optimization," Energy, Elsevier, vol. 36(2), pages 1273-1279.

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