IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v166y2020icp163-175.html
   My bibliography  Save this article

Cocoa pod husk-plantain peel blend as a novel green heterogeneous catalyst for renewable and sustainable honne oil biodiesel synthesis: A case of biowastes-to-wealth

Author

Listed:
  • Olatundun, Esther Adedayo
  • Borokini, Omowumi Oluwatumininu
  • Betiku, Eriola

Abstract

The present study investigated honne oil methyl esters (HOME) production from crude honne seed oil (HSO) using a novel catalyst synthesized from a blend of cocoa pod husk and plantain peel. A two-step esterification-transesterification method was used for the HOME production. For the esterification, the crude HSO was pretreated with H2SO4 to reduce its very high acid value to an acceptable level prior to transesterification to biodiesel. Characterization of the calcined cocoa pod husk-plantain peel ash (CCPA) showed that K (50.95%), Mg (2.49%) and Ca (2.30%) were the major metals present, thereby confirming its heterogeneity. Physisorption isotherms obtained for the CCPA indicate it is composed of nanoparticles that are mesoporous in nature. The initial high acid value of the oil (35.5 g KOH/g oil) was reduced to 1.68 ± 0.57 g KOH/g oil via esterification at a temperature of 65 °C, MeOH:HSO molar ratio of 50:1 and H2SO4 of 2 vol% after 2.5 h. The best operating condition that gave maximum HOME yield (98.98 ± 0.04 wt%) was CCPA amount of 4.5 wt%, reaction temperature of 65 °C, time of 2.5 h and MeOH:pretreated HSO molar ratio of 15:1. The HOME produced satisfied standard limits set for biodiesel.

Suggested Citation

  • Olatundun, Esther Adedayo & Borokini, Omowumi Oluwatumininu & Betiku, Eriola, 2020. "Cocoa pod husk-plantain peel blend as a novel green heterogeneous catalyst for renewable and sustainable honne oil biodiesel synthesis: A case of biowastes-to-wealth," Renewable Energy, Elsevier, vol. 166(C), pages 163-175.
    • Handle: RePEc:eee:renene:v:166:y:2020:i:c:p:163-175
    DOI: 10.1016/j.renene.2020.11.131
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120318838
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.11.131?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Gohain, Minakshi & Laskar, Khairujjaman & Paul, Atanu Kumar & Daimary, Niran & Maharana, Mrutyunjay & Goswami, Imon Kalyan & Hazarika, Anil & Bora, Utpal & Deka, Dhanapati, 2020. "Carica papaya stem: A source of versatile heterogeneous catalyst for biodiesel production and C–C bond formation," Renewable Energy, Elsevier, vol. 147(P1), pages 541-555.
    2. Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Yussof, Hafizuddin Wan & Chong, W.T. & Lee, Keat Teong, 2013. "A comparative evaluation of physical and chemical properties of biodiesel synthesized from edible and non-edible oils and study on the effect of biodiesel blending," Energy, Elsevier, vol. 58(C), pages 296-304.
    3. Vadery, Vinu & Narayanan, Binitha N. & Ramakrishnan, Resmi M. & Cherikkallinmel, Sudha Kochiyil & Sugunan, Sankaran & Narayanan, Divya P. & Sasidharan, Sreenikesh, 2014. "Room temperature production of jatropha biodiesel over coconut husk ash," Energy, Elsevier, vol. 70(C), pages 588-594.
    4. Arumugam, A. & Ponnusami, V., 2014. "Biodiesel production from Calophyllum inophyllum oil using lipase producing Rhizopus oryzae cells immobilized within reticulated foams," Renewable Energy, Elsevier, vol. 64(C), pages 276-282.
    5. Balajii, Muthusamy & Niju, Subramaniapillai, 2020. "Banana peduncle – A green and renewable heterogeneous base catalyst for biodiesel production from Ceiba pentandra oil," Renewable Energy, Elsevier, vol. 146(C), pages 2255-2269.
    6. Yesilyurt, Murat Kadir & Cesur, Cüneyt & Aslan, Volkan & Yilbasi, Zeki, 2020. "The production of biodiesel from safflower (Carthamus tinctorius L.) oil as a potential feedstock and its usage in compression ignition engine: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    7. Anietie O. Etim & Eriola Betiku & Sheriff O. Ajala & Peter J. Olaniyi & Tunde V. Ojumu, 2018. "Potential of Ripe Plantain Fruit Peels as an Ecofriendly Catalyst for Biodiesel Synthesis: Optimization by Artificial Neural Network Integrated with Genetic Algorithm," Sustainability, MDPI, vol. 10(3), pages 1-15, March.
    8. Mohammad I. Jahirul & Wenyong Koh & Richard J. Brown & Wijitha Senadeera & Ian O'Hara & Lalehvash Moghaddam, 2014. "Biodiesel Production from Non-Edible Beauty Leaf ( Calophyllum inophyllum ) Oil: Process Optimization Using Response Surface Methodology (RSM)," Energies, MDPI, vol. 7(8), pages 1-15, August.
    9. Betiku, Eriola & Akintunde, Aramide Mistura & Ojumu, Tunde Victor, 2016. "Banana peels as a biobase catalyst for fatty acid methyl esters production using Napoleon's plume (Bauhinia monandra) seed oil: A process parameters optimization study," Energy, Elsevier, vol. 103(C), pages 797-806.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Daimary, Niran & Boruah, Pankaj & Eldiehy, Khalifa S.H. & Pegu, Tapan & Bardhan, Pritam & Bora, Utpal & Mandal, Manabendra & Deka, Dhanapati, 2022. "Musa acuminata peel: A bioresource for bio-oil and by-product utilization as a sustainable source of renewable green catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 187(C), pages 450-462.
    2. Christopher Tunji Oloyede & Simeon Olatayo Jekayinfa & Abass Olanrewaju Alade & Oyetola Ogunkunle & Opeyeolu Timothy Laseinde & Ademola Oyejide Adebayo & Adeola Ibrahim Abdulkareem & Ghassan Fadhil Sm, 2023. "Synthesis of Biobased Composite Heterogeneous Catalyst for Biodiesel Production Using Simplex Lattice Design Mixture: Optimization Process by Taguchi Method," Energies, MDPI, vol. 16(5), pages 1-26, February.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Eldiehy, Khalifa S.H. & Gohain, Minakshi & Daimary, Niran & Borah, Doljit & Mandal, Manabendra & Deka, Dhanapati, 2022. "Radish (Raphanus sativus L.) leaves: A novel source for a highly efficient heterogeneous base catalyst for biodiesel production using waste soybean cooking oil and Scenedesmus obliquus oil," Renewable Energy, Elsevier, vol. 191(C), pages 888-901.
    2. Daimary, Niran & Boruah, Pankaj & Eldiehy, Khalifa S.H. & Pegu, Tapan & Bardhan, Pritam & Bora, Utpal & Mandal, Manabendra & Deka, Dhanapati, 2022. "Musa acuminata peel: A bioresource for bio-oil and by-product utilization as a sustainable source of renewable green catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 187(C), pages 450-462.
    3. Babatunde Oladipo & Tunde V Ojumu & Lekan M Latinwo & Eriola Betiku, 2020. "Pawpaw ( Carica papaya ) Peel Waste as a Novel Green Heterogeneous Catalyst for Moringa Oil Methyl Esters Synthesis: Process Optimization and Kinetic Study," Energies, MDPI, vol. 13(21), pages 1-25, November.
    4. Nath, Biswajit & Basumatary, Bidangshri & Brahma, Sujata & Das, Bipul & Kalita, Pranjal & Rokhum, Samuel Lalthazuala & Basumatary, Sanjay, 2023. "Musa champa peduncle waste-derived efficient catalyst: Studies of biodiesel synthesis, reaction kinetics and thermodynamics," Energy, Elsevier, vol. 270(C).
    5. Nath, Biswajit & Kalita, Pranjal & Das, Bipul & Basumatary, Sanjay, 2020. "Highly efficient renewable heterogeneous base catalyst derived from waste Sesamum indicum plant for synthesis of biodiesel," Renewable Energy, Elsevier, vol. 151(C), pages 295-310.
    6. Vigneshwar, V. & Krishnan, S. Yogesh & Kishna, R. Susanth & Srinath, R. & Ashok, B. & Nanthagopal, K., 2019. "Comprehensive review of Calophyllum inophyllum as a feasible alternate energy for CI engine applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    7. Miladinović, Marija R. & Krstić, Jugoslav B. & Zdujić, Miodrag V. & Veselinović, Ljiljana M. & Veljović, Djordje N. & Banković-Ilić, Ivana B. & Stamenković, Olivera S. & Veljković, Vlada B., 2022. "Transesterification of used cooking sunflower oil catalyzed by hazelnut shell ash," Renewable Energy, Elsevier, vol. 183(C), pages 103-113.
    8. Adepoju, T.F. & Ibeh, M.A. & Udoetuk, E.N. & Babatunde, E.O., 2021. "Quaternary blend of Carica papaya - Citrus sinesis - Hibiscus sabdariffa - Waste used oil for biodiesel synthesis using CaO-based catalyst derived from binary mix of Lattorina littorea and Mactra cora," Renewable Energy, Elsevier, vol. 171(C), pages 22-33.
    9. Das, Arpita & Li, Hui & Kataki, Rupam & Agrawal, Pratibha S. & Moyon, N.S. & Gurunathan, Baskar & Rokhum, Samuel Lalthazuala, 2023. "Terminalia arjuna bark – A highly efficient renewable heterogeneous base catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 212(C), pages 185-196.
    10. Mendonça, Iasmin M. & Paes, Orlando A.R.L. & Maia, Paulo J.S. & Souza, Mayane P. & Almeida, Richardson A. & Silva, Cláudia C. & Duvoisin, Sérgio & de Freitas, Flávio A., 2019. "New heterogeneous catalyst for biodiesel production from waste tucumã peels (Astrocaryum aculeatum Meyer): Parameters optimization study," Renewable Energy, Elsevier, vol. 130(C), pages 103-110.
    11. Jisieike, Chiazor Faustina & Ishola, Niyi Babatunde & Latinwo, Lekan M. & Betiku, Eriola, 2023. "Crude rubber seed oil esterification using a solid catalyst: Optimization by hybrid adaptive neuro-fuzzy inference system and response surface methodology," Energy, Elsevier, vol. 263(PB).
    12. Arumugam, A. & Ponnusami, V., 2019. "Biodiesel production from Calophyllum inophyllum oil a potential non-edible feedstock: An overview," Renewable Energy, Elsevier, vol. 131(C), pages 459-471.
    13. Akhabue, Christopher Ehiaguina & Osa-Benedict, Evidence Osayi & Oyedoh, Eghe Amenze & Otoikhian, Shegun Kevin, 2020. "Development of a bio-based bifunctional catalyst for simultaneous esterification and transesterification of neem seed oil: Modeling and optimization studies," Renewable Energy, Elsevier, vol. 152(C), pages 724-735.
    14. Gohain, Minakshi & Laskar, Khairujjaman & Paul, Atanu Kumar & Daimary, Niran & Maharana, Mrutyunjay & Goswami, Imon Kalyan & Hazarika, Anil & Bora, Utpal & Deka, Dhanapati, 2020. "Carica papaya stem: A source of versatile heterogeneous catalyst for biodiesel production and C–C bond formation," Renewable Energy, Elsevier, vol. 147(P1), pages 541-555.
    15. Pooja, S. & Anbarasan, B. & Ponnusami, V. & Arumugam, A., 2021. "Efficient production and optimization of biodiesel from kapok (Ceiba pentandra) oil by lipase transesterification process: Addressing positive environmental impact," Renewable Energy, Elsevier, vol. 165(P1), pages 619-631.
    16. Miladinović, Marija R. & Zdujić, Miodrag V. & Veljović, Djordje N. & Krstić, Jugoslav B. & Banković-Ilić, Ivana B. & Veljković, Vlada B. & Stamenković, Olivera S., 2020. "Valorization of walnut shell ash as a catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 147(P1), pages 1033-1043.
    17. Zhang, Xiaolei & Yan, Song & Tyagi, Rajeshwar D. & Surampalli, RaoY. & Valéro, Jose R., 2014. "Wastewater sludge as raw material for microbial oils production," Applied Energy, Elsevier, vol. 135(C), pages 192-201.
    18. Patchimpet, Jaran & Simpson, Benjamin K. & Sangkharak, Kanokphorn & Klomklao, Sappasith, 2020. "Optimization of process variables for the production of biodiesel by transesterification of used cooking oil using lipase from Nile tilapia viscera," Renewable Energy, Elsevier, vol. 153(C), pages 861-869.
    19. Altarazi, Yazan S.M. & Abu Talib, Abd Rahim & Gires, Ezanee & Yu, Jianglong & Lucas, John & Yusaf, Talal, 2021. "Performance and exhaust emissions rate of small-scale turbojet engine running on dual biodiesel blends using Gasturb," Energy, Elsevier, vol. 232(C).
    20. Veronica Winoto & Nuttawan Yoswathana, 2019. "Optimization of Biodiesel Production Using Nanomagnetic CaO-Based Catalysts with Subcritical Methanol Transesterification of Rubber Seed Oil," Energies, MDPI, vol. 12(2), pages 1-13, January.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:166:y:2020:i:c:p:163-175. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.