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Optimization of the Transesterification of Waste Cooking Oil with Mg-Al Hydrotalcite Using Response Surface Methodology

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  • Laureano Costarrosa

    (Department of Physical Chemistry and Applied Thermodynamics, EPS, Edificio Leonardo da Vinci, Campus de Rabanales, Universidad de Córdoba, Campus de Excelencia Agroalimentario ceiA3, 14014 Córdoba, Spain)

  • David Eduardo Leiva-Candia

    (Department of Physical Chemistry and Applied Thermodynamics, EPS, Edificio Leonardo da Vinci, Campus de Rabanales, Universidad de Córdoba, Campus de Excelencia Agroalimentario ceiA3, 14014 Córdoba, Spain)

  • Antonio José Cubero-Atienza

    (Department of Rural Engineering, EPS, Edificio Leonardo da Vinci, Campus de Rabanales, Universidad de Córdoba, Campus de Excelencia Agroalimentario ceiA3, 14014 Córdoba, Spain)

  • Juan José Ruiz

    (Department of Physical Chemistry and Applied Thermodynamics, EPS, Edificio Leonardo da Vinci, Campus de Rabanales, Universidad de Córdoba, Campus de Excelencia Agroalimentario ceiA3, 14014 Córdoba, Spain)

  • M. Pilar Dorado

    (Department of Physical Chemistry and Applied Thermodynamics, EPS, Edificio Leonardo da Vinci, Campus de Rabanales, Universidad de Córdoba, Campus de Excelencia Agroalimentario ceiA3, 14014 Córdoba, Spain)

Abstract

Nowadays, biodiesel has become a very promising alternative to fossil diesel fuel, regarding environmental concerns and fuel resource depletion. Biodiesel is usually produced through homogeneous or heterogeneous transesterification of different fatty raw materials. Although main research has been carried out with homogenous catalysts, heterogeneous catalysts may be of interest due to ease of recovery and recycling, as well as readiness for continuous processing. In this work, calcined Mg-Al hydrotalcite (HT) was used for the heterogeneous transesterification of waste cooking oil. Three reaction parameters, namely, reaction time, amount of catalyst, and methanol-to-oil molar ratio, were optimized by means of Response Surface Methodology (RSM) at constant temperature (65 °C), using a Box-Behnken design. Optimal fatty acid methyl ester (FAME) content (86.23% w / w FAME/sample) was predicted by the model with an R-squared value of 98.45%, using 3.39 g of HT (8.5% w / w oil) and an 8:1 methanol-oil molar ratio, for a duration of 3.12 h. It was observed that calcination of HT, while avoiding the previous washing step, allowed the presence of chemical species that enhanced the effect of the catalyst. It can be concluded from this field trial that calcined and nonwashed Mg-Al hydrotalcite may be considered an effective basic catalyst for the production of biodiesel from waste cooking oil. Also, RSM proved to be a useful tool for predicting biodiesel yield.

Suggested Citation

  • Laureano Costarrosa & David Eduardo Leiva-Candia & Antonio José Cubero-Atienza & Juan José Ruiz & M. Pilar Dorado, 2018. "Optimization of the Transesterification of Waste Cooking Oil with Mg-Al Hydrotalcite Using Response Surface Methodology," Energies, MDPI, vol. 11(2), pages 1-9, January.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:2:p:302-:d:129384
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    References listed on IDEAS

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    1. Ma, Yingqun & Wang, Qunhui & Zheng, Lu & Gao, Zhen & Wang, Qiang & Ma, Yuhui, 2016. "Mixed methanol/ethanol on transesterification of waste cooking oil using Mg/Al hydrotalcite catalyst," Energy, Elsevier, vol. 107(C), pages 523-531.
    2. Dorado, M.P. & Cruz, F. & Palomar, J.M. & López, F.J., 2006. "An approach to the economics of two vegetable oil-based biofuels in Spain," Renewable Energy, Elsevier, vol. 31(8), pages 1231-1237.
    3. Marina Corral Bobadilla & Rubén Lostado Lorza & Rubén Escribano García & Fátima Somovilla Gómez & Eliseo P. Vergara González, 2017. "An Improvement in Biodiesel Production from Waste Cooking Oil by Applying Thought Multi-Response Surface Methodology Using Desirability Functions," Energies, MDPI, vol. 10(1), pages 1-20, January.
    4. Mohammad I. Jahirul & Wenyong Koh & Richard J. Brown & Wijitha Senadeera & Ian O'Hara & Lalehvash Moghaddam, 2014. "Biodiesel Production from Non-Edible Beauty Leaf ( Calophyllum inophyllum ) Oil: Process Optimization Using Response Surface Methodology (RSM)," Energies, MDPI, vol. 7(8), pages 1-15, August.
    5. Arjun B. Chhetri & K. Chris Watts & M. Rafiqul Islam, 2008. "Waste Cooking Oil as an Alternate Feedstock for Biodiesel Production," Energies, MDPI, vol. 1(1), pages 1-16, April.
    6. Hwei Voon Lee & Joon Ching Juan & Taufiq-Yap Yun Hin & Hwai Chyuan Ong, 2016. "Environment-Friendly Heterogeneous Alkaline-Based Mixed Metal Oxide Catalysts for Biodiesel Production," Energies, MDPI, vol. 9(8), pages 1-12, August.
    7. Muhammad Qasim & Tariq Mahmood Ansari & Mazhar Hussain, 2017. "Combustion, Performance, and Emission Evaluation of a Diesel Engine with Biodiesel Like Fuel Blends Derived From a Mixture of Pakistani Waste Canola and Waste Transformer Oils," Energies, MDPI, vol. 10(7), pages 1-16, July.
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    3. Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.
    4. Fábio Antônio do Nascimento Setúbal & Sérgio de Souza Custódio Filho & Newton Sure Soeiro & Alexandre Luiz Amarante Mesquita & Marcus Vinicius Alves Nunes, 2022. "Force Identification from Vibration Data by Response Surface and Random Forest Regression Algorithms," Energies, MDPI, vol. 15(10), pages 1-15, May.
    5. Jemima Romola, C.V. & Meganaharshini, M. & Rigby, S.P. & Ganesh Moorthy, I. & Shyam Kumar, R. & Karthikumar, Sankar, 2021. "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
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