IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v79y2015icp363-370.html
   My bibliography  Save this article

Ethanol adsorption onto metal organic framework: Theory and experiments

Author

Listed:
  • Saha, Bidyut Baran
  • El-Sharkawy, Ibrahim I.
  • Miyazaki, Takahiko
  • Koyama, Shigeru
  • Henninger, Stefan K.
  • Herbst, Annika
  • Janiak, Christoph

Abstract

This paper presents experimental and theoretical investigations of adsorption characteristics of ethanol onto metal organic framework namely MIL-101Cr. Adsorption isotherms and kinetics of the studied pair have been measured gravimetrically using a magnetic suspension adsorption measurement unit and volumetrically employing a Quantachrome Autosorb iQ MP machine. The present experiments have been conducted within relative pressures between 0.1 and 0.9 and adsorption temperatures ranging from 30 to 70 °C, which are suitable for adsorption cooling applications. Adsorption isotherm data exhibit that 1 kg of MIL-101Cr can adsorb as high as 1.1 kg of ethanol at adsorption temperature of 30 °C, and the Tóth equation has been used to fit the experimentally measured data. As of the experimentally measured adsorption uptake rate data, the Fickian diffusion model is found to be suitable. These data are essential for designing a new generation of adsorption chiller.

Suggested Citation

  • Saha, Bidyut Baran & El-Sharkawy, Ibrahim I. & Miyazaki, Takahiko & Koyama, Shigeru & Henninger, Stefan K. & Herbst, Annika & Janiak, Christoph, 2015. "Ethanol adsorption onto metal organic framework: Theory and experiments," Energy, Elsevier, vol. 79(C), pages 363-370.
    • Handle: RePEc:eee:energy:v:79:y:2015:i:c:p:363-370
    DOI: 10.1016/j.energy.2014.11.022
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214012778
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.11.022?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Gordeeva, Larisa G. & Aristov, Yuriy I., 2011. "Composite sorbent of methanol “LiCl in mesoporous silica gel” for adsorption cooling: Dynamic optimization," Energy, Elsevier, vol. 36(2), pages 1273-1279.
    2. Rezk, Ahmed & AL-Dadah, Raya & Mahmoud, Saad & Elsayed, Ahmed, 2013. "Investigation of Ethanol/metal organic frameworks for low temperature adsorption cooling applications," Applied Energy, Elsevier, vol. 112(C), pages 1025-1031.
    3. Henninger, S.K. & Munz, G. & Ratzsch, K.-F. & Schossig, P., 2011. "Cycle stability of sorption materials and composites for the use in heat pumps and cooling machines," Renewable Energy, Elsevier, vol. 36(11), pages 3043-3049.
    4. Cui, Qun & Tao, Gang & Chen, Haijun & Guo, Xinyue & Yao, Huqing, 2005. "Environmentally benign working pairs for adsorption refrigeration," Energy, Elsevier, vol. 30(2), pages 261-271.
    5. Gordeeva, Larisa & Aristov, Yuriy, 2010. "Novel sorbents of ethanol “salt confined to porous matrix” for adsorptive cooling," Energy, Elsevier, vol. 35(6), pages 2703-2708.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Askalany, Ahmed A. & Ernst, Sebastian-Johannes & Hügenell, Philipp P.C. & Bart, Hans-Jörg & Henninger, Stefan K. & Alsaman, Ahmed S., 2017. "High potential of employing bentonite in adsorption cooling systems driven by low grade heat source temperatures," Energy, Elsevier, vol. 141(C), pages 782-791.
    2. Xu, Zhou & Yin, Yu & Shao, Junpeng & Liu, Yerong & Zhang, Lin & Cui, Qun & Wang, Haiyan, 2020. "Study on heat transfer and cooling performance of copper foams cured MIL-101 adsorption unit tube," Energy, Elsevier, vol. 191(C).
    3. Gordeeva, Larisa G. & Solovyeva, Marina V. & Aristov, Yuri I., 2016. "NH2-MIL-125 as a promising material for adsorptive heat transformation and storage," Energy, Elsevier, vol. 100(C), pages 18-24.
    4. Frazzica, A. & Palomba, V. & Dawoud, B. & Gullì, G. & Brancato, V. & Sapienza, A. & Vasta, S. & Freni, A. & Costa, F. & Restuccia, G., 2016. "Design, realization and testing of an adsorption refrigerator based on activated carbon/ethanol working pair," Applied Energy, Elsevier, vol. 174(C), pages 15-24.
    5. Singh, Vinod Kumar & Kumar, E. Anil & Saha, Bidyut Baran, 2018. "Adsorption isotherms, kinetics and thermodynamic simulation of CO2-CSAC pair for cooling application," Energy, Elsevier, vol. 160(C), pages 1158-1173.
    6. Mikhaeil, Makram & Gaderer, Matthias & Dawoud, Belal, 2020. "On the development of an innovative adsorber plate heat exchanger for adsorption heat transformation processes; an experimental and numerical study," Energy, Elsevier, vol. 207(C).
    7. Korhammer, Kathrin & Neumann, Karsten & Opel, Oliver & Ruck, Wolfgang K.L., 2018. "Thermodynamic and kinetic study of CaCl2-CH3OH adducts for solid sorption refrigeration by TGA/DSC," Applied Energy, Elsevier, vol. 230(C), pages 1255-1278.
    8. Brancato, V. & Frazzica, A. & Sapienza, A. & Gordeeva, L. & Freni, A., 2015. "Ethanol adsorption onto carbonaceous and composite adsorbents for adsorptive cooling system," Energy, Elsevier, vol. 84(C), pages 177-185.
    9. Henninger, Stefan K. & Ernst, Sebastian-Johannes & Gordeeva, Larisa & Bendix, Phillip & Fröhlich, Dominik & Grekova, Alexandra D. & Bonaccorsi, Lucio & Aristov, Yuri & Jaenchen, Jochen, 2017. "New materials for adsorption heat transformation and storage," Renewable Energy, Elsevier, vol. 110(C), pages 59-68.
    10. Shabir, Faizan & Sultan, Muhammad & Miyazaki, Takahiko & Saha, Bidyut B. & Askalany, Ahmed & Ali, Imran & Zhou, Yuguang & Ahmad, Riaz & Shamshiri, Redmond R., 2020. "Recent updates on the adsorption capacities of adsorbent-adsorbate pairs for heat transformation applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    11. Mohammed, Ramy H. & Rezk, Ahmed & Askalany, Ahmed & Ali, Ehab S. & Zohir, A.E. & Sultan, Muhammad & Ghazy, Mohamed & Abdelkareem, Mohammad Ali & Olabi, A.G., 2021. "Metal-organic frameworks in cooling and water desalination: Synthesis and application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    12. Marcin Sowa & Karol Sztekler & Agata Mlonka-Mędrala & Łukasz Mika, 2023. "An Overview of Developments In Silica Gel Matrix Composite Sorbents for Adsorption Chillers with Desalination Function," Energies, MDPI, vol. 16(15), pages 1-34, August.
    13. Ma, Liejun & Yang, Huan & Wu, Qi & Yin, Yu & Liu, Zongjian & Cui, Qun & Wang, Haiyan, 2015. "Study on adsorption refrigeration performance of MIL-101-isobutane working pair," Energy, Elsevier, vol. 93(P1), pages 786-794.
    14. Gado, Mohamed G. & Ookawara, Shinichi & Nada, Sameh & El-Sharkawy, Ibrahim I., 2021. "Hybrid sorption-vapor compression cooling systems: A comprehensive overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    15. Gordeeva, L.G. & Aristov, Yu.I., 2019. "Adsorptive heat storage and amplification: New cycles and adsorbents," Energy, Elsevier, vol. 167(C), pages 440-453.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sapienza, Alessio & Santamaria, Salvatore & Frazzica, Andrea & Freni, Angelo, 2011. "Influence of the management strategy and operating conditions on the performance of an adsorption chiller," Energy, Elsevier, vol. 36(9), pages 5532-5538.
    2. Frazzica, A. & Palomba, V. & Dawoud, B. & Gullì, G. & Brancato, V. & Sapienza, A. & Vasta, S. & Freni, A. & Costa, F. & Restuccia, G., 2016. "Design, realization and testing of an adsorption refrigerator based on activated carbon/ethanol working pair," Applied Energy, Elsevier, vol. 174(C), pages 15-24.
    3. Brancato, V. & Frazzica, A. & Sapienza, A. & Gordeeva, L. & Freni, A., 2015. "Ethanol adsorption onto carbonaceous and composite adsorbents for adsorptive cooling system," Energy, Elsevier, vol. 84(C), pages 177-185.
    4. Choudhury, Biplab & Saha, Bidyut Baran & Chatterjee, Pradip K. & Sarkar, Jyoti Prakas, 2013. "An overview of developments in adsorption refrigeration systems towards a sustainable way of cooling," Applied Energy, Elsevier, vol. 104(C), pages 554-567.
    5. Korhammer, Kathrin & Neumann, Karsten & Opel, Oliver & Ruck, Wolfgang K.L., 2018. "Thermodynamic and kinetic study of CaCl2-CH3OH adducts for solid sorption refrigeration by TGA/DSC," Applied Energy, Elsevier, vol. 230(C), pages 1255-1278.
    6. Gordeeva, Larisa G. & Aristov, Yuriy I., 2011. "Composite sorbent of methanol “LiCl in mesoporous silica gel” for adsorption cooling: Dynamic optimization," Energy, Elsevier, vol. 36(2), pages 1273-1279.
    7. Frazzica, A. & Brancato, V. & Caprì, A. & Cannilla, C. & Gordeeva, L.G. & Aristov, Y.I., 2020. "Development of “salt in porous matrix” composites based on LiCl for sorption thermal energy storage," Energy, Elsevier, vol. 208(C).
    8. Askalany, Ahmed A. & Ernst, Sebastian-Johannes & Hügenell, Philipp P.C. & Bart, Hans-Jörg & Henninger, Stefan K. & Alsaman, Ahmed S., 2017. "High potential of employing bentonite in adsorption cooling systems driven by low grade heat source temperatures," Energy, Elsevier, vol. 141(C), pages 782-791.
    9. Jung-Gil Lee & Kyung Jin Bae & Oh Kyung Kwon, 2020. "Performance Investigation of a Two-Bed Type Adsorption Chiller with Various Adsorbents," Energies, MDPI, vol. 13(10), pages 1-16, May.
    10. Xu, Zhou & Yin, Yu & Shao, Junpeng & Liu, Yerong & Zhang, Lin & Cui, Qun & Wang, Haiyan, 2020. "Study on heat transfer and cooling performance of copper foams cured MIL-101 adsorption unit tube," Energy, Elsevier, vol. 191(C).
    11. Ozsezen, Ahmet Necati & Canakci, Mustafa, 2011. "Performance and combustion characteristics of alcohol–gasoline blends at wide-open throttle," Energy, Elsevier, vol. 36(5), pages 2747-2752.
    12. Alves, Luís & Pereira, Vítor & Lagarteira, Tiago & Mendes, Adélio, 2021. "Catalytic methane decomposition to boost the energy transition: Scientific and technological advancements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    13. Hassan, H.Z. & Mohamad, A.A. & Alyousef, Y. & Al-Ansary, H.A., 2015. "A review on the equations of state for the working pairs used in adsorption cooling systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 600-609.
    14. Long, Rui & Zhao, Yanan & Li, Mingliang & Pan, Yao & Liu, Zhichun & Liu, Wei, 2021. "Evaluations of adsorbents and salt-methanol solutions for low-grade heat driven osmotic heat engines," Energy, Elsevier, vol. 229(C).
    15. Zhang, Y.N. & Wang, R.Z. & Li, T.X., 2017. "Experimental investigation on an open sorption thermal storage system for space heating," Energy, Elsevier, vol. 141(C), pages 2421-2433.
    16. Shmroukh, Ahmed N. & Ali, Ahmed Hamza H. & Ookawara, Shinichi, 2015. "Adsorption working pairs for adsorption cooling chillers: A review based on adsorption capacity and environmental impact," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 445-456.
    17. Andreas Velte & Jörg Weise & Eric Laurenz & Joachim Baumeister & Gerrit Füldner, 2021. "Zeolite NaY-Copper Composites Produced by Sintering Processes for Adsorption Heat Transformation—Technology, Structure and Performance," Energies, MDPI, vol. 14(7), pages 1-24, April.
    18. Solmus, Ismail & YamalI, Cemil & Kaftanoglu, Bilgin & Baker, Derek & Çaglar, Ahmet, 2010. "Adsorption properties of a natural zeolite-water pair for use in adsorption cooling cycles," Applied Energy, Elsevier, vol. 87(6), pages 2062-2067, June.
    19. Girnik, I.S. & Grekova, A.D. & Li, T.X. & Wang, R.Z. & Dutta, P. & Srinivasa Murthy, S. & Aristov, Yu.I., 2020. "Composite “LiCl/MWCNT/PVA” for adsorption thermal battery: Dynamics of methanol sorption," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    20. Ilya Girnik & Yuri Aristov, 2020. "An Aqueous CaCl 2 Solution in the Condenser/Evaporator Instead of Pure Water: Application for the New Adsorptive Cycle “Heat from Cold”," Energies, MDPI, vol. 13(11), pages 1-11, June.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:79:y:2015:i:c:p:363-370. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.