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Adsorption of ethanol onto activated carbon: Modeling and consequent interpretations based on statistical physics treatment

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  • Bouzid, Mohamed
  • Sellaoui, Lotfi
  • Khalfaoui, Mohamed
  • Belmabrouk, Hafedh
  • Lamine, Abdelmottaleb Ben

Abstract

In this work, we studied the adsorption of ethanol on three types of activated carbon, namely parent Maxsorb III and two chemically modified activated carbons (H2–Maxsorb III and KOH–H2–Maxsorb III). This investigation has been conducted on the basis of the grand canonical formalism in statistical physics and on simplified assumptions. This led to three parameter equations describing the adsorption of ethanol onto the three types of activated carbon. There was a good correlation between experimental data and results obtained by the new proposed equation. The parameters characterizing the adsorption isotherm were the number of adsorbed molecules (s) per site n, the density of the receptor sites per unit mass of the adsorbent Nm, and the energetic parameter p1/2.

Suggested Citation

  • Bouzid, Mohamed & Sellaoui, Lotfi & Khalfaoui, Mohamed & Belmabrouk, Hafedh & Lamine, Abdelmottaleb Ben, 2016. "Adsorption of ethanol onto activated carbon: Modeling and consequent interpretations based on statistical physics treatment," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 444(C), pages 853-869.
    • Handle: RePEc:eee:phsmap:v:444:y:2016:i:c:p:853-869
    DOI: 10.1016/j.physa.2015.09.097
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    1. Wang, L.W. & Wang, R.Z. & Oliveira, R.G., 2009. "A review on adsorption working pairs for refrigeration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(3), pages 518-534, April.
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    3. Knani, S. & Aouaini, F. & Bahloul, N. & Khalfaoui, M. & Hachicha, M.A. & Ben Lamine, A. & Kechaou, N., 2014. "Modeling of adsorption isotherms of water vapor on Tunisian olive leaves using statistical mechanical formulation," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 400(C), pages 57-70.
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    1. Shabir, Faizan & Sultan, Muhammad & Miyazaki, Takahiko & Saha, Bidyut B. & Askalany, Ahmed & Ali, Imran & Zhou, Yuguang & Ahmad, Riaz & Shamshiri, Redmond R., 2020. "Recent updates on the adsorption capacities of adsorbent-adsorbate pairs for heat transformation applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).

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