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Liquid Lipase-Catalyzed Esterification of Oleic Acid with Methanol for Biodiesel Production in the Presence of Superabsorbent Polymer: Optimization by Using Response Surface Methodology

Author

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  • Hoang Chinh Nguyen

    (Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City 700000, Vietnam
    These authors contributed equally to this work.)

  • Dinh Thi My Huong

    (Faculty of Chemical Engineering, University of Technology and Education—The University of Danang, Danang City 550000, Vietnam
    Department of Chemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan
    These authors contributed equally to this work.)

  • Horng-Yi Juan

    (Department of Chemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan
    These authors contributed equally to this work.)

  • Chia-Hung Su

    (Department of Chemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan)

  • Chien-Chung Chien

    (Department of Chemical Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan)

Abstract

Liquid lipase-catalyzed esterification of fatty acids with methanol is a promising process for biodiesel production. However, water by-product from this process favors the reverse reaction, thus reducing the reaction yield. To address this, superabsorbent polymer (SAP) was used as a water-removal agent in the esterification in this study. SAP significantly enhanced the conversion yield compared with the reaction without SAP. The lipase-catalyzed esterification in the presence of SAP was then optimized by response surface methodology to maximize the reaction conversion. A maximum conversion of 96.73% was obtained at a temperature of 35.25 °C, methanol to oleic acid molar ratio of 3.44:1, SAP loading of 10.55%, and enzyme loading of 11.98%. Under these conditions, the Eversa Transform lipase could only be reused once. This study suggests that the liquid lipase-catalyzed esterification of fatty acids using SAP as a water-removal agent is an efficient process for producing biodiesel.

Suggested Citation

  • Hoang Chinh Nguyen & Dinh Thi My Huong & Horng-Yi Juan & Chia-Hung Su & Chien-Chung Chien, 2018. "Liquid Lipase-Catalyzed Esterification of Oleic Acid with Methanol for Biodiesel Production in the Presence of Superabsorbent Polymer: Optimization by Using Response Surface Methodology," Energies, MDPI, vol. 11(5), pages 1-12, April.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:5:p:1085-:d:143693
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    References listed on IDEAS

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    1. Su, Chia-Hung, 2013. "Recoverable and reusable hydrochloric acid used as a homogeneous catalyst for biodiesel production," Applied Energy, Elsevier, vol. 104(C), pages 503-509.
    2. Monique Branco-Vieira & Sergio San Martin & Cristian Agurto & Marco Aurélio dos Santos & Marcos A. V. Freitas & Teresa M. Mata & António A. Martins & Nídia S. Caetano, 2017. "Potential of Phaeodactylum tricornutum for Biodiesel Production under Natural Conditions in Chile," Energies, MDPI, vol. 11(1), pages 1-15, December.
    3. Han Jin & Praveen Kolar & Steven W. Peretti & Jason A. Osborne & Jay J. Cheng, 2017. "Kinetics and Mechanism of NaOH-Impregnated Calcined Oyster Shell-Catalyzed Transesterification of Soybean Oil," Energies, MDPI, vol. 10(11), pages 1-18, November.
    4. Francisca Diana Da Silva Araújo & Antonio Do Nascimento Cavalcante & Maria das Dores B. Sousa & Carla Verônica Rodarte De Moura & Mariana Helena Chaves & Sabria Aued-Pimentel & Miriam Solange Fernande, 2017. "Biodiesel Production from Bombacopsis glabra Oil by Methyl Transesterification Method," Energies, MDPI, vol. 10(9), pages 1-14, September.
    5. Yang, Sen & Li, Qing & Gao, Yang & Zheng, Longyu & Liu, Ziduo, 2014. "Biodiesel production from swine manure via housefly larvae (Musca domestica L.)," Renewable Energy, Elsevier, vol. 66(C), pages 222-227.
    6. Jeeban Poudel & Sujeeta Karki & Nawaraj Sanjel & Malesh Shah & Sea Cheon Oh, 2017. "Comparison of Biodiesel Obtained from Virgin Cooking Oil and Waste Cooking Oil Using Supercritical and Catalytic Transesterification," Energies, MDPI, vol. 10(4), pages 1-14, April.
    7. Jeeban Poudel & Malesh Shah & Sujeeta Karki & Sea Cheon Oh, 2017. "Qualitative Analysis of Transesterification of Waste Pig Fat in Supercritical Alcohols," Energies, MDPI, vol. 10(3), pages 1-13, February.
    8. Keon Hee Kim & Eun Yeol Lee, 2017. "Simultaneous Production of Transformer Insulating Oil and Value-Added Glycerol Carbonates from Soybean Oil by Lipase-Catalyzed Transesterification in Dimethyl Carbonate," Energies, MDPI, vol. 11(1), pages 1-11, December.
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    Cited by:

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    2. Wei-Hsin Chen & Keat Teong Lee & Hwai Chyuan Ong, 2019. "Biofuel and Bioenergy Technology," Energies, MDPI, vol. 12(2), pages 1-12, January.
    3. Ibnu Maulana Hidayatullah & Frederick Soetandar & Pingkan Vanessa Sudiyasa & Patrick Cognet & Heri Hermansyah, 2023. "Ion Exchange Resin and Entrapped Candida rugosa Lipase for Biodiesel Synthesis in the Recirculating Packed-Bed Reactor: A Performance Comparison of Heterogeneous Catalysts," Energies, MDPI, vol. 16(12), pages 1-17, June.
    4. Wancura, João H.C. & Brondani, Michel & dos Santos, Maicon S.N. & Oro, Carolina E.D. & Wancura, Guilherme C. & Tres, Marcus V. & Oliveira, J. Vladimir, 2023. "Demystifying the enzymatic biodiesel: How lipases are contributing to its technological advances," Renewable Energy, Elsevier, vol. 216(C).
    5. Hoang Chinh Nguyen & Fu-Ming Wang & Kim Khue Dinh & Thanh Truc Pham & Horng-Yi Juan & Nguyen Phuong Nguyen & Hwai Chyuan Ong & Chia-Hung Su, 2020. "Microwave-Assisted Noncatalytic Esterification of Fatty Acid for Biodiesel Production: A Kinetic Study," Energies, MDPI, vol. 13(9), pages 1-15, May.

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