IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i6p1708-d520198.html
   My bibliography  Save this article

Co-Hydrothermal Liquefaction of Lignocellulosic Biomass in Supercritical Water

Author

Listed:
  • Kamaldeep Sharma

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark)

  • Ayaz A. Shah

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark
    Department of Energy & Environment Engineering, Dawood University of Engineering & Technology, New M. A. Jinnah Road, Jamshed Quarters Muslimabad, Karachi 74800, Sindh, Pakistan)

  • Saqib S. Toor

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark)

  • Tahir H. Seehar

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark
    Department of Energy & Environment Engineering, Dawood University of Engineering & Technology, New M. A. Jinnah Road, Jamshed Quarters Muslimabad, Karachi 74800, Sindh, Pakistan)

  • Thomas H. Pedersen

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark)

  • Lasse A. Rosendahl

    (Department of Energy Technology, Aalborg University, Pontoppidanstræde 111, 9220 Aalborg, Denmark)

Abstract

Hydrothermal liquefaction (HTL) is an effective technology for bio-crude production. To date, various co-liquefaction studies were performed with contrasted (different composition) biomasses in subcritical water. Therefore, the present study investigated co-hydrothermal liquefaction of similar kinds of lignocellulosic biomasses (wheat straw, eucalyptus, and pinewood) in supercritical water under equal ratios at 400 °C with catalytic medium (K 2 CO 3 ). The lower bio-crude and higher solid yields were obtained in co-liquefaction experiments, as compared to liquefaction of individual feedstocks. On the other hand, higher carbon recovery and higher HHVs were noticed in co-liquefaction-derived bio-crudes. Gas chromatography with mass spectrometry (GC-MS) results showed that organic compounds were detected in all bio-crudes in the order of phenol derivatives > ketones/aldehydes > aromatics > carboxylic acids/esters. The aqueous phase from all samples contained higher TOC in the range of 19 to 33 g/L, with alkaline pH. In short, the co-liquefaction slightly improved the bio-crude quality with a significant reduction in bio-crude energy recovery. This reflects that co-liquefaction of lignocellulosic feedstock is not favorable for enhancing bio-crude yield and improving the overall process economics of HTL.

Suggested Citation

  • Kamaldeep Sharma & Ayaz A. Shah & Saqib S. Toor & Tahir H. Seehar & Thomas H. Pedersen & Lasse A. Rosendahl, 2021. "Co-Hydrothermal Liquefaction of Lignocellulosic Biomass in Supercritical Water," Energies, MDPI, vol. 14(6), pages 1-13, March.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:6:p:1708-:d:520198
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/6/1708/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/6/1708/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Xu, Donghai & Wang, Yang & Lin, Guike & Guo, Shuwei & Wang, Shuzhong & Wu, Zhiqiang, 2019. "Co-hydrothermal liquefaction of microalgae and sewage sludge in subcritical water: Ash effects on bio-oil production," Renewable Energy, Elsevier, vol. 138(C), pages 1143-1151.
    2. Chen, Wan-Ting & Zhang, Yuanhui & Zhang, Jixiang & Schideman, Lance & Yu, Guo & Zhang, Peng & Minarick, Mitchell, 2014. "Co-liquefaction of swine manure and mixed-culture algal biomass from a wastewater treatment system to produce bio-crude oil," Applied Energy, Elsevier, vol. 128(C), pages 209-216.
    3. Kumar, Mayank & Olajire Oyedun, Adetoyese & Kumar, Amit, 2018. "A review on the current status of various hydrothermal technologies on biomass feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1742-1770.
    4. Tahir H. Seehar & Saqib S. Toor & Ayaz A. Shah & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Biocrude Production from Wheat Straw at Sub and Supercritical Hydrothermal Liquefaction," Energies, MDPI, vol. 13(12), pages 1-18, June.
    5. Pedersen, T.H. & Grigoras, I.F. & Hoffmann, J. & Toor, S.S. & Daraban, I.M. & Jensen, C.U. & Iversen, S.B. & Madsen, R.B. & Glasius, M. & Arturi, K.R. & Nielsen, R.P. & Søgaard, E.G. & Rosendahl, L.A., 2016. "Continuous hydrothermal co-liquefaction of aspen wood and glycerol with water phase recirculation," Applied Energy, Elsevier, vol. 162(C), pages 1034-1041.
    6. Tungal, Richa & Shende, Rajesh V., 2014. "Hydrothermal liquefaction of pinewood (Pinus ponderosa) for H2, biocrude and bio-oil generation," Applied Energy, Elsevier, vol. 134(C), pages 401-412.
    7. Toor, Saqib Sohail & Rosendahl, Lasse & Rudolf, Andreas, 2011. "Hydrothermal liquefaction of biomass: A review of subcritical water technologies," Energy, Elsevier, vol. 36(5), pages 2328-2342.
    8. Daniele Castello & Thomas Helmer Pedersen & Lasse Aistrup Rosendahl, 2018. "Continuous Hydrothermal Liquefaction of Biomass: A Critical Review," Energies, MDPI, vol. 11(11), pages 1-35, November.
    9. Zhu, Zhe & Rosendahl, Lasse & Toor, Saqib Sohail & Yu, Donghong & Chen, Guanyi, 2015. "Hydrothermal liquefaction of barley straw to bio-crude oil: Effects of reaction temperature and aqueous phase recirculation," Applied Energy, Elsevier, vol. 137(C), pages 183-192.
    10. Gollakota, A.R.K. & Kishore, Nanda & Gu, Sai, 2018. "A review on hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1378-1392.
    11. Akhtar, Javaid & Amin, Nor Aishah Saidina, 2011. "A review on process conditions for optimum bio-oil yield in hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1615-1624, April.
    12. Yang, Jie & (Sophia) He, Quan & Yang, Linxi, 2019. "A review on hydrothermal co-liquefaction of biomass," Applied Energy, Elsevier, vol. 250(C), pages 926-945.
    13. Ayaz A. Shah & Saqib S. Toor & Tahir H. Seehar & Rasmus S. Nielsen & Asbjørn H. Nielsen & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Bio-Crude Production through Aqueous Phase Recycling of Hydrothermal Liquefaction of Sewage Sludge," Energies, MDPI, vol. 13(2), pages 1-18, January.
    14. Dimitriadis, Athanasios & Bezergianni, Stella, 2017. "Hydrothermal liquefaction of various biomass and waste feedstocks for biocrude production: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 113-125.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Guanyu Zhang & Kejie Wang & Quan Liu & Lujia Han & Xuesong Zhang, 2022. "A Comprehensive Hydrothermal Co-Liquefaction of Diverse Biowastes for Energy-Dense Biocrude Production: Synergistic and Antagonistic Effects," IJERPH, MDPI, vol. 19(17), pages 1-17, August.
    2. Ankit Mathanker & Snehlata Das & Deepak Pudasainee & Monir Khan & Amit Kumar & Rajender Gupta, 2021. "A Review of Hydrothermal Liquefaction of Biomass for Biofuels Production with a Special Focus on the Effect of Process Parameters, Co-Solvents, and Extraction Solvents," Energies, MDPI, vol. 14(16), pages 1-60, August.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tahir H. Seehar & Saqib S. Toor & Ayaz A. Shah & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Biocrude Production from Wheat Straw at Sub and Supercritical Hydrothermal Liquefaction," Energies, MDPI, vol. 13(12), pages 1-18, June.
    2. Ayaz Ali Shah & Saqib Sohail Toor & Asbjørn Haaning Nielsen & Thomas Helmer Pedersen & Lasse Aistrup Rosendahl, 2021. "Bio-Crude Production through Recycling of Pretreated Aqueous Phase via Activated Carbon," Energies, MDPI, vol. 14(12), pages 1-20, June.
    3. Gollakota, A.R.K. & Kishore, Nanda & Gu, Sai, 2018. "A review on hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1378-1392.
    4. Ankit Mathanker & Snehlata Das & Deepak Pudasainee & Monir Khan & Amit Kumar & Rajender Gupta, 2021. "A Review of Hydrothermal Liquefaction of Biomass for Biofuels Production with a Special Focus on the Effect of Process Parameters, Co-Solvents, and Extraction Solvents," Energies, MDPI, vol. 14(16), pages 1-60, August.
    5. Yang, Jie & (Sophia) He, Quan & Yang, Linxi, 2019. "A review on hydrothermal co-liquefaction of biomass," Applied Energy, Elsevier, vol. 250(C), pages 926-945.
    6. Yan, Shuo & Xia, Dehong & Zhang, Xinru & Liu, Xiangjun, 2022. "Synergistic mechanism of enhanced biocrude production during hydrothermal co-liquefaction of biomass model components: A molecular dynamics simulation," Energy, Elsevier, vol. 255(C).
    7. Li, Qingyin & Yuan, Xiangzhou & Hu, Xun & Meers, Erik & Ong, Hwai Chyuan & Chen, Wei-Hsin & Duan, Peigao & Zhang, Shicheng & Lee, Ki Bong & Ok, Yong Sik, 2022. "Co-liquefaction of mixed biomass feedstocks for bio-oil production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    8. Ayaz A. Shah & Saqib S. Toor & Tahir H. Seehar & Rasmus S. Nielsen & Asbjørn H. Nielsen & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Bio-Crude Production through Aqueous Phase Recycling of Hydrothermal Liquefaction of Sewage Sludge," Energies, MDPI, vol. 13(2), pages 1-18, January.
    9. SundarRajan, P. & Gopinath, K.P. & Arun, J. & GracePavithra, K. & Adithya Joseph, A. & Manasa, S., 2021. "Insights into valuing the aqueous phase derived from hydrothermal liquefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    10. Daniele Castello & Thomas Helmer Pedersen & Lasse Aistrup Rosendahl, 2018. "Continuous Hydrothermal Liquefaction of Biomass: A Critical Review," Energies, MDPI, vol. 11(11), pages 1-35, November.
    11. Genel, Salih & Durak, Halil & Durak, Emre Demirer & Güneş, Hasret & Genel, Yaşar, 2023. "Hydrothermal liquefaction of biomass with molybdenum, aluminum, cobalt metal powder catalysts and evaluation of wastewater by fungus cultivation," Renewable Energy, Elsevier, vol. 203(C), pages 20-32.
    12. Kumar, R. & Strezov, V., 2021. "Thermochemical production of bio-oil: A review of downstream processing technologies for bio-oil upgrading, production of hydrogen and high value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    13. Xu, Donghai & Lin, Guike & Guo, Shuwei & Wang, Shuzhong & Guo, Yang & Jing, Zefeng, 2018. "Catalytic hydrothermal liquefaction of algae and upgrading of biocrude: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 97(C), pages 103-118.
    14. Liu, Quan & Zhang, Guanyu & Liu, Mingyang & Kong, Ge & Xu, Ruolan & Han, Lujia & Zhang, Xuesong, 2022. "Fast hydrothermal liquefaction coupled with homogeneous catalysts to valorize livestock manure for enhanced biocrude oil and hydrochar production," Renewable Energy, Elsevier, vol. 198(C), pages 521-533.
    15. Li, Bingshuo & Liu, Yixuan & Yang, Tianhua & Feng, Bixuan & Kai, Xingping & Wang, Shurong & Li, Rundong, 2021. "Aqueous phase reforming of biocrude derived from lignocellulose hydrothermal liquefaction: Conditions optimization and mechanism study," Renewable Energy, Elsevier, vol. 175(C), pages 98-107.
    16. Marco Balsamo & Francesca Di Lauro & Maria Laura Alfieri & Paola Manini & Piero Salatino & Fabio Montagnaro & Roberto Solimene, 2024. "Unravelling the Role of Biochemical Compounds within the Hydrothermal Liquefaction Process of Real Sludge Mixtures," Sustainability, MDPI, vol. 16(5), pages 1-18, February.
    17. Arun, J. & Raghu, R. & Suhail Madhar Hanif, S. & Thilak, P.G. & Sridhar, D. & Nirmala, N. & Dawn, S.S. & Sivaramakrishnan, R. & Chi, Nguyen Thuy Lan & Pugazhendhi, Arivalagan, 2022. "A comparative review on photo and mixotrophic mode of algae cultivation: Thermochemical processing of biomass, necessity of bio-oil upgrading, challenges and future roadmaps," Applied Energy, Elsevier, vol. 325(C).
    18. Prajitno, Hermawan & Park, Jongkeun & Ryu, Changkook & Park, Ho Young & Lim, Hyun Soo & Kim, Jaehoon, 2018. "Effects of solvent participation and controlled product separation on biomass liquefaction: A case study of sewage sludge," Applied Energy, Elsevier, vol. 218(C), pages 402-416.
    19. Nikolaos Montesantos & Marco Maschietti, 2020. "Supercritical Carbon Dioxide Extraction of Lignocellulosic Bio-Oils: The Potential of Fuel Upgrading and Chemical Recovery," Energies, MDPI, vol. 13(7), pages 1-35, April.
    20. Bi, Zheting & Zhang, Ji & Zhu, Zeying & Liang, Yanna & Wiltowski, Tomasz, 2018. "Generating biocrude from partially defatted Cryptococcus curvatus yeast residues through catalytic hydrothermal liquefaction," Applied Energy, Elsevier, vol. 209(C), pages 435-444.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:6:p:1708-:d:520198. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.