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Dynamic study of adsorbers by a new gravimetric version of the Large Temperature Jump method

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  • Sapienza, Alessio
  • Santamaria, Salvatore
  • Frazzica, Andrea
  • Freni, Angelo
  • Aristov, Yuri I.

Abstract

This paper presents a new experimental setup devoted to measure the ad-/desorption kinetics of an Ad-HEX (adsorbent+heat exchanger) under typical boundary conditions of an Adsorption Heat Transformer (AHT) as well as the results of the first test campaign carried out. The experimental apparatus can be considered as a gravimetric version of the known Large Temperature Jump method. In fact, the dynamic evolution of the uptake during the isobaric ad-/desorption stages is directly measured by a weighing system suitable to work in the range of 5–600g of sample mass (adsorbent+HEX) with the accuracy ±0.1g and the time response shorter than 0.1s The experimental campaign was conducted on an Ad-HEX composed of granules of a commercial SAPO-34 adsorbent placed on a flat type aluminum HEX, under operating conditions reproducing two different thermodynamic cycles (Th=90°C, Te=10°C, Tc=30 and 35°C), typical for adsorption air conditioning.

Suggested Citation

  • Sapienza, Alessio & Santamaria, Salvatore & Frazzica, Andrea & Freni, Angelo & Aristov, Yuri I., 2014. "Dynamic study of adsorbers by a new gravimetric version of the Large Temperature Jump method," Applied Energy, Elsevier, vol. 113(C), pages 1244-1251.
    • Handle: RePEc:eee:appene:v:113:y:2014:i:c:p:1244-1251
    DOI: 10.1016/j.apenergy.2013.09.005
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    1. Aristov, Yuriy I. & Glaznev, Ivan S. & Girnik, Ilya S., 2012. "Optimization of adsorption dynamics in adsorptive chillers: Loose grains configuration," Energy, Elsevier, vol. 46(1), pages 484-492.
    2. Gordeeva, Larisa G. & Aristov, Yuriy I., 2011. "Composite sorbent of methanol “LiCl in mesoporous silica gel” for adsorption cooling: Dynamic optimization," Energy, Elsevier, vol. 36(2), pages 1273-1279.
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    5. Choudhury, Biplab & Saha, Bidyut Baran & Chatterjee, Pradip K. & Sarkar, Jyoti Prakas, 2013. "An overview of developments in adsorption refrigeration systems towards a sustainable way of cooling," Applied Energy, Elsevier, vol. 104(C), pages 554-567.
    6. Zhai, X.Q. & Wang, R.Z. & Wu, J.Y. & Dai, Y.J. & Ma, Q., 2008. "Design and performance of a solar-powered air-conditioning system in a green building," Applied Energy, Elsevier, vol. 85(5), pages 297-311, May.
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    3. Sapienza, Alessio & Palomba, Valeria & Gullì, Giuseppe & Frazzica, Andrea & Vasta, Salvatore, 2017. "A new management strategy based on the reallocation of ads-/desorption times: Experimental operation of a full-scale 3 beds adsorption chiller," Applied Energy, Elsevier, vol. 205(C), pages 1081-1090.
    4. Santamaria, Salvatore & Sapienza, Alessio & Frazzica, Andrea & Freni, Angelo & Girnik, Ilya S. & Aristov, Yuri I., 2014. "Water adsorption dynamics on representative pieces of real adsorbers for adsorptive chillers," Applied Energy, Elsevier, vol. 134(C), pages 11-19.
    5. Elsayed, Ahmed M. & Askalany, Ahmed A. & Shea, Andrew D. & Dakkama, Hassan J. & Mahmoud, Saad & Al-Dadah, Raya & Kaialy, Waseem, 2017. "A state of the art of required techniques for employing activated carbon in renewable energy powered adsorption applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 503-519.
    6. Tokarev, M.M. & Aristov, Yu.I., 2017. "A new version of the Large Temperature Jump method: The thermal response (T–LTJ)," Energy, Elsevier, vol. 140(P1), pages 481-487.
    7. Valeria Palomba & Efstratios Varvagiannis & Sotirios Karellas & Andrea Frazzica, 2019. "Hybrid Adsorption-Compression Systems for Air Conditioning in Efficient Buildings: Design through Validated Dynamic Models," Energies, MDPI, vol. 12(6), pages 1-28, March.
    8. Aristov, Yuri I., 2020. "Dynamics of adsorptive heat conversion systems: Review of basics and recent advances," Energy, Elsevier, vol. 205(C).
    9. Gordeeva, Larisa & Frazzica, Andrea & Sapienza, Alessio & Aristov, Yuri & Freni, Angelo, 2014. "Adsorption cooling utilizing the “LiBr/silica – ethanol” working pair: Dynamic optimization of the adsorber/heat exchanger unit," Energy, Elsevier, vol. 75(C), pages 390-399.
    10. Okunev, Boris N. & Aristov, Yuri I., 2014. "Making adsorptive chillers faster by a proper choice of adsorption isobar shape: Comparison of optimal and real adsorbents," Energy, Elsevier, vol. 76(C), pages 400-405.
    11. Teng, W.S. & Leong, K.C. & Chakraborty, A., 2016. "Revisiting adsorption cooling cycle from mathematical modelling to system development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 315-332.
    12. Girnik, Ilya S. & Aristov, Yuri I., 2016. "Dynamic optimization of adsorptive chillers: The “AQSOA™-FAM-Z02 – Water” working pair," Energy, Elsevier, vol. 106(C), pages 13-22.
    13. Aristov, Yu. I., 2022. "Adsorption heat conversion and storage in closed systems: What have we learned over the past decade of this century?," Energy, Elsevier, vol. 239(PB).
    14. N'Tsoukpoe, Kokouvi Edem & Restuccia, Giovanni & Schmidt, Thomas & Py, Xavier, 2014. "The size of sorbents in low pressure sorption or thermochemical energy storage processes," Energy, Elsevier, vol. 77(C), pages 983-998.
    15. Palomba, Valeria & Sapienza, Alessio & Aristov, Yuri, 2019. "Dynamics and useful heat of the discharge stage of adsorptive cycles for long term thermal storage," Applied Energy, Elsevier, vol. 248(C), pages 299-309.
    16. Sapienza, Alessio & Velte, Andreas & Girnik, Ilya & Frazzica, Andrea & Füldner, Gerrit & Schnabel, Lena & Aristov, Yuri, 2017. "“Water - Silica Siogel” working pair for adsorption chillers: Adsorption equilibrium and dynamics," Renewable Energy, Elsevier, vol. 110(C), pages 40-46.
    17. An, G.L. & Wang, L.W. & Gao, J. & Wang, R.Z., 2018. "A review on the solid sorption mechanism and kinetic models of metal halide-ammonia working pairs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 783-792.
    18. Aristov, Yuri I., 2017. "Adsorptive transformation and storage of renewable heat: Review of current trends in adsorption dynamics," Renewable Energy, Elsevier, vol. 110(C), pages 105-114.
    19. Girnik, Ilya S. & Aristov, Yuri I., 2016. "Dynamics of water vapour adsorption by a monolayer of loose AQSOA™-FAM-Z02 grains: Indication of inseparably coupled heat and mass transfer," Energy, Elsevier, vol. 114(C), pages 767-773.
    20. Palomba, V. & Lombardo, W. & Groβe, A. & Herrmann, R. & Nitsch, B. & Strehlow, A. & Bastian, R. & Sapienza, A. & Frazzica, A., 2020. "Evaluation of in-situ coated porous structures for hybrid heat pumps," Energy, Elsevier, vol. 209(C).

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