IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v162y2020icp134-143.html
   My bibliography  Save this article

Degradation effect of Ce/Al2O3 catalyst on pyrolysis volatility of pine

Author

Listed:
  • Pang, Yunji
  • Wu, Yuting
  • Chen, Yisheng
  • Luo, Fuliang
  • Chen, Junjun

Abstract

Supported catalysts were prepared with CeCl3 and CeO2 as active components, the catalytic degradation of volatiles from pine particle pyrolysis was studied. Activated alumina was used as the carrier of CeO2 and CeCl3 to prepare CeO2/Al2O3 and CeCl3/Al2O3 catalysts. Experimental results show that the two catalysts can effectively reduce the yield of pyrolysis liquid-phase products and markedly increase the yield of gas-phase products. Compared with no catalyst, the liquid product yield decreased by 25.69% and the pyrolysis gas yield increased by 29.48% at a pyrolysis temperature of 650 °C by using CeO2/Al2O3 catalyst. The active components in CeO2 reduced the volume fraction of CnHm in pyrolysis gas and increased the volume fraction of H2. Under the catalysis of CeCl3/Al2O3, the CO content and the low calorific value of the product gas increases. The addition of the two catalysts cracked the oxygen-containing functional groups in the tar to various extents, reducing the tar yield and increasing the pyrolysis gas yield. For the simple reduction of tar yield in pyrolysis gas, the catalytic cracking effect of CeO2/Al2O3 catalyst was better than that of CeCl3/Al2O3 catalyst, and CeCl3/Al2O3 catalyst should be selected when degrading tar while obtaining a relatively high low heating value.

Suggested Citation

  • Pang, Yunji & Wu, Yuting & Chen, Yisheng & Luo, Fuliang & Chen, Junjun, 2020. "Degradation effect of Ce/Al2O3 catalyst on pyrolysis volatility of pine," Renewable Energy, Elsevier, vol. 162(C), pages 134-143.
    • Handle: RePEc:eee:renene:v:162:y:2020:i:c:p:134-143
    DOI: 10.1016/j.renene.2020.07.125
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120312015
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.07.125?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Safar, Michal & Lin, Bo-Jhih & Chen, Wei-Hsin & Langauer, David & Chang, Jo-Shu & Raclavska, H. & Pétrissans, Anélie & Rousset, Patrick & Pétrissans, Mathieu, 2019. "Catalytic effects of potassium on biomass pyrolysis, combustion and torrefaction," Applied Energy, Elsevier, vol. 235(C), pages 346-355.
    2. Hu, Mian & Laghari, Mahmood & Cui, Baihui & Xiao, Bo & Zhang, Beiping & Guo, Dabin, 2018. "Catalytic cracking of biomass tar over char supported nickel catalyst," Energy, Elsevier, vol. 145(C), pages 228-237.
    3. Thitsartarn, Warintorn & Maneerung, Thawatchai & Kawi, Sibudjing, 2015. "Highly active and durable Ca-doped Ce-SBA-15 catalyst for biodiesel production," Energy, Elsevier, vol. 89(C), pages 946-956.
    4. Hervy, Maxime & Weiss-Hortala, Elsa & Pham Minh, Doan & Dib, Hadi & Villot, Audrey & Gérente, Claire & Berhanu, Sarah & Chesnaud, Anthony & Thorel, Alain & Le Coq, Laurence & Nzihou, Ange, 2019. "Reactivity and deactivation mechanisms of pyrolysis chars from bio-waste during catalytic cracking of tar," Applied Energy, Elsevier, vol. 237(C), pages 487-499.
    5. An, Lu & Dong, Changqing & Yang, Yongping & Zhang, Junjiao & He, Lei, 2011. "The influence of Ni loading on coke formation in steam reforming of acetic acid," Renewable Energy, Elsevier, vol. 36(3), pages 930-935.
    6. Niu, Shengli & Zhang, Xiangyu & Ning, Yilin & Zhang, Yujiao & Qu, Tongxin & Hu, Xun & Gong, Zhiqiang & Lu, Chunmei, 2020. "Dolomite incorporated with cerium to enhance the stability in catalyzing transesterification for biodiesel production," Renewable Energy, Elsevier, vol. 154(C), pages 107-116.
    7. Sebestyén, Z. & Barta-Rajnai, E. & Bozi, J. & Blazsó, M. & Jakab, E. & Miskolczi, N. & Sója, J. & Czégény, Zs., 2017. "Thermo-catalytic pyrolysis of biomass and plastic mixtures using HZSM-5," Applied Energy, Elsevier, vol. 207(C), pages 114-122.
    8. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    9. Saraeian, Alireza & Nolte, Michael W. & Shanks, Brent H., 2019. "Deoxygenation of biomass pyrolysis vapors: Improving clarity on the fate of carbon," Renewable and Sustainable Energy Reviews, Elsevier, vol. 104(C), pages 262-280.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Longzhi & Cai, Dongqiang & Zhang, Lianjie & Zhang, Yue & Zhao, Zhiyang & Zhang, Zhonglei & Sun, Jifu & Tan, Yongdong & Zou, Guifu, 2023. "Synergistic effects during pyrolysis of binary mixtures of biomass components using microwave-assisted heating coupled with iron base tip-metal," Renewable Energy, Elsevier, vol. 203(C), pages 312-322.
    2. Yousef, Samy & Eimontas, Justas & Striūgas, Nerijus & Abdelnaby, Mohammed Ali, 2022. "Gasification kinetics of char derived from metallised food packaging plastics waste pyrolysis," Energy, Elsevier, vol. 239(PB).
    3. Chen, Chunxiang & Zhao, Jian & Wei, Yixue & Huang, Xiaodong & Lu, Wei & Fan, Dianzhao & Bi, Yingxin & Qiu, Hongfu, 2023. "Influence of graphite/alumina on co-pyrolysis of Chlorella vulgaris and polypropylene for producing bio-oil," Energy, Elsevier, vol. 265(C).
    4. Dong, Yichen & Mao, Songbo & Guo, Feiqiang & Shu, Rui & Bai, Jiaming & Qian, Lin & Bai, Yonghui, 2022. "Coal gasification fine slags: Investigation of the potential as both microwave adsorbers and catalysts in microwave-induced biomass pyrolysis applications," Energy, Elsevier, vol. 238(PB).
    5. Jiang, Haifeng & Liu, Haipeng & Dong, Jiaxin & Song, Jiaxing & Deng, Sunhua & Chen, Jie & Zhang, Yu & Hong, Wenpeng, 2022. "Enhancing ketones and syngas production by CO2-assisted catalytic pyrolysis of cellulose with the Ce–Co–Na ternary catalyst," Energy, Elsevier, vol. 250(C).
    6. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part II: Catalytic research," Renewable Energy, Elsevier, vol. 189(C), pages 315-338.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Kan, Tao & Strezov, Vladimir & Evans, Tim & He, Jing & Kumar, Ravinder & Lu, Qiang, 2020. "Catalytic pyrolysis of lignocellulosic biomass: A review of variations in process factors and system structure," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    2. Salvilla, John Nikko V. & Ofrasio, Bjorn Ivan G. & Rollon, Analiza P. & Manegdeg, Ferdinand G. & Abarca, Ralf Ruffel M. & de Luna, Mark Daniel G., 2020. "Synergistic co-pyrolysıs of polyolefin plastics with wood and agricultural wastes for biofuel production," Applied Energy, Elsevier, vol. 279(C).
    3. Wang, Shuxiao & Zhang, Yuyuan & Shan, Rui & Gu, Jing & Yuan, Haoran & Chen, Yong, 2022. "Steam reforming of biomass tar model compound over two waste char-based Ni catalysts for syngas production," Energy, Elsevier, vol. 246(C).
    4. Bhoi, P.R. & Ouedraogo, A.S. & Soloiu, V. & Quirino, R., 2020. "Recent advances on catalysts for improving hydrocarbon compounds in bio-oil of biomass catalytic pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    5. Md Sumon Reza & Zhanar Baktybaevna Iskakova & Shammya Afroze & Kairat Kuterbekov & Asset Kabyshev & Kenzhebatyr Zh. Bekmyrza & Marzhan M. Kubenova & Muhammad Saifullah Abu Bakar & Abul K. Azad & Hrido, 2023. "Influence of Catalyst on the Yield and Quality of Bio-Oil for the Catalytic Pyrolysis of Biomass: A Comprehensive Review," Energies, MDPI, vol. 16(14), pages 1-39, July.
    6. Shen, Feng & Xiong, Xinni & Fu, Junyan & Yang, Jirui & Qiu, Mo & Qi, Xinhua & Tsang, Daniel C.W., 2020. "Recent advances in mechanochemical production of chemicals and carbon materials from sustainable biomass resources," Renewable and Sustainable Energy Reviews, Elsevier, vol. 130(C).
    7. Wang, Shuxiao & Shan, Rui & Lu, Tao & Zhang, Yuyuan & Yuan, Haoran & Chen, Yong, 2020. "Pyrolysis char derived from waste peat for catalytic reforming of tar model compound," Applied Energy, Elsevier, vol. 263(C).
    8. Gu, Jing & Wang, Shuxiao & Lu, Tao & Wu, Yufeng & Yuan, Haoran & Chen, Yong, 2020. "Synthesis and evaluation of pyrolysis waste peat char supported catalyst for steam reforming of toluene," Renewable Energy, Elsevier, vol. 160(C), pages 964-973.
    9. Palizdar, A. & Sadrameli, S.M., 2020. "Catalytic upgrading of biomass pyrolysis oil over tailored hierarchical MFI zeolite: Effect of porosity enhancement and porosity-acidity interaction on deoxygenation reactions," Renewable Energy, Elsevier, vol. 148(C), pages 674-688.
    10. Ong, Hwai Chyuan & Chen, Wei-Hsin & Farooq, Abid & Gan, Yong Yang & Lee, Keat Teong & Ashokkumar, Veeramuthu, 2019. "Catalytic thermochemical conversion of biomass for biofuel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    11. Li, Chao & Sun, Yifan & Li, Qingyang & Zhang, Lijun & Zhang, Shu & Wang, Huaisheng & Hu, Guangzhi & Hu, Xun, 2022. "Effects of volatiles on properties of char during sequential pyrolysis of PET and cellulose," Renewable Energy, Elsevier, vol. 189(C), pages 139-151.
    12. Ayub, Yousaf & Ren, Jingzheng & Shi, Tao & Shen, Weifeng & He, Chang, 2023. "Poultry litter valorization: Development and optimization of an electro-chemical and thermal tri-generation process using an extreme gradient boosting algorithm," Energy, Elsevier, vol. 263(PC).
    13. Zhang, Zhikun & Zhu, Zongyuan & Shen, Boxiong & Liu, Lina, 2019. "Insights into biochar and hydrochar production and applications: A review," Energy, Elsevier, vol. 171(C), pages 581-598.
    14. Zhao, Ming & Memon, Muhammad Zaki & Ji, Guozhao & Yang, Xiaoxiao & Vuppaladadiyam, Arun K. & Song, Yinqiang & Raheem, Abdul & Li, Jinhui & Wang, Wei & Zhou, Hui, 2020. "Alkali metal bifunctional catalyst-sorbents enabled biomass pyrolysis for enhanced hydrogen production," Renewable Energy, Elsevier, vol. 148(C), pages 168-175.
    15. Zang, Guiyan & Zhang, Jianan & Jia, Junxi & Lora, Electo Silva & Ratner, Albert, 2020. "Life cycle assessment of power-generation systems based on biomass integrated gasification combined cycles," Renewable Energy, Elsevier, vol. 149(C), pages 336-346.
    16. Kumar, R. & Strezov, V., 2021. "Thermochemical production of bio-oil: A review of downstream processing technologies for bio-oil upgrading, production of hydrogen and high value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    17. Gupta, Shubhi & Gupta, Goutam Kishore & Mondal, Monoj Kumar, 2019. "Slow pyrolysis of chemically treated walnut shell for valuable products: Effect of process parameters and in-depth product analysis," Energy, Elsevier, vol. 181(C), pages 665-676.
    18. Adnan, Muflih A. & Hossain, Mohammad M. & Kibria, Md Golam, 2020. "Biomass upgrading to high-value chemicals via gasification and electrolysis: A thermodynamic analysis," Renewable Energy, Elsevier, vol. 162(C), pages 1367-1379.
    19. Yan, Beibei & Li, Songjiang & Cao, Xingsijin & Zhu, Xiaochao & Li, Jian & Zhou, Shengquan & Zhao, Juan & Sun, Yunan & Chen, Guanyi, 2023. "Flue gas torrefaction integrated with gasification based on the circulation of Mg-additive," Applied Energy, Elsevier, vol. 333(C).
    20. Lech Nowicki & Dorota Siuta & Maciej Markowski, 2020. "Pyrolysis of Rapeseed Oil Press Cake and Steam Gasification of Solid Residues," Energies, MDPI, vol. 13(17), pages 1-12, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:162:y:2020:i:c:p:134-143. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.