IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v171y2021icp22-33.html

Quaternary blend of Carica papaya - Citrus sinesis - Hibiscus sabdariffa - Waste used oil for biodiesel synthesis using CaO-based catalyst derived from binary mix of Lattorina littorea and Mactra coralline shell

Author

Listed:
  • Adepoju, T.F.
  • Ibeh, M.A.
  • Udoetuk, E.N.
  • Babatunde, E.O.

Abstract

These studies focuses on synthesizing of an efficient CaO-based-catalyst derived from the binary mixture of Lattorina littorea (periwinkles shell) and Mactra coralline (seashell), and apply it to transesterification of a quaternary mix of Carica papaya - Citrus sinesis- Hibiscus sabdariffa- Waste used. Details characterization of the developed catalyst was carried out using SEM, FTIR, and XRD to establish its catalytic potential. Process parameters optimization for the transesterification process was carried out to determine the optimum yield of biodiesel from oil blend. Lattorina littorea and Mactra coralline were made into powder by milling after drying, the powdered were mixed in the same ratio to obtain a developed catalyst before characterization. Oil was extracted from Carica papaya, Citrus sinesis, Hibiscus sabdariffa seed powder through solvent extraction method, the extracted oil was mixed in quaternary ratio with waste used oil, the properties of the mixed oil was determined before the transesterification with ethanol. Process optimization was carried using response surface methodology (RSM) coupled with central composite design (CCD) by considering four independent variables (reaction time, derived calcined catalyst powder (DCCP) amount, reaction temperature, and EtOH/OMR). The catalyst recyclability test was carried out, and the biodiesel quality was determined through physicochemical properties. The results showed 25:25:25:25 quaternary blend produced oil with low viscous and high volatility. Thermal treatment of a developed catalyst (DP) from Lattorina littorea mix with Mactra coralline, at 900 °C for 3 h produced CaO of 99.02 (% wt.) on XRD analysis result. The produced catalyst developed was re-used up to 3–cycles for base transesterification. The maximum experimental yield of 99.95 (% wt.) at a reaction time of 60 min, DCCP amount of 3.0 (g), reaction temperature of 70 °C, and EtOH/OMR of 6:1 (ml/ml), was obtained, but the statistical optimization predicted biodiesel yield of 99.8044 (wt. %) at a reaction time of 57.72 min, DCCP amount of 3.0 (g), reaction temperature of 69.54 °C, and EtOH/OMR of 6:1 (ml/ml), this yield was validated in triplicate and an average biodiesel yield of 99.7800 (%wt.) was obtained. Analysis of variance and the p-value showed that the selected variable factors were remarkably significant (p-value<0.0001). Based on fit statistics and model comparison statistics, the coefficient of determination (R squared) of 99.84% was obtained with the predicted R2 of 99.06 in reasonable agreement with the adjusted R2 of 99.68. The quality of biodiesel produced was within the specification limits of biodiesel standard.

Suggested Citation

  • Adepoju, T.F. & Ibeh, M.A. & Udoetuk, E.N. & Babatunde, E.O., 2021. "Quaternary blend of Carica papaya - Citrus sinesis - Hibiscus sabdariffa - Waste used oil for biodiesel synthesis using CaO-based catalyst derived from binary mix of Lattorina littorea and Mactra cora," Renewable Energy, Elsevier, vol. 171(C), pages 22-33.
    • Handle: RePEc:eee:renene:v:171:y:2021:i:c:p:22-33
    DOI: 10.1016/j.renene.2021.02.020
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121001877
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.02.020?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Abdolsaeid Ganjehkaviri & Mohammad Nazri Mohd Jaafar & Seyed Ehsan Hosseini & Anas Basri Musthafa, 2016. "Performance Evaluation of Palm Oil-Based Biodiesel Combustion in an Oil Burner," Energies, MDPI, vol. 9(2), pages 1-10, February.
    2. Qiu, Fengxian & Li, Yihuai & Yang, Dongya & Li, Xiaohua & Sun, Ping, 2011. "Biodiesel production from mixed soybean oil and rapeseed oil," Applied Energy, Elsevier, vol. 88(6), pages 2050-2055, June.
    3. Banković–Ilić, Ivana B. & Miladinović, Marija R. & Stamenković, Olivera S. & Veljković, Vlada B., 2017. "Application of nano CaO–based catalysts in biodiesel synthesis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 746-760.
    4. Md Mofijur Rahman & Mohammad Rasul & Nur Md Sayeed Hassan & Justin Hyde, 2016. "Prospects of Biodiesel Production from Macadamia Oil as an Alternative Fuel for Diesel Engines," Energies, MDPI, vol. 9(6), pages 1-15, May.
    5. Anietie O. Etim & Eriola Betiku & Sheriff O. Ajala & Peter J. Olaniyi & Tunde V. Ojumu, 2018. "Potential of Ripe Plantain Fruit Peels as an Ecofriendly Catalyst for Biodiesel Synthesis: Optimization by Artificial Neural Network Integrated with Genetic Algorithm," Sustainability, MDPI, vol. 10(3), pages 1-15, March.
    6. Balajii, Muthusamy & Niju, Subramaniapillai, 2020. "Banana peduncle – A green and renewable heterogeneous base catalyst for biodiesel production from Ceiba pentandra oil," Renewable Energy, Elsevier, vol. 146(C), pages 2255-2269.
    7. Lin, Lin & Cunshan, Zhou & Vittayapadung, Saritporn & Xiangqian, Shen & Mingdong, Dong, 2011. "Opportunities and challenges for biodiesel fuel," Applied Energy, Elsevier, vol. 88(4), pages 1020-1031, April.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Sun, Chihe & Hu, Yun & Sun, Fubao & Sun, Yahui & Song, Guojie & Chang, Haixing & Lunprom, Siriporn, 2022. "Comparison of biodiesel production using a novel porous Zn/Al/Co complex oxide prepared from different methods: Physicochemical properties, reaction kinetic and thermodynamic studies," Renewable Energy, Elsevier, vol. 181(C), pages 1419-1430.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Olatundun, Esther Adedayo & Borokini, Omowumi Oluwatumininu & Betiku, Eriola, 2020. "Cocoa pod husk-plantain peel blend as a novel green heterogeneous catalyst for renewable and sustainable honne oil biodiesel synthesis: A case of biowastes-to-wealth," Renewable Energy, Elsevier, vol. 166(C), pages 163-175.
    2. Jisieike, Chiazor Faustina & Betiku, Eriola & Ojumu, Tunde V. & Latinwo, Lekan M., 2025. "Rubber seed oil biodiesel synthesis via ethanolysis using a blend of four biogenic residues as a sustainable heterogeneous catalyst," Renewable Energy, Elsevier, vol. 252(C).
    3. Mohammad Anwar & Mohammad G. Rasul & Nanjappa Ashwath & Md Mofijur Rahman, 2018. "Optimisation of Second-Generation Biodiesel Production from Australian Native Stone Fruit Oil Using Response Surface Method," Energies, MDPI, vol. 11(10), pages 1-18, September.
    4. Maleki, Esmat & Aroua, Mohamed Kheireddine & Sulaiman, Nik Meriam Nik, 2013. "Improved yield of solvent free enzymatic methanolysis of palm and jatropha oils blended with castor oil," Applied Energy, Elsevier, vol. 104(C), pages 905-909.
    5. Nath, Biswajit & Kalita, Pranjal & Das, Bipul & Basumatary, Sanjay, 2020. "Highly efficient renewable heterogeneous base catalyst derived from waste Sesamum indicum plant for synthesis of biodiesel," Renewable Energy, Elsevier, vol. 151(C), pages 295-310.
    6. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Zarei, Alireza & Noshadi, Iman, 2013. "Transesterification of waste cooking oil by heteropoly acid (HPA) catalyst: Optimization and kinetic model," Applied Energy, Elsevier, vol. 102(C), pages 283-292.
    7. Eldiehy, Khalifa S.H. & Gohain, Minakshi & Daimary, Niran & Borah, Doljit & Mandal, Manabendra & Deka, Dhanapati, 2022. "Radish (Raphanus sativus L.) leaves: A novel source for a highly efficient heterogeneous base catalyst for biodiesel production using waste soybean cooking oil and Scenedesmus obliquus oil," Renewable Energy, Elsevier, vol. 191(C), pages 888-901.
    8. Liu, Chien-Hung & Huang, Chien-Chang & Wang, Yao-Wen & Lee, Duu-Jong & Chang, Jo-Shu, 2012. "Biodiesel production by enzymatic transesterification catalyzed by Burkholderia lipase immobilized on hydrophobic magnetic particles," Applied Energy, Elsevier, vol. 100(C), pages 41-46.
    9. Rathmann, Régis & Szklo, Alexandre & Schaeffer, Roberto, 2012. "Targets and results of the Brazilian Biodiesel Incentive Program – Has it reached the Promised Land?," Applied Energy, Elsevier, vol. 97(C), pages 91-100.
    10. Adepoju, T.F. & Ekanem, U. & Ibeh, M.A. & Udoetuk, E.N., 2020. "A derived novel mesoporous catalyst for biodiesel synthesis from Hura creptian-Sesamum indicum-Blighia sapida-Ayo/Ncho oil blend: A case of Brachyura, Achatina fulica and Littorina littorea shells mix," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    11. Wang, Jiayan & Xing, Shiyou & Huang, Yanqin & Fan, Pei & Fu, Junying & Yang, Gaixiu & Yang, Lingmei & Lv, Pengmei, 2017. "Highly stable gasified straw slag as a novel solid base catalyst for the effective synthesis of biodiesel: Characteristics and performance," Applied Energy, Elsevier, vol. 190(C), pages 703-712.
    12. Ramachandra, T.V. & Saranya, G., 2022. "Sustainable Bioeconomy prospects of diatom biorefineries in the Indian west coast," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    13. Aghel, Babak & Mohadesi, Majid & Ansari, Ahmadreza & Maleki, Mahmoud, 2019. "Pilot-scale production of biodiesel from waste cooking oil using kettle limescale as a heterogeneous catalyst," Renewable Energy, Elsevier, vol. 142(C), pages 207-214.
    14. Bora, Plaban & Konwar, Lakhya Jyoti & Boro, Jutika & Phukan, Mayur Mausoom & Deka, Dhanapati & Konwar, Bolin Kumar, 2014. "Hybrid biofuels from non-edible oils: A comparative standpoint with corresponding biodiesel," Applied Energy, Elsevier, vol. 135(C), pages 450-460.
    15. Wongwuttanasatian, Tanakorn & Jookjantra, Kittichai, 2020. "Effect of dual-frequency pulsed ultrasonic excitation and catalyst size for biodiesel production," Renewable Energy, Elsevier, vol. 152(C), pages 1220-1226.
    16. Joshi, Girdhar & Pandey, Jitendra K. & Rana, Sravendra & Rawat, Devendra S., 2017. "Challenges and opportunities for the application of biofuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 850-866.
    17. Daimary, Niran & Boruah, Pankaj & Eldiehy, Khalifa S.H. & Pegu, Tapan & Bardhan, Pritam & Bora, Utpal & Mandal, Manabendra & Deka, Dhanapati, 2022. "Musa acuminata peel: A bioresource for bio-oil and by-product utilization as a sustainable source of renewable green catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 187(C), pages 450-462.
    18. Thanh Xuan NguyenThi & Jean-Patrick Bazile & David Bessières, 2018. "Density Measurements of Waste Cooking Oil Biodiesel and Diesel Blends Over Extended Pressure and Temperature Ranges," Energies, MDPI, vol. 11(5), pages 1-14, May.
    19. Peralta-Ruiz, Y. & González-Delgado, A.-D. & Kafarov, V., 2013. "Evaluation of alternatives for microalgae oil extraction based on exergy analysis," Applied Energy, Elsevier, vol. 101(C), pages 226-236.
    20. Glisic, Sandra B. & Pajnik, Jelena M. & Orlović, Aleksandar M., 2016. "Process and techno-economic analysis of green diesel production from waste vegetable oil and the comparison with ester type biodiesel production," Applied Energy, Elsevier, vol. 170(C), pages 176-185.

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:171:y:2021:i:c:p:22-33. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.