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New composite sorbents of water and methanol “salt in anodic alumina”: Evaluation for adsorption heat transformation

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  • Grekova, A.D.
  • Girnik, I.S.
  • Nikulin, V.V.
  • Tokarev, M.M.
  • Gordeeva, L.G.
  • Aristov, Yu.I.

Abstract

Development of new adsorbents of water and methanol specialised for AHT (adsorption heat transformation) can essentially advance this emerging low-carbon technology. This paper addresses the synthesis of novel composite sorbents based on an AA (anodic alumina) layer impregnated with hygroscopic salts, and the study of their ability to sorb water and methanol vapours. This work consists of the three parts: (1) synthesis and comparison of AA/Al sandwiches obtained with various electrolytes (sulphuric, oxalic, and phosphoric acids); (2) preparation of salt/AA composites (salt = CaCl2 and LiCl) and study of their sorption equilibrium and dynamics with water and methanol vapours; and (3) evaluation of the new sorbents feasibility for AHT applications. The results obtained show that a) the new AA-based composites could be interesting for making compact AHT units with short working cycles, and b) still more R&D are necessary for further progress towards practical implementation of the new sorbents.

Suggested Citation

  • Grekova, A.D. & Girnik, I.S. & Nikulin, V.V. & Tokarev, M.M. & Gordeeva, L.G. & Aristov, Yu.I., 2016. "New composite sorbents of water and methanol “salt in anodic alumina”: Evaluation for adsorption heat transformation," Energy, Elsevier, vol. 106(C), pages 231-239.
    • Handle: RePEc:eee:energy:v:106:y:2016:i:c:p:231-239
    DOI: 10.1016/j.energy.2016.03.050
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    Cited by:

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    2. Korhammer, Kathrin & Neumann, Karsten & Opel, Oliver & Ruck, Wolfgang K.L., 2018. "Thermodynamic and kinetic study of CaCl2-CH3OH adducts for solid sorption refrigeration by TGA/DSC," Applied Energy, Elsevier, vol. 230(C), pages 1255-1278.
    3. Manca Ocvirk & Alenka Ristić & Nataša Zabukovec Logar, 2021. "Synthesis of Mesoporous γ-Alumina Support for Water Composite Sorbents for Low Temperature Sorption Heat Storage," Energies, MDPI, vol. 14(22), pages 1-15, November.
    4. Henninger, Stefan K. & Ernst, Sebastian-Johannes & Gordeeva, Larisa & Bendix, Phillip & Fröhlich, Dominik & Grekova, Alexandra D. & Bonaccorsi, Lucio & Aristov, Yuri & Jaenchen, Jochen, 2017. "New materials for adsorption heat transformation and storage," Renewable Energy, Elsevier, vol. 110(C), pages 59-68.
    5. Piotr Boruta & Tomasz Bujok & Łukasz Mika & Karol Sztekler, 2021. "Adsorbents, Working Pairs and Coated Beds for Natural Refrigerants in Adsorption Chillers—State of the Art," Energies, MDPI, vol. 14(15), pages 1-41, August.

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