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Thermodynamic analysis and reaction routes of steam reforming of bio-oil aqueous fraction

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  • Resende, K.A.
  • Ávila-Neto, C.N.
  • Rabelo-Neto, R.C.
  • Noronha, F.B.
  • Hori, C.E.

Abstract

Steam reforming of the bio-oil aqueous fraction is a potential process to produce hydrogen. Therefore, to perform a thermodynamic study of this process can be interesting to determine the most favorable operating conditions. The calculations were made using a model compound and an aqueous fraction of a specific bio-oil. The data were obtained at different temperatures and for different steam(S)/fuel(F)ratios. Thermodynamic data showed that the behavior of model compounds was very similar to the one observed for the aqueous fraction of bio-oil. Therefore, acetic acid was used as a model compound of the aqueous fraction of bio-oil in the experimental tests. Temperature-programmed acetic acid desorption, temperature programmed reaction and steam reforming reactions were conducted. The experimental results were correlated with data predicted by thermodynamic analyses. There was a good correlation between the experimental results and predicted by equilibrium calculations. It helped to clarify the possible reactions pathways that are present in the reform process studied. According to the results the steam reforming of acetic acid can follow two different routes: (i) acetic acid can be converted to acetone at intermediate temperatures or (ii) acetic acid is transformed into adsorbed acetate species (CH3COO*) followed by decomposition into acetyl species (CH3CO*).

Suggested Citation

  • Resende, K.A. & Ávila-Neto, C.N. & Rabelo-Neto, R.C. & Noronha, F.B. & Hori, C.E., 2015. "Thermodynamic analysis and reaction routes of steam reforming of bio-oil aqueous fraction," Renewable Energy, Elsevier, vol. 80(C), pages 166-176.
    • Handle: RePEc:eee:renene:v:80:y:2015:i:c:p:166-176
    DOI: 10.1016/j.renene.2015.01.057
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    References listed on IDEAS

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    1. Ayalur Chattanathan, Shyamsundar & Adhikari, Sushil & Abdoulmoumine, Nourredine, 2012. "A review on current status of hydrogen production from bio-oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2366-2372.
    2. Medrano, J.A. & Oliva, M. & Ruiz, J. & García, L. & Arauzo, J., 2011. "Hydrogen from aqueous fraction of biomass pyrolysis liquids by catalytic steam reforming in fluidized bed," Energy, Elsevier, vol. 36(4), pages 2215-2224.
    3. An, Lu & Dong, Changqing & Yang, Yongping & Zhang, Junjiao & He, Lei, 2011. "The influence of Ni loading on coke formation in steam reforming of acetic acid," Renewable Energy, Elsevier, vol. 36(3), pages 930-935.
    4. de Ávila, C.N. & Hori, C.E. & de Assis, A.J., 2011. "Thermodynamic assessment of hydrogen production and cobalt oxidation susceptibility under ethanol reforming conditions," Energy, Elsevier, vol. 36(7), pages 4385-4395.
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    1. Ochoa, Aitor & Bilbao, Javier & Gayubo, Ana G. & Castaño, Pedro, 2020. "Coke formation and deactivation during catalytic reforming of biomass and waste pyrolysis products: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    2. Chen, Guanyi & Tao, Junyu & Liu, Caixia & Yan, Beibei & Li, Wanqing & Li, Xiangping, 2017. "Hydrogen production via acetic acid steam reforming: A critical review on catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1091-1098.
    3. Resende, K.A. & de Souza, P.M. & Noronha, F.B. & Hori, C.E., 2019. "Thermodynamic analysis of phenol hydrodeoxygenation reaction system in gas phase," Renewable Energy, Elsevier, vol. 136(C), pages 365-372.

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