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Microwave-Assisted Noncatalytic Esterification of Fatty Acid for Biodiesel Production: A Kinetic Study

Author

Listed:
  • Hoang Chinh Nguyen

    (Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Vietnam)

  • Fu-Ming Wang

    (Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 10607, Taiwan)

  • Kim Khue Dinh

    (Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Vietnam)

  • Thanh Truc Pham

    (Graduate School of Biochemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan)

  • Horng-Yi Juan

    (Graduate School of Biochemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan)

  • Nguyen Phuong Nguyen

    (Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Vietnam)

  • Hwai Chyuan Ong

    (School of Information, Systems and Modelling, Faculty of Engineering and Information Technology, University of Technology Sydney, Ultimo, NSW 2007, Australia)

  • Chia-Hung Su

    (Graduate School of Biochemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan)

Abstract

This study developed a microwave-mediated noncatalytic esterification of oleic acid for producing ethyl biodiesel. The microwave irradiation process outperformed conventional heating methods for the reaction. A highest reaction conversion, 97.62%, was achieved by performing esterification with microwave irradiation at a microwave power of 150 W, 2:1 ethanol:oleic acid molar ratio, reaction time of 6 h, and temperature of 473 K. A second-order reaction model (R 2 of up to 0.997) was established to describe esterification. The reaction rate constants were promoted with increasing microwave power and temperature. A strong linear relation of microwave power to pre-exponential factors was also established, and microwave power greatly influenced the reaction due to nonthermal effects. This study suggested that microwave-assisted noncatalytic esterification is an efficient approach for biodiesel synthesis.

Suggested Citation

  • Hoang Chinh Nguyen & Fu-Ming Wang & Kim Khue Dinh & Thanh Truc Pham & Horng-Yi Juan & Nguyen Phuong Nguyen & Hwai Chyuan Ong & Chia-Hung Su, 2020. "Microwave-Assisted Noncatalytic Esterification of Fatty Acid for Biodiesel Production: A Kinetic Study," Energies, MDPI, vol. 13(9), pages 1-15, May.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:9:p:2167-:d:352937
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    Cited by:

    1. Wei-Hsin Chen & Hwai Chyuan Ong & Shih-Hsin Ho & Pau Loke Show, 2021. "Green Energy Technology," Energies, MDPI, vol. 14(20), pages 1-4, October.

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