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Microwave-Assisted Noncatalytic Esterification of Fatty Acid for Biodiesel Production: A Kinetic Study

Author

Listed:
  • Hoang Chinh Nguyen

    (Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Vietnam)

  • Fu-Ming Wang

    (Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 10607, Taiwan)

  • Kim Khue Dinh

    (Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Vietnam)

  • Thanh Truc Pham

    (Graduate School of Biochemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan)

  • Horng-Yi Juan

    (Graduate School of Biochemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan)

  • Nguyen Phuong Nguyen

    (Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Vietnam)

  • Hwai Chyuan Ong

    (School of Information, Systems and Modelling, Faculty of Engineering and Information Technology, University of Technology Sydney, Ultimo, NSW 2007, Australia)

  • Chia-Hung Su

    (Graduate School of Biochemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan)

Abstract

This study developed a microwave-mediated noncatalytic esterification of oleic acid for producing ethyl biodiesel. The microwave irradiation process outperformed conventional heating methods for the reaction. A highest reaction conversion, 97.62%, was achieved by performing esterification with microwave irradiation at a microwave power of 150 W, 2:1 ethanol:oleic acid molar ratio, reaction time of 6 h, and temperature of 473 K. A second-order reaction model (R 2 of up to 0.997) was established to describe esterification. The reaction rate constants were promoted with increasing microwave power and temperature. A strong linear relation of microwave power to pre-exponential factors was also established, and microwave power greatly influenced the reaction due to nonthermal effects. This study suggested that microwave-assisted noncatalytic esterification is an efficient approach for biodiesel synthesis.

Suggested Citation

  • Hoang Chinh Nguyen & Fu-Ming Wang & Kim Khue Dinh & Thanh Truc Pham & Horng-Yi Juan & Nguyen Phuong Nguyen & Hwai Chyuan Ong & Chia-Hung Su, 2020. "Microwave-Assisted Noncatalytic Esterification of Fatty Acid for Biodiesel Production: A Kinetic Study," Energies, MDPI, vol. 13(9), pages 1-15, May.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:9:p:2167-:d:352937
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    References listed on IDEAS

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    1. Budžaki, Sandra & Miljić, Goran & Sundaram, Smitha & Tišma, Marina & Hessel, Volker, 2018. "Cost analysis of enzymatic biodiesel production in small-scaled packed-bed reactors," Applied Energy, Elsevier, vol. 210(C), pages 268-278.
    2. Samuel Santos & Luís Nobre & João Gomes & Jaime Puna & Rosa Quinta-Ferreira & João Bordado, 2019. "Soybean Oil Transesterification for Biodiesel Production with Micro-Structured Calcium Oxide (CaO) from Natural Waste Materials as a Heterogeneous Catalyst," Energies, MDPI, vol. 12(24), pages 1-10, December.
    3. Huang, Yu-Fong & Chiueh, Pei-Te & Kuan, Wen-Hui & Lo, Shang-Lien, 2016. "Microwave pyrolysis of lignocellulosic biomass: Heating performance and reaction kinetics," Energy, Elsevier, vol. 100(C), pages 137-144.
    4. Hoang Chinh Nguyen & Dinh Thi My Huong & Horng-Yi Juan & Chia-Hung Su & Chien-Chung Chien, 2018. "Liquid Lipase-Catalyzed Esterification of Oleic Acid with Methanol for Biodiesel Production in the Presence of Superabsorbent Polymer: Optimization by Using Response Surface Methodology," Energies, MDPI, vol. 11(5), pages 1-12, April.
    5. Suresh, M. & Jawahar, C.P. & Richard, Arun, 2018. "A review on biodiesel production, combustion, performance, and emission characteristics of non-edible oils in variable compression ratio diesel engine using biodiesel and its blends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 92(C), pages 38-49.
    6. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.
    7. Li, Qiang & Xu, Jingyang & Du, Wei & Li, Yang & Liu, Dehua, 2013. "Ethanol as the acyl acceptor for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 742-748.
    8. Mahlia, T.M.I. & Syazmi, Z.A.H.S. & Mofijur, M. & Abas, A.E. Pg & Bilad, M.R. & Ong, Hwai Chyuan & Silitonga, A.S., 2020. "Patent landscape review on biodiesel production: Technology updates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    9. Silitonga, A.S. & Masjuki, H.H. & Mahlia, T.M.I. & Ong, H.C. & Chong, W.T. & Boosroh, M.H., 2013. "Overview properties of biodiesel diesel blends from edible and non-edible feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 346-360.
    10. Ming-Chien Hsiao & Li-Wen Chang & Shuhn-Shyurng Hou, 2019. "Study of Solid Calcium Diglyceroxide for Biodiesel Production from Waste Cooking Oil Using a High Speed Homogenizer," Energies, MDPI, vol. 12(17), pages 1-11, August.
    11. Cui, Yi & Liang, Yanna, 2014. "Direct transesterification of wet Cryptococcus curvatus cells to biodiesel through use of microwave irradiation," Applied Energy, Elsevier, vol. 119(C), pages 438-444.
    12. Kibong Choi & Suhan Park & Hyun Gu Roh & Chang Sik Lee, 2019. "Combustion and Emission Reduction Characteristics of GTL-Biodiesel Fuel in a Single-Cylinder Diesel Engine," Energies, MDPI, vol. 12(11), pages 1-16, June.
    13. Chia-Hung Su & Hoang Chinh Nguyen & Uyen Khanh Pham & My Linh Nguyen & Horng-Yi Juan, 2018. "Biodiesel Production from a Novel Nonedible Feedstock, Soursop ( Annona muricata L.) Seed Oil," Energies, MDPI, vol. 11(10), pages 1-11, September.
    14. Inam Ullah Khan & Zhenhua Yan & Jun Chen, 2019. "Optimization, Transesterification and Analytical Study of Rhus typhina Non-Edible Seed Oil as Biodiesel Production," Energies, MDPI, vol. 12(22), pages 1-21, November.
    15. Ong, Hwai Chyuan & Masjuki, H.H. & Mahlia, T.M.I. & Silitonga, A.S. & Chong, W.T. & Yusaf, Talal, 2014. "Engine performance and emissions using Jatropha curcas, Ceiba pentandra and Calophyllum inophyllum biodiesel in a CI diesel engine," Energy, Elsevier, vol. 69(C), pages 427-445.
    16. Sara Almasi & Barat Ghobadian & Gholam Hassan Najafi & Talal Yusaf & Masoud Dehghani Soufi & Seyed Salar Hoseini, 2019. "Optimization of an Ultrasonic-Assisted Biodiesel Production Process from One Genotype of Rapeseed (TERI (OE) R-983) as a Novel Feedstock Using Response Surface Methodology," Energies, MDPI, vol. 12(14), pages 1-14, July.
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    Cited by:

    1. Wei-Hsin Chen & Hwai Chyuan Ong & Shih-Hsin Ho & Pau Loke Show, 2021. "Green Energy Technology," Energies, MDPI, vol. 14(20), pages 1-4, October.

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