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Optimization of hydrothermal co-liquefaction of seaweeds with lignocellulosic biomass: Merging 2nd and 3rd generation feedstocks for enhanced bio-oil production

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  • Yuan, Chuan
  • Wang, Shuang
  • Cao, Bin
  • Hu, Yamin
  • Abomohra, Abd El-Fatah
  • Wang, Qian
  • Qian, Lili
  • Liu, Lu
  • Liu, Xinlin
  • He, Zhixia
  • Sun, Chaoqun
  • Feng, Yongqiang
  • Zhang, Bo

Abstract

The present work aimed to explore the optimized conditions of hydrothermal co-liquefaction (co-HTL) of the green seaweed “Enteromorpha clathrata (EN)” and the lignocellulosic agricultural waste “rice husk (RH)”. Separate hydrothermal liquefaction (HTL) of EN and RH showed bio-oil yields of 26.0% and 45.6%, respectively. However, co-HTL under optimized conditions showed significant increase in the bio-oil yield by 71.7% over that of EN, and insignificant difference with that of RH. Nevertheless, the conversion ratio of co-HTL showed 10.6% significant increase over that of RH. GC-MS results showed that main compounds of EN and RH bio-oil lump into the C15–C20 and C5–C12 regions, mainly representing carbon range of diesel and gasoline, respectively. Short-chain (C5–C12) and long-chain (C14–C20) compounds in the bio-oil obtained by co-HTL represented 72% and 28%, respectively. In addition, the ratio of aromatic compounds in the bio-oil of RH was reduced by 9.3% as a result of co-HTL. In conclusion, results suggested 50% ethanol as a co-solvent, 300 °C and 45 min as optimum conditions for co-HTL of EN:RH (1:1 w/w). The present study demonstrated an efficient route for co-HTL of 3rd generation feedstocks with 2nd generation feedstocks which will have a significant impact on large-scale applications.

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  • Yuan, Chuan & Wang, Shuang & Cao, Bin & Hu, Yamin & Abomohra, Abd El-Fatah & Wang, Qian & Qian, Lili & Liu, Lu & Liu, Xinlin & He, Zhixia & Sun, Chaoqun & Feng, Yongqiang & Zhang, Bo, 2019. "Optimization of hydrothermal co-liquefaction of seaweeds with lignocellulosic biomass: Merging 2nd and 3rd generation feedstocks for enhanced bio-oil production," Energy, Elsevier, vol. 173(C), pages 413-422.
  • Handle: RePEc:eee:energy:v:173:y:2019:i:c:p:413-422
    DOI: 10.1016/j.energy.2019.02.091
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