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Integrated Leaching and Thermochemical Technologies for Producing High-Value Products from Rice Husk: Leaching of Rice Husk with the Aqueous Phases of Bioliquids

Author

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  • Wenran Gao

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China)

  • Hui Li

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China)

  • Karnowo

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
    Faculty of Engineering, Universitas Negeri Semarang (UNNES), Jawa Tengah 50229, Indonesia)

  • Bing Song

    (Scion, Te Papa Tipu Innovation Park, 49 Sala Street, Private Bag 3020, Rotorua 3046, New Zealand)

  • Shu Zhang

    (Joint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China)

Abstract

It remains challenging to develop a techno-economically feasible method to remove alkali and alkaline earth metal species (AAEMs) from rice husk (RH), which is a widely available bioresource across the world. In this study, the AAEMs leaching effect of aqueous phases of both bio-crude prepared by hydrothermal liquefaction (AP-HT) and bio-oil prepared by pyrolysis (AP-Pyro) of RH were systematically investigated. The results indicated that although the acidity of AP-HT and AP-Pyro are much lower than that of HCl, they performed a comparable removal efficiency on AAEMs (Na: 56.2%, K: 96.7%, Mg: 91.0%, Ca: 46.1% for AP-HT, while Na: 58.9%, K: 96.9%, Mg: 94.0%, Ca: 86.3% for AP-Pyro) with HCl. The presence of phenolics in bio-oil could facilitate the penetration of water and organic acids into the inner area of RH cells, thus enhancing the AAEMs removal via chelate reactions. The thermal stability of leached RH during thermochemical conversions was studied via TG and Py-GC-MS. The results showed that the heat conduction efficiency in leached RH was enhanced with a high pyrolysis rate, resulting in a narrow carbon chain distribution (C 5 –C 10 ) of derived chemical compounds.

Suggested Citation

  • Wenran Gao & Hui Li & Karnowo & Bing Song & Shu Zhang, 2020. "Integrated Leaching and Thermochemical Technologies for Producing High-Value Products from Rice Husk: Leaching of Rice Husk with the Aqueous Phases of Bioliquids," Energies, MDPI, vol. 13(22), pages 1-15, November.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:22:p:6033-:d:447281
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    References listed on IDEAS

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    Cited by:

    1. Gao, Anjiang & Wang, Yao & Lin, Guiying & Li, Bin & Hu, Xun & Huang, Yong & Zhang, Shu & Zhang, Hong, 2022. "Volatile-char interactions during biomass pyrolysis: Reactor design toward product control," Renewable Energy, Elsevier, vol. 185(C), pages 1-7.
    2. Na Xu & Mifen Cui & Zhuxiu Zhang & Jihai Tang & Xu Qiao, 2022. "Quest for the Co-Pyrolysis Behavior of Rice Husk and Cresol Distillation Residue: Interaction, Gas Evolution and Kinetics," Energies, MDPI, vol. 15(6), pages 1-13, March.
    3. Carvalho, Pollyana R. & Medeiros, Samuel L.S. & Paixão, Raul L. & Figueredo, Igor M. & Mattos, Adriano L.A. & Rios, M. Alexsandra S., 2023. "Thermogravimetric pyrolysis of residual biomasses obtained post-extraction of carnauba wax: Determination of kinetic parameters using Friedman's isoconversional method," Renewable Energy, Elsevier, vol. 207(C), pages 703-713.

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