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Hydrogen Production through Autothermal Reforming of Ethanol: Enhancement of Ni Catalyst Performance via Promotion

Author

Listed:
  • Ekaterina Matus

    (Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia)

  • Olga Sukhova

    (Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia)

  • Ilyas Ismagilov

    (Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia)

  • Mikhail Kerzhentsev

    (Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia)

  • Olga Stonkus

    (Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia)

  • Zinfer Ismagilov

    (Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia
    Federal State Budget Scientific Centre «The Federal Research Center of Coal and Coal-Chemistry of Siberian Branch of the Russian Academy of Sciences», 650000 Kemerovo, Russia)

Abstract

Autothermal reforming of bioethanol (ATR of C 2 H 5 OH) over promoted Ni/Ce 0.8 La 0.2 O 1.9 catalysts was studied to develop carbon-neutral technologies for hydrogen production. The regulation of the functional properties of the catalysts was attained by adjusting their nanostructure and reducibility by introducing various types and content of M promoters (M = Pt, Pd, Rh, Re; molar ratio M/Ni = 0.003–0.012). The composition–characteristics–activity correlation was determined using catalyst testing in ATR of C 2 H 5 OH, thermal analysis, N 2 adsorption, X-ray diffraction, transmission electron microscopy, and EDX analysis. It was shown that the type and content of the promoter, as well as the preparation mode (combined or sequential impregnation methods), determine the redox properties of catalysts and influence the textural and structural characteristics of the samples. The reducibility of catalysts improves in the following sequence of promoters: Re < Rh < Pd < Pt, with an increase in their content, and when using the co-impregnation method. It was found that in ATR of C 2 H 5 OH over bimetallic Ni-M/Ce 0.8 La 0.2 O 1.9 catalysts at 600 °C, the hydrogen yield increased in the following row of promoters: Pt < Rh < Pd < Re at 100% conversion of ethanol. The introduction of M leads to the formation of a NiM alloy under reaction conditions and affects the resistance of the catalyst to oxidation, sintering, and coking. It was found that for enhancing Ni catalyst performance in H 2 production through ATR of C 2 H 5 OH, the most effective promotion is with Re: at 600 °C over the optimum 10Ni-0.4Re/Ce 0.8 La 0.2 O 1.9 catalyst the highest hydrogen yield 65% was observed.

Suggested Citation

  • Ekaterina Matus & Olga Sukhova & Ilyas Ismagilov & Mikhail Kerzhentsev & Olga Stonkus & Zinfer Ismagilov, 2021. "Hydrogen Production through Autothermal Reforming of Ethanol: Enhancement of Ni Catalyst Performance via Promotion," Energies, MDPI, vol. 14(16), pages 1-16, August.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:16:p:5176-:d:619180
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    References listed on IDEAS

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    Cited by:

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    2. Ratikorn Sornumpol & Dang Saebea & Amornchai Arpornwichanop & Yaneeporn Patcharavorachot, 2023. "Process Optimization and CO 2 Emission Analysis of Coal/Biomass Gasification Integrated with a Chemical Looping Process," Energies, MDPI, vol. 16(6), pages 1-17, March.
    3. Vladislav Sadykov, 2023. "Advances in Hydrogen and Syngas Generation," Energies, MDPI, vol. 16(7), pages 1-4, March.
    4. Bogdan Ulejczyk & Łukasz Nogal & Michał Młotek & Krzysztof Krawczyk, 2022. "Efficient Plasma Technology for the Production of Green Hydrogen from Ethanol and Water," Energies, MDPI, vol. 15(8), pages 1-14, April.
    5. Ekaterina Matus & Mikhail Kerzhentsev & Ilyas Ismagilov & Andrey Nikitin & Sergey Sozinov & Zinfer Ismagilov, 2023. "Hydrogen Production from Biogas: Development of an Efficient Nickel Catalyst by the Exsolution Approach," Energies, MDPI, vol. 16(7), pages 1-21, March.
    6. Eugenio Meloni & Marco Martino & Giuseppina Iervolino & Concetta Ruocco & Simona Renda & Giovanni Festa & Vincenzo Palma, 2022. "The Route from Green H 2 Production through Bioethanol Reforming to CO 2 Catalytic Conversion: A Review," Energies, MDPI, vol. 15(7), pages 1-36, March.

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