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Ethanol steam reforming for hydrogen production: Latest and effective catalyst modification strategies to minimize carbonaceous deactivation

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  • Sharma, Yogesh Chandra
  • Kumar, Ashutosh
  • Prasad, Ram
  • Upadhyay, Siddh Nath

Abstract

Hydrogen is being contemplated as the future fuel in view of the abundant availability of hydrogen bearing substances in nature, its high energy content (120.7kJ/g), and its combustion without creating any environmental pollution. Pollution free sources for hydrogen generation and efficient conversion to useful energy are the two important factors controlling the development of hydrogen economy. Out of various liquid hydrogen sources, ethanol is a sustainable candidate because of its renewable nature, increasing availability, biodegradable nature, low toxicity, and ease of transport. It can be easily converted to a hydrogen rich mixture through catalytic steam reforming process. Further, ethanol steam reforming (ESR) is thermodynamically feasible and does not cause catalyst poisoning due to complete absence of S-impurities. However, the carbonaceous deposition during ESR is still an issue to make it sustainable for hydrogen generation. This review contains all parallel possible reactions besides the desired reactions, which can promote carbonaceous deposition over catalyst surface with respect to temperature. The role of operating conditions such as water and ethanol feed ratio and temperature with carbon generation were interrelated. The characterization of different carbon forms synthesized during ESR and the possible role of active catalyst into carbon synthesis mechanism was also considered. The contribution of precursor used for catalyst preparation, the role of active metals, the interaction between active metals for bimetallic catalyst, different kind of support prominently studied for ESR and their structural behaviors were also correlated. This review makes an attempt to critically summarize the recent strategies used to reduce the carbonaceous deactivation of catalyst during ESR on the basis of available literature survey. The focus of the review is catalyst deactivation due to carbonaceous deposition during reforming and possible strategies used to control the deactivation process during ESR.

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  • Sharma, Yogesh Chandra & Kumar, Ashutosh & Prasad, Ram & Upadhyay, Siddh Nath, 2017. "Ethanol steam reforming for hydrogen production: Latest and effective catalyst modification strategies to minimize carbonaceous deactivation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 89-103.
    • Handle: RePEc:eee:rensus:v:74:y:2017:i:c:p:89-103
    DOI: 10.1016/j.rser.2017.02.049
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    1. Ayalur Chattanathan, Shyamsundar & Adhikari, Sushil & Abdoulmoumine, Nourredine, 2012. "A review on current status of hydrogen production from bio-oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2366-2372.
    2. Hou, Tengfei & Zhang, Shaoyin & Chen, Yongdong & Wang, Dazhi & Cai, Weijie, 2015. "Hydrogen production from ethanol reforming: Catalysts and reaction mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 132-148.
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    3. Charisiou, N.D. & Italiano, C. & Pino, L. & Sebastian, V. & Vita, A. & Goula, M.A., 2020. "Hydrogen production via steam reforming of glycerol over Rh/γ-Al2O3 catalysts modified with CeO2, MgO or La2O3," Renewable Energy, Elsevier, vol. 162(C), pages 908-925.
    4. Deng, Yimin & Li, Shuo & Appels, Lise & Zhang, Huili & Sweygers, Nick & Baeyens, Jan & Dewil, Raf, 2023. "Steam reforming of ethanol by non-noble metal catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    5. Wang, Yishuang & Liang, Defang & Wang, Chunsheng & Chen, Mingqiang & Tang, Zhiyuan & Hu, Jiaxin & Yang, Zhonglian & Zhang, Han & Wang, Jun & Liu, Shaomin, 2020. "Influence of calcination temperature of Ni/Attapulgite on hydrogen production by steam reforming ethanol," Renewable Energy, Elsevier, vol. 160(C), pages 597-611.
    6. Satinover, Scott J. & Schell, Dan & Borole, Abhijeet P., 2020. "Achieving high hydrogen productivities of 20 L/L-day via microbial electrolysis of corn stover fermentation products," Applied Energy, Elsevier, vol. 259(C).
    7. Łukajtis, Rafał & Hołowacz, Iwona & Kucharska, Karolina & Glinka, Marta & Rybarczyk, Piotr & Przyjazny, Andrzej & Kamiński, Marian, 2018. "Hydrogen production from biomass using dark fermentation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 665-694.
    8. Vincenzo Palma & Concetta Ruocco & Eugenio Meloni & Antonio Ricca, 2017. "Influence of Catalytic Formulation and Operative Conditions on Coke Deposition over CeO 2 -SiO 2 Based Catalysts for Ethanol Reforming," Energies, MDPI, vol. 10(7), pages 1-13, July.
    9. Greluk, Magdalena & Rotko, Marek & Turczyniak-Surdacka, Sylwia, 2020. "Enhanced catalytic performance of La2O3 promoted Co/CeO2 and Ni/CeO2 catalysts for effective hydrogen production by ethanol steam reforming," Renewable Energy, Elsevier, vol. 155(C), pages 378-395.
    10. Eugenio Meloni & Marco Martino & Giuseppina Iervolino & Concetta Ruocco & Simona Renda & Giovanni Festa & Vincenzo Palma, 2022. "The Route from Green H 2 Production through Bioethanol Reforming to CO 2 Catalytic Conversion: A Review," Energies, MDPI, vol. 15(7), pages 1-36, March.

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